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Solubility and dissolution thermodynamics of hexaquoiron(III)tris(p-toluenesulfonate) in (ethanol+water) binary mixtures within 291.15–333.15 K

  • Separation Technology, Thermodynamics
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Abstract

The solubility of hexaquoiron(III)tris(p-toluenesulfonate) [Fe(OTs)3·6H2O] in (ethanol+water) mixtures with a mole fraction of 0–0.327 ethanol was measured from 291.15 to 333.15 K by using a synthetic method. The experimental results show that the solubility of Fe(OTs)3·6H2O increases with an increase in temperature and an enrichment in ethanol content. The solubility data were correlated by the modified Apelblat equation, the Redlich-Kister (CNIBS/R-K) model, and the hybrid model, and the results showed that the three models agree well with experimental data. The thermodynamic properties of the dissolution process, including enthalpy, entropy, and Gibbs energy were estimated from the experimental data by the modified van’t Hoff equation, indicating that the process of the dissolution of Fe(OTs)3·6H2O is endothermic and spontaneous.

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References

  1. M. Horacio and M. M. Afonso, Synth Commun., 38, 2607 (2008).

    Article  Google Scholar 

  2. M. J. Spafford, E.D. Anderson, J.R. Lacey, A.C. Palma and R.S. Mohan, Tetrahedron. Lett., 48, 8665 (2007).

    Article  CAS  Google Scholar 

  3. K. Komeyama, T. Morimoto, Y. Nakayama and K. Takaki, Tetrahedron. Lett., 48, 3259 (2007).

    Article  CAS  Google Scholar 

  4. F. Ke, Z. K. Li, H. F. Xiang and X. G. Zhou, Tetrahedron. Lett., 52, 318 (2011).

    Article  CAS  Google Scholar 

  5. J.C. Choi, K. Kohno, D. Masuda, H. Yasuda and T. Sakakura, Chem. Commun., 38, 777 (2008).

    Article  Google Scholar 

  6. M.S. Jung, W. S. Kim, Y.H. Shin, H. J. Jin, Y. S. Kim and E. J. Kang, Org. Lett., 14, 6262 (2012).

    Article  CAS  Google Scholar 

  7. J. M. Bothwell, V.V. Angeles, J. P. Carolan, M. E. Olson and R. S. Mohan, Tetrahedron. Lett., 51, 1056 (2010).

    Article  CAS  Google Scholar 

  8. M.E. Olson, J.P. Carolan, M.V. Chiodo, P.R. Lazzara and R.S. Mohan, Tetrahedron. Lett., 51, 3969 (2010).

    Article  CAS  Google Scholar 

  9. S.M. Holmes, S. G. Mckinley and G. S. Girolami, Inorganic Syntheses., 33, 91 (2002).

    CAS  Google Scholar 

  10. J. Chen, Z. X. Zeng, W. L. Xue, D. Wang and Y. Huang, Ind. Eng. Chem. Res., 50, 11755 (2011).

    Article  CAS  Google Scholar 

  11. C. Yu, Z. X. Zeng and W. L. Xue, Ind. Eng. Chem., Res., 54, 3961 (2015).

    Article  CAS  Google Scholar 

  12. C. Yu, Z. J. Huang, Z. X. Zeng and W. L. Xue, J. Solution Chem., 45, 395 (2016).

    Article  CAS  Google Scholar 

  13. A. Apelblat and E. Manzurola, J. Chem. Thermodynamics, 31, 85 (1999).

    Article  CAS  Google Scholar 

  14. A. Apelblat and E. Manzurola, Chem. Thermodyn., 33, 147 (2001).

    Article  CAS  Google Scholar 

  15. Q.H. Luan, Y. L. Wang, G. Wang, J.X. Yang and H. X. Hao, J. Chem. Eng. Data, 59, 2642 (2014).

    Article  CAS  Google Scholar 

  16. A. Jouyban-Gharamaleki and W. E. Acree Jr., Int. J. Pharm., 167, 177 (1998).

    Article  CAS  Google Scholar 

  17. Z.M. Zhou, Y. X. Qu, J.D. Wang, S. Wang, J. S. Liu and M. Wu, J. Chem. Eng. Data, 56, 1622 (2011).

    Article  CAS  Google Scholar 

  18. M.M. Liang, Y. H. Hu, X. Liu, J. Guan, W. G. Yang and Y. Liu, J. Mol. Liq., 197, 35 (2014).

    Article  CAS  Google Scholar 

  19. X.Q. Zhou, J. S. Fan, N. Li, Z. X. Du, H. J. Ying, J. L. Wu, J. Xiong and J.X. Bai, Fluid Phase Equilib., 316, 26 (2012).

    Article  CAS  Google Scholar 

  20. D.M. Cristancho and F. Martínez, J. Mol. Liq., 200, 122 (2014).

    Article  CAS  Google Scholar 

  21. D.W. Wei, H. L. Li, Y. N. Li and J. Zhu, Fluid Phase Equilib., 316, 132 (2012).

    Article  CAS  Google Scholar 

  22. A. Maher, D. Croker, A. C. Rasmuson and B. K. Hodnett, J. Chem. Eng. Data, 55, 5314 (2010).

    Article  CAS  Google Scholar 

  23. Y. Yang, Q. Zhang, C. C. Cao, L.M. Cheng, Y. Shi, W. G. Yang and Y. H. Hu, Thermochim. Acta, 592, 52 (2014).

    Article  CAS  Google Scholar 

  24. A.R. Holguín, D.R. Delgado, F. Martínez and Y. Marcus, J. Solution Chem., 40, 1987 (2011).

    Article  Google Scholar 

  25. M.A. Ruidiaz, D.R. Delgado, F. Martínez and Y. Marcus, Fluid Phase Equilib., 299, 259 (2010).

    Article  CAS  Google Scholar 

  26. E. Tomlinson, Int. J. Pharm., 13, 115 (1983).

    Article  CAS  Google Scholar 

  27. E.A. Ahumada, D.R. Delgado and F. Martínez, Fluid Phase Equilib., 332, 120 (2012).

    Article  CAS  Google Scholar 

  28. J.Y. Zhang, P. P. Zhang, T.T. Liu, L. Zhou, L.Q. Zhang, R. Lin, G.D. Yang, W.R.Wang and Y. P. Li, J. Mol. Liq., 203, 98 (2015).

    Article  CAS  Google Scholar 

  29. D.R. Delgado, G. A. Rodríguez and F. Martínez, J. Mol. Liq., 177, 156 (2013).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237, China

    Zhijuan Huang, Chao Yu, Weilan Xue, Fucong Lin & Zuoxiang Zeng

Authors
  1. Zhijuan Huang
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  2. Chao Yu
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  3. Weilan Xue
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  4. Fucong Lin
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  5. Zuoxiang Zeng
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Correspondence to Zuoxiang Zeng.

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11814_2016_247_MOESM1_ESM.pdf

Solubility and dissolution thermodynamics of hexaquoiron(III)tris(p-toluenesulfonate) in (ethanol+water) binary mixtures within 291.15–333.15 K

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Huang, Z., Yu, C., Xue, W. et al. Solubility and dissolution thermodynamics of hexaquoiron(III)tris(p-toluenesulfonate) in (ethanol+water) binary mixtures within 291.15–333.15 K. Korean J. Chem. Eng. 34, 206–213 (2017). https://doi.org/10.1007/s11814-016-0247-7

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  • DOI: https://doi.org/10.1007/s11814-016-0247-7

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