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Laccase-catalyzed polymerization of m-phenylenediamine in aqueous buffers

  • Polymer, Industrial Chemistry
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Abstract

In the laccase-catalyzed polymerization of m-phenylendiamine in 100% aqueous buffers, the yield of the polymer was strongly influenced by various reaction conditions such as the solution pH and the concentrations of laccase and m-phenylendiamine. When the reaction was performed at pH 3, the 100% synthetic yield of the polymer was achieved. As pH increased, the yield of the polymer decreased significantly to only 4.4% at pH 9. Effects of solution pH on the morphology and the thermal stability of the polymer were investigated in detail. The polymer synthesized at pH 3 has the typical aggregated morphology of globular particles, but being synthesized at pH 7, it has non-aggregated morphology. The thermal stability of the polymer deteriorated as reaction pH increased.

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Authors and Affiliations

  1. Department of Chemical Engineering, College of Engineering, University of Ulsan, Ulsan, 44610, Korea

    Nasrin Raseda, Junghee Park & Keungarp Ryu

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  1. Nasrin Raseda
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  2. Junghee Park
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  3. Keungarp Ryu
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Correspondence to Keungarp Ryu.

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Raseda, N., Park, J. & Ryu, K. Laccase-catalyzed polymerization of m-phenylenediamine in aqueous buffers. Korean J. Chem. Eng. 33, 3011–3015 (2016). https://doi.org/10.1007/s11814-016-0163-x

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  • DOI: https://doi.org/10.1007/s11814-016-0163-x

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