Skip to main content
SpringerLink
Log in

Density, viscosity, refraction index and excess properties of binary mixtures of 1-(1-methypiperidinium-1-yl) pentane-(1-pyridinium) bis(trifluoromethane) sulfonamide with acetonitrile at T=(293.15 to 323.15) K

  • Separation Technology, Thermodynamics
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

The density, viscosity, and refractive index of a pure asymmetrical dicationic ionic liquid, 1-(1-methypiperidinium-1-yl) pentane-(1-pyridinium) bis(trifluoromethane)sulfonamide, and its binary mixtures with acetonitrile were investigated at temperatures from 293.15 K to 323.15 K over the entire range of composition at ambient pressure. From the experimental data, the excess molar volumes, dynamic viscosity deviations, and refractive index deviations were, respectively,calculated and correlated with Redlich-Kister-type polynomials. The temperature dependence of viscosity for pure ionic liquid was described by modified Vogel–Tammann-Fulcher (VTF) equation. The enthalpy and entropy of activation for viscous flow were obtained. The values of molar refraction and polarizability indicated that the dominant interactions between ionic liquids and acetonitrile were dipole-dipole molecular interactions. These thermodynamic properties were discussed in terms of nature of molecular interactions between the ionic liquid and acetonitrile.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Abo-Hamad, M. Hayyan, M. A. AlSaadi and M. A. Hashim, Chem. Eng. J., 273, 551 (2015).

    Article  CAS  Google Scholar 

  2. H. Du, X. Lin, Z. Xu and D. Chu, J. Mater. Sci., 50, 5641 (2015).

    Article  CAS  Google Scholar 

  3. M. Elnagdi, M. Moustafa, S. Al-Mousawi, R. Mekheimer and K. Sadek, Mol. Divers., 19, 625 (2015).

    Article  CAS  Google Scholar 

  4. Y. Li, C. Zhang, Y. Zhou, Y. Dong and W. Chen, Eur. Polym. J., 69, 441 (2015).

    Article  CAS  Google Scholar 

  5. D.R. MacFarlane, M. Forsyth, P.C. Howlett, J.M. Pringle, J. Sun, G. Annat, W. Neil and E. I. Izgorodina, Acc. Chem. Res., 40, 1165 (2007).

    Article  CAS  Google Scholar 

  6. R.D. Rogers and K.R. Seddon, Science, 302, 792 (2003).

    Article  Google Scholar 

  7. J. E. Bara, T.K. Carlisle, C. J. Gabriel, D. Camper, A. Finotello, D. L. Gin and R.D. Noble, Ind. Eng. Chem. Res., 48, 2739 (2009).

    Article  CAS  Google Scholar 

  8. M. Petkovic, K.R. Seddon, L.P.N. Rebelo and C. Silva Pereira, Chem. Soc. Rev., 40, 1383 (2011).

    Article  CAS  Google Scholar 

  9. S. Zhang, J. Sun, X. Zhang, J. Xin, Q. Miao and J. Wang, Chem. Soc. Rev., 43, 7838 (2014).

    Article  CAS  Google Scholar 

  10. X. Zhang, X. Zhang, H. Dong, Z. Zhao, S. Zhang and Y. Huang, Energy Environ. Sci., 5, 6668 (2012).

    Article  CAS  Google Scholar 

  11. F. D’Anna and R. Noto, Eur. J. Org. Chem., 2014, 4201 (2014).

    Article  Google Scholar 

  12. Z. Tang and S. Li, Curr. Opin. Solid State Mater. Sci., 18, 119 (2014).

    Article  CAS  Google Scholar 

  13. J. L. Anderson and D.W. Armstrong, Anal. Chem., 77, 6453 (2005).

    Article  CAS  Google Scholar 

  14. L. Zhang, H. Qi, Y. Wang, L. Yang, P. Yu and L. Mao, Anal. Chem., 86, 7280 (2014).

    Article  CAS  Google Scholar 

  15. T. Hamamoto, M. Okai and S. Katsuta, J. Phys. Chem. B, 119, 6317 (2015).

    Article  CAS  Google Scholar 

  16. Z. Long, Y. Zhou, W. Ge, G. Chen, J. Xie, Q. Wang and J. Wang, ChemPlusChem., 79, 1590 (2014).

    Article  CAS  Google Scholar 

  17. D. Wei-Li, J. Bi, L. Sheng-Lian, L. Xu-Biao, T. Xin-Man and A. Chak-Tong, Catal. Today, 233, 92 (2014).

    Article  Google Scholar 

  18. M. Atilhan, J. Jacquemin, D. Rooney, M. Khraisheh and S. Aparicio, Ind. Eng. Chem. Res., 52, 16774 (2013).

    Article  CAS  Google Scholar 

  19. I. Bahadur, T.M. Letcher, S. Singh, G.G. Redhi, P. Venkatesu and D. Ramjugernath, J. Chem. Thermodyn., 82, 34 (2015).

    Article  CAS  Google Scholar 

  20. F. Nabi, M. Malik, C. Jesudason and S. Al-Thabaiti, Korean J. Chem. Eng., 31, 1505 (2014).

    Article  CAS  Google Scholar 

  21. M. Sattari, A. Kamari, A. H. Mohammadi and D. Ramjugernath, J. Taiwan Inst. Chem. E., 52, 165 (2015).

    Article  CAS  Google Scholar 

  22. X. Zhang, F. Huo, X. Liu, K. Dong, H. He, X. Yao and S. Zhang, Ind. Eng. Chem. Res., 54, 3505 (2015).

    Article  Google Scholar 

  23. R. Majdan-Cegincara, M.T. Zafarani-Moattar and H. Shekaari, J. Mol. Liq., 203, 198 (2015).

    Article  CAS  Google Scholar 

  24. F. Chen, Z. Yang, Z. Chen, J. Hu, C. Chen and J. Cai, J. Mol. Liq., 209, 683 (2015).

    Article  CAS  Google Scholar 

  25. M.S. Rahman, M.A. Saleh, F.I. Chowdhury, M.S. Ahmed, M.M.H. Rocky and S. Akhtar, J. Mol. Liq., 190, 208 (2014).

    Article  CAS  Google Scholar 

  26. M. Geppert-Rybczynska, A. Heintz, J. K. Lehmann and A. Golus, J. Chem. Eng. Data, 55, 4114 (2010).

    Article  CAS  Google Scholar 

  27. H.-C. Ku and C.-H. Tu, J. Chem. Eng. Data, 43, 465 (1998).

    Article  CAS  Google Scholar 

  28. A.K. Nain, S. Ansari and A. Ali, J. Solution Chem., 43, 1032 (2014).

    Article  CAS  Google Scholar 

  29. R.K. Shukla, A. Kumar, N. Awasthi, U. Srivastava and V.S. Gangwar, Exp. Therm. Fluid Sci., 37, 1 (2012).

    Article  CAS  Google Scholar 

  30. J. Chen, L. Chen and Y. Xu, J. Chem. Thermodyn., 88, 110 (2015).

    Article  CAS  Google Scholar 

  31. A. Zhu, J. Wang and R. Liu, J. Chem. Thermodyn., 43, 796 (2011).

    Article  CAS  Google Scholar 

  32. M. Geppert-Rybczynska, J. K. Lehmann and A. Heintz, J. Chem. Thermodyn., 71, 171 (2014).

    Article  CAS  Google Scholar 

  33. M. Geppert-Rybczynska and M. Sitarek, J. Chem. Eng. Data, 59, 1213 (2014).

    Article  CAS  Google Scholar 

  34. J.-Y. Wu, Y.-P. Chen and C.-S. Su, J. Solution Chem., 44, 395 (2015).

    Article  CAS  Google Scholar 

  35. M. Anouti, A. Vigeant, J. Jacquemin, C. Brigouleix and D. Lemordant, J. Chem. Thermodyn., 42, 834 (2010).

    Article  CAS  Google Scholar 

  36. E. Gómez, N. Calvar, Á. Domínguez and E. A. Macedo, J. Chem. Thermodyn., 42, 1324 (2010).

    Article  Google Scholar 

  37. M. Anouti, J. Jacquemin and D. Lemordant, J. Chem. Eng. Data, 55, 5719 (2010).

    Article  CAS  Google Scholar 

  38. T. Zhao, J. Zhang, L. Li, B. Guo, L. Gao and X. Wei, J. Mol. Liq., 198, 21 (2014).

    Article  CAS  Google Scholar 

  39. A. Pal and A. Kumar, Fluid Phase Equilib., 143, 241 (1998).

    Article  CAS  Google Scholar 

  40. T. Zhao, J. Zhang, B. Guo, F. Zhang, F. Sha, X. Xie and X. Wei, J. Mol. Liq., 207, 315 (2015).

    Article  CAS  Google Scholar 

  41. I. Banik and M.N. Roy, J. Chem. Thermodyn., 63, 52 (2013).

    Article  CAS  Google Scholar 

  42. L. F. Sanz, J.A. González, I. García De La Fuente and J. C. Cobos, J. Mol. Liq., 172, 26 (2012).

    Article  CAS  Google Scholar 

  43. A. Chelkowski, Dielectric physics, Elsevier Science & Technology (1980).

    Google Scholar 

  44. H. Shekaari, M.T. Zafarani-Moattar and S. N. Mirheydari, J. Chem. Eng. Data, 60, 1572 (2015).

    Article  CAS  Google Scholar 

  45. G.R. Sunkara, M. M. Tadavarthi, V. K. Tadekoru, S. K. Tadikonda and S.R. Bezawada, J. Chem. Eng. Data, 60, 886 (2015).

    Article  CAS  Google Scholar 

  46. P. Diaz-Rodriguez, J. C. Cancilla, N.V. Plechkova, G. Matute, K.R. Seddon and J. S. Torrecilla, Phys. Chem. Chem. Phys., 16, 128 (2014).

    Article  CAS  Google Scholar 

  47. Y. Kayama, T. Ichikawa and H. Ohno, Chem. Commun., 50, 14790 (2014).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Henan Provincial Key Laboratory of Surface and Interface Science, Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration, Zhengzhou University of Light Industry, Zhengzhou, 450002, P. R. China

    Jun Wang, Hao Song, Xuzhao Yang, Wenyuan Zou, Yufei Chen, Shaochan Duan & Jun Sun

Authors
  1. Jun Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hao Song
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Xuzhao Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Wenyuan Zou
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yufei Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Shaochan Duan
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Jun Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jun Wang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, J., Song, H., Yang, X. et al. Density, viscosity, refraction index and excess properties of binary mixtures of 1-(1-methypiperidinium-1-yl) pentane-(1-pyridinium) bis(trifluoromethane) sulfonamide with acetonitrile at T=(293.15 to 323.15) K. Korean J. Chem. Eng. 33, 2460–2468 (2016). https://doi.org/10.1007/s11814-016-0104-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-016-0104-8

Keywords

Search

Navigation