Skip to main content
Log in

A facile synthetic route for Co3O4 nanoparticle/porous carbon composite as an efficient anode material for lithium-ion batteries

  • Fluidization, Particle Technology
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Facile synthesis and electrochemical performance of a Co3O4 nanoparticles/porous carbon composite used as an anode in Li-ion batteries is reported in this work. Co3O4 nanoparticles (5-10 nm in size) were embedded in a disordered porous carbon network using a simple template-free chemical method. The synthesized composite work well as an anode material for Li-ion batteries by delivering stable cycle life and highly reversible capacities of 480 mAhg-1 at 500mAg-1, which is higher than that of commercially available graphite electrodes and is comparable to values reported for Co3O4/graphene composites.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. F. Zhou, C. Z. Meng, F. Zhu, Q.Q. Li, C. H. Liu, S. S. Fan and K. L. Jiang, Nanotechnology, 21, 345701 (2010).

    Article  Google Scholar 

  2. C.T. Heish and J.Y. Lin, ECS Transactions, 13, 73 (2008).

    Article  Google Scholar 

  3. Y. Shan and L. Gao, Chem. Lett., 33, 1560 (2004).

    Article  CAS  Google Scholar 

  4. T. H. Yoon and Y. J. Park, Nanoscale Res. Lett., 7, 1 (2012).

    Article  Google Scholar 

  5. R. J. Wu, J.G. Wu, M. R. Yu, T. K. T. Sai and C. T. Yeh, Sen. Lett., 6, 848 (2008).

    Article  CAS  Google Scholar 

  6. J.W. Lang, X.B. Yan and Q.J. Xue, J. Power Sources, 196, 7841 (2011).

    Article  CAS  Google Scholar 

  7. N. Venugopal and W.-S. Kim, Korean J. Chem. Eng., 32, 1918 (2015).

    Article  CAS  Google Scholar 

  8. Y. Shan and L. Gao, Mat. Chem. Phy., 103, 206 (2007).

    Article  CAS  Google Scholar 

  9. B. J. Li, H.Q. Cao, J. Shao, G.Q. Li, M. Z. Qu and G. Yin, Inorg. Chem., 50, 1628 (2011).

    Article  CAS  Google Scholar 

  10. W.L. Yao, J.L. Wang, J. Yang and G.D. Du, J. Power Sources, 176, 369 (2008).

    Article  CAS  Google Scholar 

  11. Y. He, L. Huang, J. S. Cai, X.M. Zheng and S.G. Sun, Electrochim. Acta, 55, 1140 (2010).

    Article  CAS  Google Scholar 

  12. K. H. Park, D. Lee, J. Kim, J. Song, Y. M. Lee, H.-T. Kim and J.-K. Park, Nano Lett., 14, 4306 (2014).

    Article  CAS  Google Scholar 

  13. N. Du, H. Zhang, B. Chen, J.B. Wu, X.Y. Ma, Z. H. Liu, Y.Q. Zhang, D. Yang, X. H. Huang and J. P. Tu, Adv. Mater., 19, 4505 (2007).

    Article  CAS  Google Scholar 

  14. K. S.W. Sing, Pure Appl. Chem., 54, 2201 (1982).

    Article  Google Scholar 

  15. Z. S. Wu, W. C. Ren, L. Wen, L.B. Gao, J. P. Zhao, Z. P. Chen, G. M. Zhou, F. Li and H. M. Cheng, ACS Nano, 4, 3187 (2010).

    Article  CAS  Google Scholar 

  16. T. Zheng and J. R. Dahn, Applications of carbon in lithium-ion batteries, in Carbon Material of Advanced Technology, Pergamon Press, Oxford, UK (1999).

    Google Scholar 

  17. W. L. Yao, J. Yang, J. L. Wang and L. A. Tao, Electrochim. Acta, 53, 7326 (2008).

    Article  CAS  Google Scholar 

  18. H. Kim, D. H. Seo, S.W. Kim, J. Kim and K. Kang, Carbon, 49, 326 (2011).

    Article  CAS  Google Scholar 

  19. L. Zhuo, Y. Wu, J. Ming, L. Wang, Y. Yu, X. Zhang and F. Zhao, J. Mater. Chem. A, 1, 1141 (2013).

    Article  CAS  Google Scholar 

  20. P. Zhang, Z.P. Guo, Y. Huang, D. Jia and H.K. Liu, J. Power. Sources, 196, 6987 (2011).

    Article  CAS  Google Scholar 

  21. F. Hao, Z. Zhang and L. Yin, ACS Appl. Mater. Interfaces, 5, 8337 (2013).

    Article  CAS  Google Scholar 

  22. B.G. Choi, S. J. Chang, Y. B. Lee, J. S. Bae, H. J. Kim and Y. S. Huh, Nanoscale, 4, 5924 (2012).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Taekyung Yu.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Venugopal, N., Kim, WS. & Yu, T. A facile synthetic route for Co3O4 nanoparticle/porous carbon composite as an efficient anode material for lithium-ion batteries. Korean J. Chem. Eng. 33, 1500–1504 (2016). https://doi.org/10.1007/s11814-015-0274-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-015-0274-9

Keywords

Navigation