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Characteristics and intermolecular interaction of eutectic binary mixtures: Reline and Glyceline

  • Polymer, Industrial Chemistry
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Abstract

Deep Eutectic Solvents are promising greener and cheaper alternatives to ionic liquids. The applications involving these solvents depend largely on their physical and chemical properties. However, a DES may possess both desirable and undesirable properties for a certain application. In such situations, mixing two DESs, each possessing a unique set of properties, may yield one with a more suitable set of physical and chemical properties for the same application. In this work, the variation in the physical properties of Reline upon addition of Glyceline was investigated. While a positive deviation of excess molar volume was observed, a negative deviation of viscosity was recorded with the increase in Glyceline mol% indicating a disruption of the ordered structure of Reline. The highest deviation in both cases was observed at 30 mol% Glyceline. The physical properties measured were density, viscosity, pH, RI and conductivity. The Glyceline molar percentage studied was 0 to 100mol% while temperature was varied within the range of 20 °C to 80 °C.

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Authors and Affiliations

  1. Petroleum and Chemical Engineering Department, Sultan Qaboos University, Muscat, Oman

    Farouq Sabri Mjalli & Omar Umar Ahmed

Authors
  1. Farouq Sabri Mjalli
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  2. Omar Umar Ahmed
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Correspondence to Farouq Sabri Mjalli.

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Mjalli, F.S., Ahmed, O.U. Characteristics and intermolecular interaction of eutectic binary mixtures: Reline and Glyceline. Korean J. Chem. Eng. 33, 337–343 (2016). https://doi.org/10.1007/s11814-015-0134-7

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  • DOI: https://doi.org/10.1007/s11814-015-0134-7

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