Skip to main content
SpringerLink
Log in

Vapor-liquid equilibria for the binary mixtures of dimethyl ether (DME)+ dimethyl carbonate (DMC)

  • Separation Technology, Thermodynamics
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Isothermal vapor-liquid equilibrium data for the binary system of dimethyl ether (DME)+dimethyl carbonate (DMC) were measured at 303.15, 313.15, 323.15, 333.15 and 343.15 K using a circulation-type equilibrium apparatus with on-line gas chromatography analysis. The experimental data were correlated with the Peng-Robinson equation of state (PR-EoS) using the van der Waals one fluid mixing rule and the Peng-Robinson equation of state (PR-EoS) using the Wong-Sandler mixing rule combined with the NRTL excess Gibbs free energy model. This system showed negative deviation from Raoult’s law, and no azeotropic behavior was observed for all the temperature ranges studied here. Calculated results with PR-EoS using both two mixing rules showed good agreement with experimental data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P. Tundo and M. Selva, Accounts Chem. Res., 35, 706 (2002).

    Article  CAS  Google Scholar 

  2. Y. Ono, Appl. Catal. A-Gen., 155, 133 (1997).

    Article  CAS  Google Scholar 

  3. M. A. Pacheco and C. L. Marshall, Energy Fuel, 11, 2 (1997).

    Article  CAS  Google Scholar 

  4. Y. Ono, Catal. Today, 35, 15 (1997).

    Article  CAS  Google Scholar 

  5. A. -A. G. Shaikh and S. Sivaram, Chem. Rev., 96, 951 (1996).

    Article  CAS  Google Scholar 

  6. Y. Ein-Eli, Electrochem. Commun., 4, 644 (2002).

    Article  CAS  Google Scholar 

  7. D. Delledonne, F. Rivetti and U. Romano, Appl. Catal. A-Gen., 221, 241 (2001).

    Article  CAS  Google Scholar 

  8. U. Romano, R. Tesel and M. M. Mauri, Ind. Eng. Chem. Prod. Res. Dev., 19, 396 (1980).

    Article  CAS  Google Scholar 

  9. T. Matsuzaki and A. Nakamura, Catal. Surv. Asia, 1, 77 (1997).

    Article  CAS  Google Scholar 

  10. S. Fang and K. Fujimoto, Appl. Catal. A-Gen., 142, L1 (1996).

    Article  CAS  Google Scholar 

  11. C. Li and S. Zhong, Catal. Today, 82, 83 (2003).

    Article  CAS  Google Scholar 

  12. S. T. Hong, H. S. Park, J. S. Lim, Y. W. Lee, M. Anpo and J. D. Kim, Res. Chem. Intermed., 32, 737 (2006).

    Article  CAS  Google Scholar 

  13. S. T. Hong, H. S. Park, J. S. Lim and K. P. Yoo, Korean Chem. Eng. Res., 46, 550 (2008).

    CAS  Google Scholar 

  14. K. Tomishige, T. Sakaihori, Y. Ikeda and K. Fujimoto, Catal. Lett., 58, 225 (1999).

    Article  CAS  Google Scholar 

  15. K. Almusaiteer, Catal. Commun., 10, 1127 (2009).

    Article  CAS  Google Scholar 

  16. K. Tomishige and K. Kunimori, Appl. Catal. A-Gen., 237, 103 (2002).

    Article  CAS  Google Scholar 

  17. S. A. Kim, J. H. Yim, H. S. Byun and J. S. Lim, Korean J. Chem. Eng., 28, 2324 (2011).

    Article  CAS  Google Scholar 

  18. M. H. Lee, J. H. Yim, J. W. Kang and J. S. Lim, Fluid Phase Equilib., 318, 77 (2012).

    Article  CAS  Google Scholar 

  19. M. H. Lee, J. H. Yim and J. S. Lim, Korean J. Chem. Eng., 29, 1418 (2012).

    Article  CAS  Google Scholar 

  20. H. Cho, J. H. Yim and J. S. Lim, J. Supercrit. Fluids, 81, 7 (2013).

    Article  CAS  Google Scholar 

  21. H. Cho, J. E. Kim and J. S. Lim, Fluid Phase Equilib., 379, 52 (2014).

    Article  CAS  Google Scholar 

  22. D. -Y. Peng and D. B. Robinson, Ind. Eng. Chem. Fundam., 15, 59 (1976).

    Article  CAS  Google Scholar 

  23. S. K. Shibata and S. I. Sandler, Ind. Eng. Chem. Res., 28, 1893 (1989).

    Article  CAS  Google Scholar 

  24. J. Im, M. Kim, J. Lee and H. Kim, J. Chem. Eng. Data, 49, 243 (2004).

    Article  CAS  Google Scholar 

  25. D. S. H. Wong and S. I. Sandler, AIChE J., 38, 671 (1992).

    Article  CAS  Google Scholar 

  26. D. S. Abrams and J. M. Prausnitz, AIChE J., 21, 116 (1975).

    Article  CAS  Google Scholar 

  27. H. Renon and J. M. Prausnitz, AIChE J., 14, 135 (1968).

    Article  CAS  Google Scholar 

  28. M. Frenkel, R. D. Chirico, V. Diky, C. D. Muzny and A. F. Kazakov, NIST ThermoData Engine, NIST Standard Reference Database 103b-Pure Compounds, Binary Mixtures, and Chemical Reactions, Version 5.0, Standard Reference Data Program, National Institute of Standards and Technology, Gaithersburg, MD (2010).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemical and Biomolecular Engineering, Sogang University, C. P. O. Box 1142, Seoul, 100-611, Korea

    Wan Ju Jeong & Jong Sung Lim

Authors
  1. Wan Ju Jeong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jong Sung Lim
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jong Sung Lim.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jeong, W.J., Lim, J.S. Vapor-liquid equilibria for the binary mixtures of dimethyl ether (DME)+ dimethyl carbonate (DMC). Korean J. Chem. Eng. 33, 248–254 (2016). https://doi.org/10.1007/s11814-015-0129-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-015-0129-4

Keywords

Search

Navigation