Abstract
A new method for semi-synthesis of alkyl salicylaldoximes from cardanol is reported. Cardanol was extracted from decarboxylation process of cashew nutshell liquid, an abundant agricultural by-product. Molecular structures, physical and chemical properties of cardanol and oxime derivatives were confirmed by spectroscopic analyses. The produced oximes were successfully employed to extract copper(II) cation from aqueous copper salt solutions, offering a practical and economical pathway to effectively recover metals using agricultural by-products.
Similar content being viewed by others
References
A. M. Sastre and J. Szymanowski, Solvent Extr. Ion Exch., 22(5), 737 (2004).
M. J. Hudson, Hydrometallurgy, 9(2), 149 (1982).
D. S. Flett, J. Chem. Technol. Biotechnol., 74(2), 99 (1999).
K. S. Rao, N. B. Devi and B.R. Reddy, Hydrometallurgy, 57(3), 269 (2000).
D. Dreisinger, Hydrometallurgy, 83(1), 10 (2006).
Z. Lazarova and M. Lazarova, Solvent Extr. Ion Exch., 29(1), 128 (2011).
M. Amores, A. G. Coedo and F. J. Alguacil, Hydrometallurgy, 47(1), 99 (1997).
K. C. Sole and J. B. Hiskey, Hydrometallurgy, 37(2), 129 (1995).
J. Szymanowski, Hydroxyoximes and copper hydrometallurgy, CRC Press (1993).
J. H. P. Tyman and S. J. A. Iddenten, J. Chem. Technol. Biotechnol., 80(11), 1319 (2005).
A.G. Smith, P.A. Tasker and D.J. White, Coord. Chem. Rev., 241(1–2), 61 (2003).
J. Szymanowski and A. Borowiak-resterna, Crit. Rev. Anal. Chem., 22(1–2), 519 (1991).
P. R. Seidl, A. R. Menzel and R.O.P. Couto, Process for preparation of oximes and resulting products, U.S. Patent, 6,673,969 (2004).
J.H.P. Tyman, D. Wilczynski and M.A. Kashani, J. Am. Oil. Chem. Soc., 55(9), 663 (1978).
O. A. Attanasi, S. Berretta, C. Fiani, P. Filippone, G. Mele and R. Saladino, Tetrahedron, 62(25), 6113 (2006).
G. Vasapollo, G. Mele and R. Del Sole, Molecules, 16(8), 6871 (2011).
Food and Agriculture Organization of the United Nations. Available online: http://www.fao.org (Accessed 18-08-2012).
C. Voirin, S. Caillol, N.V. Sadavarte, B.V. Tawade, B. Boutevin and P. P. Wadgaonkar, Polym. Chem., 5(9), 3142 (2014).
M.A. Abd El-Ghaffar, Z.H. Abdel-Wahab and K.Z. Elwakeel, Hydrometallurgy, 96(1–2), 27 (2009).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hoang, A.S., Tran, T.H., Nguyen, H.N. et al. Synthesis of oxime from a renewable resource for metal extraction. Korean J. Chem. Eng. 32, 1598–1605 (2015). https://doi.org/10.1007/s11814-014-0348-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-014-0348-0