Abstract
Thermal regeneration of spent granular activated carbon (GAC) using sintering, air-activation, and deoxygenation was investigated to determine the potential of this method for overcoming the drawbacks of thermal regeneration. The conditions for each step were optimized. The physicochemical properties of four regenerated GACs were assessed using BET, SEM, and FT-IR analysis. The suitability of the regenerated GACs for liquid-phase applications was assessed by phenol adsorption, using adsorption isotherms, kinetics, and thermodynamics. Sintering increased the micropore area and volume of regenerated GAC by 19% and 16%, respectively, and controlled excessive burn-off, reducing it by 19%. Air-activation has economic advantages because the reaction time is 80% less than that for steamactivation. Deoxygenation improved the maximum adsorption capacity by 7%, although the number of micropores was reduced. Regenerated GAC by sintering, air-activation, and deoxygenation was best for liquid-phase applications; the results show that these steps help to overcome the drawbacks of thermal regeneration.
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E. Sabio, E. González, J. F. González, C.M. González-García, A. Ramiro and J. Gañan, Carbon, 42, 2285 (2004).
G. San Miguel, S. D. Lambert and N. J. D. Graham, Water Res., 35, 2740 (2001).
A. L. Cazetta, O. P. Junior, A. M.M. Vargas, A. P. da Silva, X. Zou, T. Asefa and V. C. Almeida, J. Anal. Appl. Pyrol., 101, 53 (2013).
R.M. Narbaitz and J. McEwen, Water Res., 46, 4852 (2012).
B. Lai, Y. X. Zhou and P. Yang, J. Chem. Technol. Biotechnol., 88, 474 (2013).
S. Román, B. Ledesma, A. Álvarez-Murillo and J. F. González, Fuel Process. Technol., 116, 358 (2013).
M. Franz, H. A. Arafat and N.G. Pinto, Carbon, 38, 1807 (2000).
D.W. Mazyck and F. S. Cannon, Carbon, 38, 1785 (2000).
D.W. Mazyck and F. S. Cannon, Carbon, 40, 241 (2002).
F. S. Cannon, Carbon, 32, 1285 (1994).
H. McLaughlin, Int. Sugar J., 107, 112 (2005).
K. S. Ryoo, T. D. Kim and Y. H. Kim, Bull. Korean Chem. Soc., 23, 817 (2002).
S. Román, B. Ledesma, A. Álvarez-Murillo and J. F. González, Fuel Process. Technol., 116 358 (2013).
P. Pendleton, S. H. Wu and A. Badalyan, J. Colloid Interface Sci., 246, 235 (2002).
KSM 1802, Test methods for activated carbon, Korea Industrial Standards, Korean Agency for Technology and Standards (2009).
Z. Zhang, W. Qu, J. Peng, L. Zhang, X. Ma, Z. Zhang and W. Li, Desalination, 249, 247 (2009).
B. H. Hameed and A.A. Rahman, J. Hazard. Mater., 160, 576 (2008).
A. T. M. Din, B. H. Hameed and A. L. Ahmad, J. Hazard. Mater., 161, 1522 (2009).
V. C. Srivastava, M.M. Swamy, I. D. Mall, B. Prasad and I.M. Mishra, Colloids Surf., A., 272, 89 (2006).
N. D. McCafferty, M. E. Callow, L. Hoggett, B. Holden and B. S.C. Leadbeater, Water Res., 34, 2199 (2000).
D. Clifford, S. Subramonian and T. J. Sorg, Environ. Sci. Technol., 20, 1072 (1986).
J. A. Moulijn, A. E.V. Diepen and F. Kapteijn, Appl. Catal. A- Gen., 212, 3 (2001).
C. H. Bartholomew, Appl. Catal. A-Gen., 212, 17 (2001).
J.H. Yang, S. M. Shih and P.H. Lin, Ind. Eng. Chem. Res., 51, 2553 (2012).
G. San Miguel, S. D. Lambert and N. J. D. Graham, Appl. Catal. BEnviron., 40, 185 (2003).
R. Yan, D. T. Liang, L. Tsen, Y. P. Wong and Y. K. Lee, Fuel, 83, 2401 (2004).
D. Savova, E. Apak, E. Ekinci, F. Yardim, N. Petrov, T. Budinova, M. Razvigorova and V. Minkova, Biomass Bioenergy, 21, 133 (2001).
D. Xin-hui, C. Srinivasakannan, W.W. Qu, W. Xin, P. Jin-hui and Z. Li-bo, Chem. Eng. Process., 53, 53 (2012).
B. Lai, Y. Zhang, Z. Chen, P. Yang, Y. Zhou and J. Wang, Appl. Catalysis. B-Environ., 144, 816 (2014).
B. Lai, Y. Zhou and P. Yang, Chem. Eng. J., 200–202, 10 (2012).
C. H. Cheng, J. Lehmann, J. E. Thies, S.D. Burton and M. H. Engelhard, Org. Geochem., 37, 1477 (2006).
I.H. Yoon, X. Meng, C. Wang, K.W. Kim, S. Bang, E. Choe and L. Lippincott, J. Hazard. Mater., 164, 87 (2009).
A. Swiatkowski, M. Pakula, S. Biniak and M. Walczyk, Carbon, 42, 3057 (2004).
S. Azizian, J. Colloid Interface Sci., 276, 47 (2004).
A.Y. Dursun and Ç. S. Kalayci, J. Hazard. Mater., 123, 151 (2005).
M. S. Bilgili, J. Hazard. Mater., 137, 157 (2006).
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Cho, JH., Kim, YS., Jeon, SB. et al. Improvement of thermal regeneration of spent granular activated carbon using air agent : Application of sintering and deoxygenation. Korean J. Chem. Eng. 31, 1641–1650 (2014). https://doi.org/10.1007/s11814-014-0125-0
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DOI: https://doi.org/10.1007/s11814-014-0125-0