Skip to main content
SpringerLink
Log in

Preparation and adsorption characters of Cu(II)-imprinted chitosan/attapulgite polymer

  • Environmental Engineering
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Using attapulgite (ATP) as matrix, chitosan (CS) as functional monomer, and introducing the surface ionimprinting concept, a new Cu(II)-IIP was prepared, and characterized by SEM, XRD and FT-IR. The adsorption of Cu(II) aqueous solution with Cu(II)-IIP was investigated by flame atomic adsorption spectroscopy (FAAS). The polymer has good selectivity for Cu(II) from competitive metal ions, and the selectivity coefficient of Cu(II) relation to Pb(II), Cd(II) was 78.45 and 82.44, respectively. Sorption equilibrium isotherms could be described by Langmuir and Freundlich models; the Freundlich isotherm has shown the best agreement with experimental data, and experimental value of maximum adsorption capacity for Cu(II) was 35.20 mg/g. The obtained thermodynamic parameter (ΔGo, ΔHo, ΔSo) showed that the Cu(II) adsorption process is a spontaneous and endothermic process. The kinetic data showed that pseudo-second-order kinetic model agrees very well with the dynamic behavior for the sorption of Cu(II) onto Cu(II)-IIP.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Celik and A. Demirba, Energy Sources, 27, 1167 (2005).

    Article  CAS  Google Scholar 

  2. A. Demirbas, Energy Edu. Sci. Technol., 5, 21 (2000).

    CAS  Google Scholar 

  3. A. Özer and H. Pirincci, J. Hazard. Mater., 137, 849 (2006).

    Article  CAS  Google Scholar 

  4. J. Wang and C. Chen, Biotechnol. Adv., 27, 195 (2009).

    Article  CAS  Google Scholar 

  5. B. Zhu, T. Fan and D. Zhang, J. Hazard. Mater., 153, 300 (2008).

    Article  CAS  Google Scholar 

  6. A. K. Meena, K. Kadirvelu, G. Mishra, C. Rajagopal and P. Nagar, J. Hazard. Mater., 150, 604 (2008).

    Article  CAS  Google Scholar 

  7. J. Shah, M. R. Jan, M. Sadia and H. Atta-ul-Haq, Korean J. Chem. Eng., 30, 706 (2013).

    Article  CAS  Google Scholar 

  8. H. Kalavathy, M. I. Regupathi, M.G. Pillai and L. R. Miranda, Colloids Surf., B: Biointerfaces, 70, 35 (2009).

    Article  CAS  Google Scholar 

  9. O. Amuda, A. A. Giwa and I. Bello, Biochem. Eng. J., 36, 174 (2007).

    Article  CAS  Google Scholar 

  10. Y. L. Kang, M.Y. Poon, P. Monash, S. Ibrahim and P. Saravanan, Korean J. Chem. Eng., 30, 1904 (2013).

    Article  CAS  Google Scholar 

  11. A.A. Mosa, A. El-Ghamry and P. Trüby, Water, Air, Soil Pollut., 217, 637 (2011).

    Article  CAS  Google Scholar 

  12. M. Rashed, Int. J. Environ. Waste Manage., 7, 175 (2011).

    Article  CAS  Google Scholar 

  13. A. Mittal, J. Mittal, A. Malviya, D. Kaur and V. Gupta, J. Colloid Interface Sci., 343, 463 (2010).

    Article  CAS  Google Scholar 

  14. A. Saeed, M. Sharif and M. Iqbal, J. Hazard. Mater., 179, 564 (2010).

    Article  CAS  Google Scholar 

  15. S. Khattri and M. Singh, J. Hazard. Mater., 167, 1089 (2009).

    Article  CAS  Google Scholar 

  16. V. K. Gupta, R. Jain, M. Shrivastava and A. Nayak, J. Chem. Eng. Data, 55, 5083 (2010).

    Article  CAS  Google Scholar 

  17. C. Pang, Y. Liu, X. Cao, R. Hua, C. Wang and C. Li, J. Radioanal. Nucl. Chem., 286, 185 (2010).

    Article  CAS  Google Scholar 

  18. Q. Fan, X. Tan, J. Li, X. Wang, W. Wu and G. Montavon, Environ. Sci. Technol., 43, 5776 (2009).

    Article  CAS  Google Scholar 

  19. Q. Fan, D. Shao, J. Hu, W. Wu and X. Wang, Surf. Sci., 602, 778 (2008).

    Article  CAS  Google Scholar 

  20. L. Chen and X. Gao, Appl. Radiat. Isot., 67, 1 (2009).

    Article  CAS  Google Scholar 

  21. Z. Niu, Q. Fan, W. Wang, J. Xu, L. Chen and W. Wu, Appl. Radiat. Isot., 67, 1582 (2009).

    Article  CAS  Google Scholar 

  22. S. Wang, D. Yu, Y. Huang and J. Guo, J. Appl. Polym. Sci., 119, 2065 (2011).

    Article  CAS  Google Scholar 

  23. G. Dotto and L. Pinto, Carbohydr. Polym., 84, 231 (2010).

    Article  CAS  Google Scholar 

  24. X.Y. Huang, X.Y. Mao, H. T. Bu, X.Y. Yu, G.B. Jiang and M. H. Zeng, Carbohydr. Polym., 83, 528 (2011).

    Article  CAS  Google Scholar 

  25. S. Kittinaovarat, P. Kansomwan and N. Jiratumnukul, Appl. Clay Sci., 48, 87 (2010).

    Article  CAS  Google Scholar 

  26. C.M. Futalan, C. C. Kan, M. L. Dalida, K. J. Hsien, C. Pascua and M.W. Wan, Carbohydr. Polym., 83, 528 (2011).

    Article  CAS  Google Scholar 

  27. V.M. Boddu, K. Abburi, J. L. Talbott and E.D. Smith, Environ. Sci. Technol., 37, 4449 (2003).

    Article  CAS  Google Scholar 

  28. B. Godlewska-Żyłkiewicz, B. Leoeniewska and I. Wawreniuk, Talanta, 83, 596 (2010).

    Article  CAS  Google Scholar 

  29. T. Prasada Rao, S. Daniel and J. Mary Gladis, TrAC, Trends Anal. Chem., 23, 28 (2004).

    Article  Google Scholar 

  30. M. Saraji and H. Yousefi, J. Hazard. Mater., 167, 1152 (2009).

    Article  CAS  Google Scholar 

  31. E. Zambrzycka, D. Roszko, B. Lesniewska, A. Z. Wilczewska and B. Godlewska-Zylkiewicz, Spectrochim. Acta — Part B A., 66, 508 (2011).

    Article  CAS  Google Scholar 

  32. J. B. Wu and Y. L. Yi, Korean J. Chem. Eng., 30, 1111 (2013).

    Article  CAS  Google Scholar 

  33. A. Kaewchada, C. Borvornpongsakul and A. Jaree, Korean J. Chem. Eng., 29, 1279 (2012).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemical Engineering, Huaiyin Institute of Technology, Key Laboratory for Palygorskite Science and Applied Technology of Jiangsu Province, Jiangsu Huai’an, 223003, China

    Yingying Shi, Qianghua Zhang, Liangdong Feng, Qingping Xiong & Jing Chen

Authors
  1. Yingying Shi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Qianghua Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Liangdong Feng
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Qingping Xiong
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Jing Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yingying Shi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shi, Y., Zhang, Q., Feng, L. et al. Preparation and adsorption characters of Cu(II)-imprinted chitosan/attapulgite polymer. Korean J. Chem. Eng. 31, 821–827 (2014). https://doi.org/10.1007/s11814-014-0004-8

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-014-0004-8

Keywords

Search

Navigation