Skip to main content
SpringerLink
Log in

Characterization and activity of V2O5/CeO2-MgO catalyst in the dehydrogenation of ethylbenzene to styrene

  • Catalysis, Reaction Engineering
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Supported vanadia catalyst was impregnated on CeO2-MgO and characterized by N2 adsorption, XRD, XPS, TPR and solid NMR. The vanadia species dispersed well on the support surface with vanadia content up to 10 wt%. At higher vanadia content, the non-active Mg3(VO4)2 was formed. Vanadium oxides existing on the support surface as tetrahedral vanadium were observed. An ethylbenzene conversion of 43% and styrene selectivity of 91% were obtained with the 10V2O5/CeO2-MgO catalyst.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. Cavani and F. Trifiro, Appl. Catal. A, 133, 219 (1995).

    Article  CAS  Google Scholar 

  2. A. Kotarba, W. Bieniasz, P. Kustrowski, K. Stadnicka and Z. Sojka, Appl. Catal. A, 407, 100 (2011).

    Article  CAS  Google Scholar 

  3. A. C. Oliveira, J. L.G. Fierro, A. Valentini, P. S. S. Nobre and M. C. Rangel, Catal. Today, 85, 49 (2003).

    Article  CAS  Google Scholar 

  4. B.Y. Jibril, A.Y. Atta, K. Melghit, Z.M. El-Hadi, A. H. Al-Muhtaseb, Chem. Eng. J., 193-194, 391 (2012).

    Article  CAS  Google Scholar 

  5. Y. Takita, Q. Xia, K. Kikutani, K. Soda, H. Takami, H. Nishiguchi and K. Nagaoka, J. Mol. Catal. A, 248, 61 (2006).

    Article  CAS  Google Scholar 

  6. D.Y. Hong, V. P. Vislovskiy, Y. K. Hwang, S. H. Jhung and J. S. Chang, Catal. Today, 131, 140 (2008).

    Article  CAS  Google Scholar 

  7. W. S. Chang, Y. Z. Chen and B. L. Yang, Appl. Catal. A, 124, 221 (1995).

    Article  CAS  Google Scholar 

  8. A. Guerrero-Ruiz, I. Rodriguez-Ramos, J. L.G. Fierro, V. Soenen, J.M. Herrmann and J.C. Volta, Stud. Surf. Sci. Catal., 72, 203 (1992).

    Article  CAS  Google Scholar 

  9. M.V. Martinez-Huerta, J. M. Coronado, M. Fernandez-Garcia, A. Iglesias-Juez, G. Deo, J. L.G. Fierro and M. A. Banares, J. Catal., 225, 240 (2004).

    Article  CAS  Google Scholar 

  10. J. Xu, L. C. Wang, Y.M. Liu, Y. Cao, H.Y. He and K. N. Fan, Catal. Lett., 133, 307 (2009).

    Article  CAS  Google Scholar 

  11. V. K. Nguyen, J. H. Park and C. H. Shin, Reac. Kinet. Mech. Cat., 107, 157 (2012).

    Article  CAS  Google Scholar 

  12. X. Gu, J. Ge, H. Zhang, A. Auroux and J. Shen, Thermochim. Acta, 451, 84 (2006).

    Article  CAS  Google Scholar 

  13. H. L. Abbott, A. Uhl, M. Baron, Y. Lei, R. J. Meyer, D. J. Stacchiola, O. Bondarchuk, S. Shaikhutdinov and H. J. Freund, J. Catal., 272, 82 (2010).

    Article  CAS  Google Scholar 

  14. A. M. Duarte de Farias, P. Bargiela, M.G. C. Rocha and M. A. Fraga, J. Catal., 260, 93 (2008).

    Article  CAS  Google Scholar 

  15. C. Hess and R. Schogl, Chem. Phys. Lett., 432, 139 (2006).

    Article  CAS  Google Scholar 

  16. J.M. Vohs, T. Feng and G. S. Wong, Catal. Today, 85, 303 (2003).

    Article  CAS  Google Scholar 

  17. G. S. Wong and J.M. Vohs, Surf. Sci., 498, 266 (2002).

    Article  CAS  Google Scholar 

  18. T. Blasco and J. M. Lopez Nieto, Colloids Surf. A, 115, 187 (1996).

    Article  CAS  Google Scholar 

  19. H. J. Chae, I. S. Nam, S.W. Ham and S. B. Hong, Appl. Catal. B, 53, 117 (2004).

    Article  CAS  Google Scholar 

  20. J.M. Miller and L. J. Lakshmi, J. Mol. Catal. A, 144, 451 (1999).

    Article  CAS  Google Scholar 

  21. E. F. Aboelfetoh, M. Fechtelkord and R. Pietschnig, J. Mol. Catal. A, 318, 51 (2010).

    Article  CAS  Google Scholar 

  22. M. Koranne, J. G. Goodwin and G. Marcelin, J. Catal., 148, 369 (1994).

    Article  CAS  Google Scholar 

  23. H. Zhao, S. Bennici, J. Cai, J. Shen and A. Auroux, J. Catal., 274, 259 (2010).

    Article  CAS  Google Scholar 

  24. E. P. Reddy and R. S. Varma, J. Catal., 221, 93 (2004).

    Article  CAS  Google Scholar 

  25. B.M. Reddy, K. N. Rao, G. K. Reddy and P. Bharali, J. Mol. Catal. A, 253, 44 (2006).

    Article  CAS  Google Scholar 

  26. N. R. Shiju, M. Anilkumar, S. P. Mirajkar, C. S. Gopinath, B. S. Rao and C. V. Satyanarayana, J. Catal., 230, 484 (2005).

    Article  CAS  Google Scholar 

  27. F. Klose, T. Wolff, H. Lorenz, A. Seidel-Morgenstern, Y. Suchorski, M. Piorkowska and H. Weiss, J. Catal., 247, 176 (2007).

    Article  CAS  Google Scholar 

  28. T. Blasco and J. M. Lopez Nieto, Appl. Catal. A, 157, 117 (1997).

    Article  CAS  Google Scholar 

  29. F. Tang, K. Zhuang, F. Yang, L. Yang, B. Xu, J. Qiu and Y. Fan, Chinese J. Catal., 33, 933 (2012).

    Article  CAS  Google Scholar 

  30. A. Wegrzyn, A. Rafalska-Lasocha, B. Dudek and R. Dziembaj, Catal. Today, 116, 74 (2006).

    Article  CAS  Google Scholar 

  31. M. Setnicka, R. Bulanek, L. Capek and P. Cicmanec, J. Mol. Catal. A, 344, 1 (2011).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemical Engineering, Chungbuk National University, Chungbuk, 361-763, Korea

    Van-Khoa Nguyen, Jung-Hyun Park & Chae-Ho Shin

  2. Institute of Chemical Technology, VAST, Hanoi, Vietnam

    Van-Khoa Nguyen

Authors
  1. Van-Khoa Nguyen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jung-Hyun Park
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chae-Ho Shin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Chae-Ho Shin.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nguyen, VK., Park, JH. & Shin, CH. Characterization and activity of V2O5/CeO2-MgO catalyst in the dehydrogenation of ethylbenzene to styrene. Korean J. Chem. Eng. 31, 582–586 (2014). https://doi.org/10.1007/s11814-013-0265-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-013-0265-7

Keywords

Search

Navigation