Abstract
We fabricated anode-supported solid oxide fuel cells using decalcomania paper. To investigate the changes in thickness of the component layer and electrical properties in a unit cell, the number of layers of cathodes and the electrolyte decalcomania paper is changed. As a result, the thickness of the electrolyte and cathode layer regularly increases with an increase in the number of decalcomania papers attached. In addition, when only one electrolyte decalcomania paper is attached to an anode support, a tight and dense 8 μm electrolyte layer is obtained. A unit cell with a cathode thickness of 120 μm to which decalcomania paper is attached nine times is shown to have an open circuit voltage (OCV) of 1.08 V and a maximum power density (MPD) of 902 mW cm−2 at 800 °C.
Similar content being viewed by others
References
N. Q. Minn, J. Am. Ceram. Soc., 76, 563 (1993).
Z.G. Lu, X. D. Zhou, D. Fisher, J. Templeton, J. Stevenson, N. J. Wu and A. Ignatiev, Electrochem. Commun., 12, 179 (2010).
S. D. Kim and S. H. Hyun, J. Power Sources, 139, 67 (2005).
B. C. H. Steele and A. Heinzel, Nature, 414, 345 (2001).
T. Ishihara, T. Shibayama, M. Honda, H. Nishiguchi and Y. Takita, J. Electrochem. Soc., 147, 1332 (2000).
S. de Souza, S. J. Visco and L. C. de Jonghe, Solid State Ionics, 98, 57 (1997).
S. Molin, W. Lewandowska-Iwaniak, B. Kusz, M. Gazda and P. Jasinki, J. Electroceram., 28, 80 (2012).
C. Wang, W. L. Worrell, S. Park, J.M. Vohs and R. J. Gorte, J. Electrochem. Soc., 148, A864 (2001).
T. Tsai, E. Perry and S. Barnett, J. Electrochem. Soc., 144, L130 (1997).
D. Simwonis, H. Thülen, F. J. Dias, A. Naoumidis and D. Stöver, J. Mater. Process. Technol., 92–93, 107 (1999).
S. J. Dillon, L. Helmick, H.M. Miller, L. Wilson, R. Gemman, V. Petrova, K. Barmark, G. S. Rohrer and P. A. Salvador, J. Am. Ceram. Soc., 94, 4045 (2011).
P. K. Srivastava, T. Quach, Y.Y. Duan, R. Donclson, S. P. Jiang and F. T. Ciaacchi, Solid State Ionics, 99, 311 (1997).
Z. Lu, J. Hardy, J. Templeton and J. Stevenson, J. Power Sources, 198, 90 (2012).
J. van Herle, A. J. MacEvoy and K.R. Thampi, Electrochim. Act, 41, 1447 (1996).
J. J. Choi, W. Qin, M. Liu and M. Liu, J. Am. Ceram. Soc., 94, 3340 (2011).
Z. Wang, J. Qian, J. Cao, S. Wang and T. Wen, J. Alloys Compounds, 437, 264 (2007).
A. A. E. Hassan, N. H. Menzler, G. Blass, M. E. Ali, H. P. Buchkremer and D. Stover, J. Mater. Sci., 37, 3467 (2002).
P. Ried, C. Lorenz, A. Brönstrup, T. Graule, N. H. Menzler, W. Sitte and P. Holtappels, J. European Ceram. Soc., 28, 1801 (2008).
L. Zhao, X. Huang, R. Zhu, Z. Lu, W. Sun, Y. Zhang, X. Ge, Z. Liu and W. Su, J. Phys. Chem. Solids, 69, 2019 (2008).
Y. Bai, J. Liu and C. Wang, J. Hydrog. Energy, 34, 7311 (2009).
J. Will, A. Mitterdorfer, C. Kleinlogel, D. Perednis and L. J. Gauckler, Solid State Ionics, 131, 79 (2000).
V.V. Kharton, F.M. B. Marques and A. Atkinson, Solid State Ionics, 174, 135 (2004).
T. Fukui, S. Ohara, M. Naito and K. Nogi, J. Nano. Res., 3, 171 (2001).
V. A. C. Haanappel, J. Mertens, D. Rutenbeck, C. Tropartz, W. Herzhof, D. Sebold and F. Tietz, J. Power Sources, 141, 216 (2005).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Cho, HR., Choi, BH., Roh, K.C. et al. Electrochemical properties related to the thickness control of the solid oxide fuel cell component layer using decalcomania paper. Korean J. Chem. Eng. 31, 50–55 (2014). https://doi.org/10.1007/s11814-013-0187-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-013-0187-4