Abstract
The reaction of m-xylylenediamine (mXD) with carbon dioxide was examined and its feasibility as a sequestration material of carbon dioxide was discussed. The reaction was monitored by using the FT-IR and gravitational methods, while the crystalline structure of the reaction product was investigated with elemental analysis, powder Xray diffraction, single crystallography, and 13C MAS NMR spectroscopy. Even at ambient temperature, mXD reacted with carbon dioxide of low partial pressure in the atmosphere and produced a 1: 1 molar adduct which appeared as a white crystalline material. The hydrogen bonds that formed between the adduct molecules resulted in the formation of a stable crystal. The sequestration capacity of mXD was very great, ∼280 mg g mXD −1 below 50 °C. An adsorbent prepared by dispersing mXD on silica was capable of capturing carbon dioxide, but it could be regenerated by evacuating at 25 °C.
Similar content being viewed by others
References
M. F. Akorede, H. Hizam, M. Z.A. Ab Kadir, I. Aris and S. D. Buda, Renew. Sust. Energy Rev., 16, 2747 (2012).
S. Choi, J.H. Drese and C.W. Jones, ChemSusChem, 2, 796 (2009).
B. Beck, J. Garrett, I. Havercroft, D. Wagner and P. Zakkour, Energy Procedia, 4, 5933 (2011).
J. Lipponen, K. Burnard, B. Beck, J. Gale and B. Pegler, Energy Procedia, 4, 5752 (2011).
K. Sumida, D. L. Rogow, J. A. Mason, T.M. McDonald, E. D. Bloch, Z. R. Herm, T.-H. Bae and J. R. Long, Chem. Rev., 112, 724 (2012).
C. A. Scholes, S. E. Kentish and G.W. Stevens, Recent Pat. Chem. Eng., 1, 52 (2008).
T. Jockenhoevel, R. Schneider and H. Rode, Energy Procedia, 1, 1043 (2009).
A. Samanta, A. Zhao, G. K. H. Shimizu, P. Sarkar and R. Gupta, Ind. Eng. Chem. Res., 51, 1438 (2012).
C. F. Song, Y. Kitamura and S.H. Li, Appl. Energy, 98, 491 (2012).
Y. Cho, S.-C. Nam, Y.-I. Yoon, S. Moon and I.H. Baek, Appl. Chem. Eng., 21, 195 (2010).
W.-J. Son, J.-S. Choi and W.-S. Ahn, Micropor. Mesopor. Mater., 113, 31 (2008).
A. L. Chaffee, G. P. Knowles, Z. Liang, J. Zhang, P. Xiao and P. A. Webley, Int. J. Greenhouse Gas Con., 1, 11 (2007).
O.M. Al-Azzawi, C. M. Hofmann, G. A. Baker and S. N. Baker, J. Colloid Inter. Sci., 385, 154 (2012).
Y. Zhao, Y. Shen and L. Bai, J. Colloid Inter. Sci., 379, 94 (2012).
C. Wu, J. Wang, P. Chang, H. Cheng, Y. Yu, Z. Wu, D. Dong and F. Zhao, Phys. Chem. Chem. Phys., 14, 464 (2012).
S. Midatera and Y. Kanda, Japan Patent, 2005–272535 (2005).
B. Sylvain, D. Bruno, C. P. Louis, J. Marc, M. Sandrine and M. Regis, French Patent, 2957268 (2010).
J. S. Jung, J.W. Park and G. Seo, Appl. Catal. A, 288, 149 (2005).
Gaussian 09, Revision B.01, Gaussian, Inc., Wallingford CT (2009).
Y. Zhao and D. G. Truhlar, Theor. Chem. Acc., 120, 215 (2008).
Y. Zhao and D.G. Truhlar, Accounts Chem. Res., 41, 157 (2008).
S. E. Wheeler and K.N. Houk, J. Chem. Theory Comput., 6, 395 (2010).
B. K. Rao, P. Jena, S. Burkart, G. Ganteför and G. Seifert, Phys. Rev. Lett., 86, 692 (2001).
D. L. Pavia, G.M. Lampman, G. S. Kriz and J. A. Vyvyan, Introduction to Spectroscopy, 4th Ed., Cengage Learning, Canada (2010).
Y.-W. Park, I.-H. Baek, S.-D. Park, J.-W. Lee and S.-J. Park, Korean J. Chem. Eng. Res., 45, 573 (2007).
T. M. McDonald, W. R. Lee, J. A. Mason, B. M. Wiers, C. S. Hong and J. R. Long, J. Am. Chem. Soc., 134, 7056 (2012).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lee, S.W., Lim, S.W., Park, S.H. et al. Sequestration of carbon dioxide by m-xylylenediamine with forming a crystalline adduct. Korean J. Chem. Eng. 30, 2241–2247 (2013). https://doi.org/10.1007/s11814-013-0171-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11814-013-0171-z