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Synthesis of single azo disperse dye containing double ester and determination of crystal structure

  • Environmental Engineering
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Abstract

The synthesis, crystal structure analysis and characterization of a monoazo dye, 4-((2,6-dichloro-4-nitro phenyl)azo)-N-(diacetyl oxygen ethyl)aniline, are reported. The dye crystallised in the triclinic system, space group P-1 with a=8.1663(3) Å, b= 9.4222(3) Å, c=15.4694(5) Å, α=78.9130(10)°, β=75.019(2)°, γ=70.787(2)°, V=1078.26(6) Å3 and Z=2. There is only one molecule in the asymmetric unit. The dihedral angle between the two phenyl rings is 53.4 Å. In the crystal structure, intermolecular C-H…O hydrogen bonds link the molecules into centrosymmetric dimers, forming R22(30) ring motifs, in which they may be effective in the stabilization of the structure. Between the phenyl rings, the π…π stacking (interactions) may further stabilize the structure.

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Authors and Affiliations

  1. College of Food Science and Light Industry, Nanjing University of Technology, Nanjing, Jiangsu, 211816, China

    Zhengyu Zhang, Hong Xu & Chunling Zheng

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  1. Zhengyu Zhang
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  2. Hong Xu
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  3. Chunling Zheng
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Correspondence to Hong Xu.

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Zhang, Z., Xu, H. & Zheng, C. Synthesis of single azo disperse dye containing double ester and determination of crystal structure. Korean J. Chem. Eng. 30, 2219–2222 (2013). https://doi.org/10.1007/s11814-013-0167-8

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  • DOI: https://doi.org/10.1007/s11814-013-0167-8

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