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Ionic liquids as novel surfactants for potential use in enhanced oil recovery

  • Polymer, Industrial Chemistry, Fluidization, Particle Technology
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Abstract

The screening and use of benign chemicals for enhanced oil recovery (EOR) applications is important because of their properties and relationship to the embedded fluids. We investigated a special type of ionic liquids (ILs) called “Ammoeng” for potential use in surfactant EOR to replace the currently used surfactants that have many disadvantages. The interfacial tension (IFT) between a representative oil sample from Saudi reservoirs and solutions of Ammoeng™ ILs at different concentrations in 10 wt% NaCl aqueous solutions were measured as a function of temperature. It was found that the IFT values decreased with the increase of IL concentration. However, the effect of temperature on the IFT depended on the type of IL. Ammoeng™ 102 gave the lowest IFT values among the screened ILs. The comparison of the results to those resulting from TritonX100, a commercially used surfactant, showed that the IFT values using Ammoeng™ 102 were smaller than the corresponding values when TritonX100 was used at the same conditions. The possibility of having a synergetic effect when using a mixture of Ammoeng™ 102 and Triton X 100 was also investigated. The results showed that the IFT values depended on the total concentration, the surfactant to IL mass ratio, and the temperature.

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References

  1. L.W. Lake, Enhanced Oil Recovery, Prentice-Hall, New Jersey, 1st Ed. (1996).

    Google Scholar 

  2. A. Carcoana, Applied Enhanced Oil Recovery, Prentice-Hall, New Jersey (1992).

    Google Scholar 

  3. Worldwide EOR survey, Oil Gas J., 94, 45 (1996).

    Google Scholar 

  4. Worldwide EOR survey, Oil Gas J., 102, 53 (2004).

    Google Scholar 

  5. Worldwide EOR survey, Oil Gas J., 104, 45 (2006).

    Google Scholar 

  6. EOR/heavy oil survey: 2010 worldwide EOR survey, Oil Gas J., 108 (2010).

    Google Scholar 

  7. X. Xie, W.W. Weiss, Z. Tong, N.R. Morrow, SPE J, 10, 276 (2005).

    CAS  Google Scholar 

  8. J. F.B. Pereira, E. J. Gudiña, R. Costa, R. Vitorino, J. A. Teixeira, J. A. P. Coutinho and L. R. Rodrigues, Fuel, 111, 259 (2013).

    Article  CAS  Google Scholar 

  9. I. M. Banat, R. S. Makkar and S. S. Cameotra, Appl. Microbiol. Biotechnol., 53, 495 (2000).

    Article  CAS  Google Scholar 

  10. E. C. Donaldson, G.V. Chilingarian and T. F. Yen, Enhanced Oil Recovery, I: fundamentals and analyses vol. 1: Elsevier Science (1985).

    Google Scholar 

  11. R. Needham and P. Doe, Journal of Petroleum Technology, 39, 1503 (1987).

    Article  CAS  Google Scholar 

  12. B. Gao and M. Sharma, “A new family of anionic surfactants for EOR applications,” in SPE Annual Technical Conference and Exhibition (2012).

    Google Scholar 

  13. M. Simjoo, T. Rezaei, A. Andrianov and P. L. J. Zitha, Colloids Surf. A: Physicochemical and Engineering Aspects, In Press, Available online 31 May 2013, http://dx.doi.org/10.1016/j.colsurfa.2013.05.062.

  14. A. Gurgel, M. C. P. A. Moura, T. N. C. Dantas, E. L. Barros Neto and A. A. Dantas Neto, Braz. J. Pet. Gas, 2, 83 (2008).

    Google Scholar 

  15. M. Ferrari, F. Ravera, M. Viviani and L. Liggieri. Colloids Surf. A: Physicochemical and Engineering Aspects, 249, 63 (2004).

    Article  CAS  Google Scholar 

  16. F. Ravera, M. Ferrari, E. Santini and L. Liggieri. Advances in Colloid Interface Sci., 117, 75 (2005).

    Article  CAS  Google Scholar 

  17. F. D. S. Curbelo, V. S. Santanna, E. L. Barros Neto, T.V. Dutra Junior, T. N. Castro Dantas, A. A. Dantas Neto and A. I. C. Garnica, Colloids Surf. A: Physicochemical and Engineering Aspects, 293, 1 (2007).

    Article  CAS  Google Scholar 

  18. F. D. S. Curbelo, A. I. C. Garnica, E. L. Barros Neto, T. N. Castro Dantas and A. I. C. Garnica, Brazilian Journal of Petroleum and Gas., 2, 9 (2008).

    Google Scholar 

  19. I. Fjelde, T. Austad and J. Milter, Journal of Petroleum Science and Engineering, 13, 193 (1995).

    Article  CAS  Google Scholar 

  20. P. Somasundaran and L. Zhang, Journal of Petroleum Science and Engineering, 52, 198 (2006).

    Article  CAS  Google Scholar 

  21. R. N. Healy and R. L. Reed, Society of Petroleum Engineers Journal, 14, 491 (1974).

    Article  CAS  Google Scholar 

  22. A. A. Dantas Neto, T. N. C. Dantas, M. C. P. A. Moura, E. L. Barros Neto and A. Gurgel, In: Microemulsions: Properties and Applications, Monzer Fanum (Ed.), CRC Press, 411 (2008).

  23. T. Austad, I. Fjelde, K. Veggeland and K. Taugbol, Journal of Petroleum Science and Engineering, 10, 255 (1994).

    Article  CAS  Google Scholar 

  24. T. Austad, I. Fjelde and K. Veggeland, Journal of Petroleum Science and Engineering, 12, 1 (1994).

    Article  CAS  Google Scholar 

  25. T. Austad and K. Taugbol, Colloids Surf. A: Physicochemical and Engineering Aspects, 101, 87 (1995).

    Article  CAS  Google Scholar 

  26. T. Austad and K. Taugbol, Colloids Surf. A: Physicochemical and Engineering Aspects, 103, 73 (1995).

    Article  CAS  Google Scholar 

  27. N. R. Morrow and G. Mason, Current Opinion in Colloid Interface Sci., 6, 321 (2001).

    Article  CAS  Google Scholar 

  28. T. Babadagli, J. Colloid Interface Sci., 246, 203 (2002).

    Article  CAS  Google Scholar 

  29. T. Babadagli, Journal of Petroleum Science and Engineering, 37, 25 (2003).

    Article  CAS  Google Scholar 

  30. T. Babadagli and T. Boluk, J. Colloid Interface Sci., 282, 162 (2005).

    Article  CAS  Google Scholar 

  31. V.C. Santanna, A.C.M. Silva, H.M. Lopes and F. A. Sampaio Neto, Journal of Petroleum Science and Engineering, 105, 116 (2013).

    Article  CAS  Google Scholar 

  32. X. P. Li, L. Yu, Y. Q. Ji, B. Wu, G. Z. Li and L. Q. Zheng, Chin. Chem. Lett., 20, 1251 (2009).

    Article  CAS  Google Scholar 

  33. M. A. Ahmadi and S. R. Shadizadeh, Fuel, 104, 462 (2013).

    Article  CAS  Google Scholar 

  34. J. Yang, W. H. Qiao, Z. S. Li and L.B. Cheng, Fuel, 84, 1607 (2005).

    CAS  Google Scholar 

  35. Z.C. Bi, W. S. Liao and L.Y. Qi, Appl. Surf. Sci., 221, 25 (2004).

    Article  CAS  Google Scholar 

  36. J. Zhang, G. Li, F. Yang, N. Xu, H. Fan, T. Yuan and L. Chen, Appl. Surf. Sci., 259, 774 (2012).

    Article  CAS  Google Scholar 

  37. T. Welton, Chemical Reviews, 99, 2071 (1999).

    Article  CAS  Google Scholar 

  38. C. Z. Liu, F. Wang, A. R. Stiles and C. Guo, Appl. Energy, 92, 406 (2012).

    Article  CAS  Google Scholar 

  39. H. Gao, C. Guo, J. Xing and J. H. ZhaoLiu, Green Chem., 12, 1220 (2010).

    Article  CAS  Google Scholar 

  40. W. M. Nelson, Green solvents for chemistry: Perspectives and practice, Oxford University Press (2003).

    Google Scholar 

  41. Y. Jiang, H. Xia, C. Guo, I. Mahmood and H. Liu, Appl. Biochem. Biotechnol. 144, 145 (2008).

    Article  CAS  Google Scholar 

  42. R. Hagiwara, T. Nohira, K. Matsumoto and Y. Tamba, Electrochemical and Solid-State Lett., 8, A231 (2005).

    Article  CAS  Google Scholar 

  43. A. Balducci, W. A. Henderson, M. Mastragostino, S. Passerini, P. Simon and F. Soavi, Electrochim. Acta, 50, 2233 (2005).

    Article  CAS  Google Scholar 

  44. Y. Jiang, Chem. Eng. J., 147, 22 (2009).

    Article  CAS  Google Scholar 

  45. Y. Jiang, H. Xia, C. Guo, I. Mahmood and H. Liu, Ind. Eng. Chem. Res., 46, 6303 (2007).

    Article  CAS  Google Scholar 

  46. Y. Jiang, C. Guo, H. Xia, I. Mahmood, C. Liu and H. Liu, J. Mol. Catal. B: Enzym., 58, 103 (2009).

    Article  CAS  Google Scholar 

  47. X. Hou, F. Zhou, Y. Sun and W. Liu, Mater. Lett., 61, 1789 (2007).

    Article  CAS  Google Scholar 

  48. S. H. Ha, M. N. Lan, S. H. Lee, S.M. Hwang and Y. M. Koo, Enzym. Microb. Technol., 41, 480 (2007).

    Article  CAS  Google Scholar 

  49. A. A. M. Lapis, L. F. Oliveira, B. A. D. Neto and J. Dupont, Chem. Sus. Chem., 1, 759 (2008).

    Article  CAS  Google Scholar 

  50. J. D Holbrey and R.D. Rogers, Green industrial applications of ionic liquids: Technology review, ACS Symposium Series, 818, 446 (2002).

    Article  CAS  Google Scholar 

  51. B. Weyershausen and K. Lehmann, Green Chem., 7, 15 (2005).

    Article  CAS  Google Scholar 

  52. C. Kohlmann, S. Leuchs, L. Greiner and W. Leitnera, Green Chem., 13, 1430 (2011).

    Article  CAS  Google Scholar 

  53. M. S. Manic, V. Najdanovic-Visak M. N. da Ponte and Z. P. Visak, AIChE J., 57, 1344 (2011).

    Article  CAS  Google Scholar 

  54. Z. Guo, D. Kahveci, B. Ozcelik and X. Xu, New Biotechnology, 26, 37 (2009).

    Article  CAS  Google Scholar 

  55. C. Kohlmann, N. Robertz, S. Leuchs, Z. Dogan, S. Lütz, K. Bitzer, S. Na’amnieh and L. Greiner, J. Mol. Catal. B: Enzym., 68, 147 (2011).

    Article  CAS  Google Scholar 

  56. C. Rodriguez, G. Gonzalo, M.W. Fraaije and V. Gotor, Green Chem., 12, 2255 (2010).

    Article  CAS  Google Scholar 

  57. J.C. Ribot, C. Guerrero-Sanchez, R. Hoogenbooma and U. S. Schubert, J. Mater. Chem., 20, 8279 (2010).

    Article  CAS  Google Scholar 

  58. B. L. A. Prabhavathi Devi, Z. Guol and X. Xu, Food and Natural Products, 57, 1628 (2011).

    CAS  Google Scholar 

  59. S. Dreyera, P. Salimb and U. Kragl, Biochem. Eng. J., 46, 176 (2009).

    Article  Google Scholar 

  60. A. E. Jimenez and M. D. Bermudez, Tribol. Lett., 33, 111 (2009).

    Article  CAS  Google Scholar 

  61. S. Keskin, D. Kayrak-Talay, U. Akman and O. Hortacsu, J. Supercrit. Fluids, 43, 150 (2007).

    Article  CAS  Google Scholar 

  62. R. A. Sheldon, R.M. Lau, F. Sorgedrager, K. Rantwijk and R. Seddon, Green Chem., 4, 147 (2002).

    Article  CAS  Google Scholar 

  63. B. Jastorff, R. Stormann, J. Ranke, K. Molter, F. Stock, B. Oberheitmann, W. Hoffmann, J. Hoffmann, M. Nüchter, B. Ondruschka and J. Filser, Green Chem., 5, 136 (2003).

    Article  CAS  Google Scholar 

  64. D. R. MacFarlane, Aust. J. Chem., 57, 111 (2004).

    Article  CAS  Google Scholar 

  65. J. S. Wilkes, Mol. Catal. A-Chem., 214, 11 (2004).

    Article  CAS  Google Scholar 

  66. L. Cammarata, S. G. Kazarian, P. A. Salter and T. Welton, Phys. Chem. Chem. Phys., 23, 5192 (2001).

    Article  Google Scholar 

  67. H. C. Hodges and J. H. Sterner, Combined tabulation of toxicity classes, in: W. S. Spector (Ed.), Handbook of Toxicilogy, W. B. Saunders Company, Philadelphia (1956).

  68. E. J. Maginn, Research: Ionic Liquids, www.nd.edu/ed/Research/ILtoxicology.html (accessed 19 April, 2007).

  69. A. S.Wells and V. T. Coombe, Org. Process Res. Dev., 10, 794 (2006).

    Article  Google Scholar 

  70. R. P. Swatloski, J. D. Holbrey, S.B. Memon, G. A. Caldwell, K. A. Caldwell and R. D. Rogers, Chem. Commun., 668 (2004).

    Google Scholar 

  71. R. J. Bernott, E. E. Kennedy and G. A. Lamberti, Environ. Toxicol. Chem., 24, 1759 (2005).

    Article  Google Scholar 

  72. T. D. Landry, K. Brooks, D. Poche and M. Woolhiser, Bull. Environ. Contam. Toxicol., 74, 559 (2005).

    Article  CAS  Google Scholar 

  73. C. Pretti, C. Chiappe, D. Pieraccini, M. Gregori, F. Abramo, G. Monnia and L. Intorre, Green Chem., 8, 238 (2006).

    Article  CAS  Google Scholar 

  74. P. Stepnowski, A. Muller, P. Behrend, J. Ranke, J. Hoffmann and B. Jastorff, J. Chromatogr. A, 993, 173 (2003).

    Article  CAS  Google Scholar 

  75. N. Gathergood, M. T. Garcia and P. J. Scammells, Green Chem., 6, 166 (2004).

    Article  CAS  Google Scholar 

  76. N. Gathergood and P. J. Scammells, Aust. J. Chem., 55, 557 (2002).

    Article  CAS  Google Scholar 

  77. E. B. Carter, S. L. Culver, P.A. Fox, R.D. Goode, I. Ntai, M. D. Tickell, R. K. Traylor, N.W. Hoffman and J. H. Davis Jr., Chem. Commun., 630 (2004).

    Google Scholar 

  78. M. T. Garcia, N. Gathergood and P. J. Scammells, Green. Chem., 7, 9 (2005).

    Article  CAS  Google Scholar 

  79. G.-H. Tao, L. He, N. Sun and Y. Kou, Chem. Commun., 3562 (2005).

    Google Scholar 

  80. N. Gathergood, P. J. Scammells and M. T. Garcia, Green Chem., 8, 156 (2006).

    Article  CAS  Google Scholar 

  81. G.-H. Tao, L. He, W.-S. Liu, L. Xu, W. Xiong, T. Wang and Y. Kou, Green Chem., 8, 639 (2006).

    Article  CAS  Google Scholar 

  82. A. Lacrama, M.V. Putz and V. Ostafe, Int. J. Mol. Sci., 8, 842 (2007).

    Article  CAS  Google Scholar 

  83. J. C. Ribot, C. Guerrero-Sanchez, R. Hoogenboom and U. S. Schubert, Chem. Commun., 46, 6971 (2010).

    Article  CAS  Google Scholar 

  84. A. Bosmann, Ionic Liquids Today, 6, 3 (2006).

    Google Scholar 

  85. R. F. M. Frade, A. A. Rosatella, C. S. Marques, L. C. Branco, P. S. K., N. M. M. Mateus, C. A.M. Afonso and C. M. M. Duarte, Green Chem., 11, 1660 (2009).

    Article  CAS  Google Scholar 

  86. B. Peric, E. Martí, J. Sierra, R. Cruañas and M. A. Garau, Green chemistry: Ecotoxicity and biodegradability of ionic liquids, in Recent Advances in Pharmaceutical Sciences II, 2012: 89–113, Ed.: D. Muñoz-Torrero, D. Haro and J. Vallès, 89 (2012).

    Google Scholar 

  87. G. Dumitrescu, L. Petculescu-Ciochin, I. Bencsik, D. Dronca and L. Boca Aquaculture, Aquarium, Conservation & Legislation International Journal of the Bioflux Society, 3, 404 (2010).

    Google Scholar 

  88. S. Lago, H. Rodríguez, M. K. Khoshkbarchi, A. Soto and A. Arce, RSC Adv., 2, 9392 (2012).

    Article  CAS  Google Scholar 

  89. A. Z. Hezave, S. Dorostkar, S. Ayatollahi, M. Nabipour and B. Hemmateenejad, Colloids Surf. A: Physicochemical and Engineering Aspects, 421, 63 (2013).

    Article  CAS  Google Scholar 

  90. A. Z. Hezave, S. Dorostkar, S. Ayatollahi, M. Nabipour and B. Hemmateenejad, J. Mol. Liquids, 187, 83 (2013).

    Article  CAS  Google Scholar 

  91. W. Karnanda, Master Thesis, King Saud University, Riyadh (2011).

  92. W. Karnanda, M. S. Benzagouta, A. AlQuraishi and M. M. Amro, Arab. J. Geosci. (2012), DOI:10.1007/s12517-012-0605-7.

    Google Scholar 

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Benzagouta, M.S., AlNashef, I.M., Karnanda, W. et al. Ionic liquids as novel surfactants for potential use in enhanced oil recovery. Korean J. Chem. Eng. 30, 2108–2117 (2013). https://doi.org/10.1007/s11814-013-0137-1

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