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Poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-dimethylacrylamide] brushes grafted onto siliceous support for preconcentration and determination of cobalt (II) in human plasma and environmental samples

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Abstract

A chelating matrix prepared by surface grafting of polymer containing a functional monomer, poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-methylacrylamide] (poly(AGE/IDA-co-DMAA) onto a modified silica. The silica surface was modified by silylation with 3-mercaptopropyltrimethoxysilane followed by graft polymerization. Monomer of allyl glycidyl ether-iminodiacetic acid was synthesized by reaction of allyl glycidyl ether with iminodiacetic acid. The chelating sorbent can be reused for 15 cycles of sorption-desorption without any significant change in sorption capacity. The profile of cobalt uptake on the sorbent reflects good accessibility of chelating sites in poly(AGE/IDA-co-DMAA)-grafted silica gel. The equilibrium adsorption data of Co(II) on modified sorbent were analyzed by Langmuir, Freundlich, Temkin and Redlich-Peterson models. The method was applied for cobalt ions determination in human plasma and sea water sample with satisfactory results.

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Authors and Affiliations

  1. Department of Chemistry, Central Tehran Branch, Islamic Azad University, Shahrak Ghods, Simaye Iran, Tehran, Iran

    Homayon Ahmad Panahi, Mahshid Nikpour Nezhati & Rohollah Abedini Kashkoieh

  2. Department of Chemistry, Varamin (Pishva) Branch, Islamic Azad University, Shahrak Naghsh Jahan, Pishva, Iran

    Elham Moniri

  3. DSM Food Specialties B.V., Delft, The Netherlands

    Igor Yu. Galaev

Authors
  1. Homayon Ahmad Panahi
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  2. Mahshid Nikpour Nezhati
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  3. Rohollah Abedini Kashkoieh
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  4. Elham Moniri
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  5. Igor Yu. Galaev
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Correspondence to Homayon Ahmad Panahi.

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Panahi, H.A., Nezhati, M.N., Kashkoieh, R.A. et al. Poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-dimethylacrylamide] brushes grafted onto siliceous support for preconcentration and determination of cobalt (II) in human plasma and environmental samples. Korean J. Chem. Eng. 30, 1722–1728 (2013). https://doi.org/10.1007/s11814-013-0100-1

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  • DOI: https://doi.org/10.1007/s11814-013-0100-1

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