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Emulsion liquid membrane for selective extraction of bismuth from nitrate medium

  • Separation Technology, Thermodynamics
  • Published:
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Abstract

The novelty of this work is the selective extraction of bismuth ions from nitrate medium by emulsion liquid membrane. Di(2-ethylhexyl)phosphoric acid was used as extractant of bismuth ions from nitrate medium by emulsion liquid membrane, and Triton X-100 was used as the biodegradable surfactant in n-pantanol n-pentanol bulk membrane. The extraction of bismuth ions was evaluated by the yield of extraction. The experimental parameters were evaluated and were optimized. They included the ratio of di(2-ethylhexyl)phosphoric acid concentration to the concentration of /Triton X-100 concentration (1.0: 0.5% w/w), nature of diluents (n-pentanol), nature and concentration of the stripping solution (sulfuric acid, 0.5M), stirring speed (1,800 rpm) and equilibrium time of extraction (20min), initial feed solution of bismuth (350 ppm) and the volume ratio of the internal stripping phase to the membrane phase (14 times). The experimental parameters of kinetic extraction revealed that the bismuth ions were extracted at 100% 97%.

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References

  1. H. Z. Chen, M. C. Kao, S. L. Young, C. C. Yu, C. H. Lin, C.M. Lee and C. R. Ou, Thin Solid Films, 517, 4818 (2009).

    Article  CAS  Google Scholar 

  2. F. Shemirani, M. Baghdadi, M. Ramezani and M. R. Jamali, Anal. Chim. Acta, 534, 163 (2005).

    Article  CAS  Google Scholar 

  3. P. Thirupathi and S. S. Kim, Tetrahedron, 65, 5168 (2009).

    Article  CAS  Google Scholar 

  4. J.G. Yang, J.Y. Yang, M. T. Tang, C. B. Tang and W. Liu, Hydrometallurgy, 96, 342 (2009).

    Article  CAS  Google Scholar 

  5. K. Campos, R. Domingo, T. Vincent, M. Ruiz, A.M. Sastre and E. Guibal, Water Res., 42, 4019 (2008).

    Article  CAS  Google Scholar 

  6. F. Habashi, Enc. Mater. Sci. Technol., 12, 332 (2008).

    Google Scholar 

  7. M. Chabani, A. Amrane and A. Bensmaili, Desalination, 206, 560 (2007).

    Article  CAS  Google Scholar 

  8. M. Gautam and B. K. Purl, Mikrochim. Acta, 1, 515 (1979).

    Article  CAS  Google Scholar 

  9. S. Kocaoba and G. Akcin, Desalination, 180, 151 (2005).

    Article  CAS  Google Scholar 

  10. B. Mokhtari and K. Pourabdollah, Supramol. Chem., 23, 696 (2011).

    Article  CAS  Google Scholar 

  11. S. Seyhan, M. Merdivan and N. Demirel, J. Hazard. Mater., 152, 79 (2008).

    Article  CAS  Google Scholar 

  12. O. Bechiri, F. Ismail, M. Abbessi and M. E. H. Samar, J. Hazard. Mater., 152, 895 (2008).

    Article  CAS  Google Scholar 

  13. M. Chiha, O. Hamdaoui, A. F. Chekkat and C. Pétrier, Ultrason. Sonochem., 17, 318 (2010).

    Article  CAS  Google Scholar 

  14. M. S. Gasser, N. E. El-hefny and J. A. Daoud, J. Hazard. Mater., 151, 610 (2008).

    Article  CAS  Google Scholar 

  15. B. Hamzah, N. Jalaluddin, A.W. Wahab and A. Upe, E. J. Chem., 7, 239 (2010).

    Article  CAS  Google Scholar 

  16. B. Sengupta, R. Sengupta and N. Subrahmanyam, Hydrometallurgy, 84, 43 (2006).

    Article  CAS  Google Scholar 

  17. C. Das, M. Rungta, G. Arya, S. DasGupta and S. De, J. Hazard. Mater., 159, 365 (2008).

    Article  CAS  Google Scholar 

  18. M. Rajasimman, R. Sangeetha and P. Karthik, J. Chem. Eng., 150, 275 (2009).

    Article  CAS  Google Scholar 

  19. Miesiac, K. Schüger and J. Szymanowski, J. Radioanal. Nucl. Chem., 163, 181 (1992).

    Article  CAS  Google Scholar 

  20. P. S. Kulkarni, S. Mukhopadhyay, M. P. Bellary and S. K. Ghosh, Hydrometallurgy, 64, 49 (2002).

    Article  CAS  Google Scholar 

  21. Kumbasar, J. Hazard. Mater., 178, 875 (2010).

    Article  CAS  Google Scholar 

  22. P. S. Kulkarni and V.V. Mahajani, J. Membr. Sci., 201, 123 (2002).

    Article  CAS  Google Scholar 

  23. S. Saravanan, K.M. Meera Sheriffa Begum and N. Anantharaman, Technol. Metallurgy, 41, 333 (2006).

    CAS  Google Scholar 

  24. S. Nosrati, N. S. Jayakumar and M. A. Hashim, Desalination, 266, 286 (2011).

    Article  CAS  Google Scholar 

  25. N. Othman, S. N. Zailani and N. Mili, J. Hazard. Mater., 198, 103 (2011).

    Article  CAS  Google Scholar 

  26. S.M. Mousavi, S. Kiani, M. Razavi Farmad, A. Hemati and B. Abbasi, J. Dispersion Sci. Technol., 33, 123 (2012).

    Article  CAS  Google Scholar 

  27. A. L. Ahmad, A. Kusumastuti, C. J. C. Derek and B. S. Ooi, Chem. Eng. J., 171, 870 (2011).

    Article  CAS  Google Scholar 

  28. Rahul Kumar Goyal, N. S. Jayakumar and M. A. Hashim, Desalination, 278, 50 (2011).

    Article  CAS  Google Scholar 

  29. B. Mokhtari and K. Pourabdollah, J. Chinese Chem. Soc., 59, 1058 (2012).

    Article  CAS  Google Scholar 

  30. B. Mokhtari and K. Pourabdollah, Korean J. Chem. Eng., 29, 1788 (2012).

    Article  CAS  Google Scholar 

  31. M. Lurdes, F. Gameiro, P. Bento, M. Rosinda, C. Ismael, M. Teresa, A. Reis and M. R. Carvalho Jorge, J. Membr. Sci., 293, 151 (2007).

    Article  CAS  Google Scholar 

  32. B. Mokhtari and K. Pourabdollah, Desalination, 292, 1 (2012).

    Article  CAS  Google Scholar 

  33. B. Xu and H. Y. Li, Adv. Mater. Res., 496, 411 (2012).

    Article  CAS  Google Scholar 

  34. A. L. Ahmad, A. Kusumastuti, C. J.C. Derek and B. S. Ooi, Desalination, 287, 30 (2012).

    Article  CAS  Google Scholar 

  35. H. Yaoqiang, Z. Ningsheng, Q. Chengtun, H. Fei and Y. Yongli, Can. J. Chem. Eng., 90, 120 (2012).

    Article  CAS  Google Scholar 

  36. Kumbasar, J. Hazard. Mater., 167, 1141 (2009).

    Article  CAS  Google Scholar 

  37. B. Mokhtari and K. Pourabdollah, J. Chinese Chem. Soc., 59, 1058 (2012).

    Article  CAS  Google Scholar 

  38. J. A. Reyes-Aguilera, M. P. Gonzalez, R. Navarro, T. I. Saucedo and M. Avila-Rodriguez, J. Membr. Sci., 310, 13 (2008).

    Article  CAS  Google Scholar 

  39. D. Melzner, J. Tilkowski, A. Mohrmann, W. Poppe, W. Halwachs and K. Schügerl, Hydrometallurgy, 13, 105 (1984).

    Article  CAS  Google Scholar 

  40. G. Charlot, Dosages absorptiométriques des éléments minéraux, 182 (1978).

    Google Scholar 

  41. G. Charlot, Les réactions chimiques en solution aqueuse et caractérisation des ions, 257 (1983).

    Google Scholar 

  42. G. H. Jeffery, J. Bassett, J. Mendham and R. C. Denny, Text book Quantitative Chemical Analysis, Fifth Edition, VOGEL’S, 684 (1989).

    Google Scholar 

  43. Kumbasar, J. Membr. Sci., 325, 460 (2008).

    Article  CAS  Google Scholar 

  44. M. T. A. Reis and J. M. R. Carvalho, J. Membr. Sci., 237, 97 (2004).

    Article  CAS  Google Scholar 

  45. N. Leepipatpiboon, U. Pancharoen and P. Ramakul, Korean J. Chem. Eng., 30, 194 (2013).

    Article  CAS  Google Scholar 

  46. S. Venkatesan and K.M. Meera Sheriffa Begum, Desalination, 236, 65 (2009).

    Article  CAS  Google Scholar 

  47. E. O. Out, Thermochim. Acta, 329, 117 (1999).

    Article  Google Scholar 

  48. Alonso, M. J. Almendral, M. D. Báez, M. J. Porras, F. López Lavín and C. García de María, Anal. Chim. Acta, 408, 129 (2000).

    Article  CAS  Google Scholar 

  49. J. A. Reyes-Aguilera, M. P. Gonzalez, R. Navarro, T. I. Saucedo and M. Avila-Rodriguez, J. Membr. Sci., 310, 13 (2008).

    Article  CAS  Google Scholar 

  50. J. Yang, J. Yang, M. Tang, C. Tang and W. Liu, Hydrometallurgy, 96, 342 (2009).

    Article  CAS  Google Scholar 

  51. N. Song, W. Li and Q. Jia, Sep. Purif. Technol., 104, 64 (2013).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemical Engineering, Shahreza Branch, Islamic Azad University, Shahreza, Iran

    Bahram Mokhtari & Kobra Pourabdollah

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  1. Bahram Mokhtari
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  2. Kobra Pourabdollah
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Correspondence to Kobra Pourabdollah.

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Mokhtari, B., Pourabdollah, K. Emulsion liquid membrane for selective extraction of bismuth from nitrate medium. Korean J. Chem. Eng. 30, 1458–1465 (2013). https://doi.org/10.1007/s11814-013-0062-3

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  • DOI: https://doi.org/10.1007/s11814-013-0062-3

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