Skip to main content
Log in

Tie-line data for aqueous mixtures of butyric acid with isobutyl acetate at various temperatures

  • Separation Technology, Thermodynamics
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Experimental liquid-liquid equilibrium (LLE) data for the system of (water+butyric acid+iso-butyl acetate) were obtained at T=(298.2, 303.2, 308.2, and 313.2) K and atmospheric pressure. This ternary system exhibits type-1 behavior of LLE. The experimental tie-line data were correlated using the UNIQUAC and NRTL models. The reliability of the experimental tie-line data was determined by applying the Othmer-Tobias and Hand correlations. Distribution coefficients and separation factors were calculated over the immiscibility regions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Senol, Fluid Phase Equilib., 243, 51 (2006).

    Article  CAS  Google Scholar 

  2. D. Özmen, J. Chem. Thermodyn., 39, 123 (2007).

    Article  Google Scholar 

  3. D. Özmen, Fluid Phase Equilib., 269, 12 (2008).

    Article  Google Scholar 

  4. H. Uslu and Ş. I. Kırbaşlar, Fluid Phase Equilib., 287, 134 (2010).

    Article  CAS  Google Scholar 

  5. S. Şahin, Ş. I. Kırbaşlar and M. Bilgin, J. Chem. Thermodyn., 41, 97 (2009).

    Article  Google Scholar 

  6. Ş. I. Kırbaşlar, S. Şahinn and M. Bilgin, J. Chem. Thermodyn., 39, 1463 (2007).

    Article  Google Scholar 

  7. M. Bilgin and C. Arisoy, Fluid Phase Equilib., 250, 59 (2006).

    Article  CAS  Google Scholar 

  8. S. A. Al-Muhtaseb and M. A. Fahim, Fluid Phase Equilib., 123, 189 (1996).

    CAS  Google Scholar 

  9. D. Vandak, J. Zigova, E. Sÿturdik and S. Schlosser, Process Biochem., 32, 245 (1977).

    Article  Google Scholar 

  10. E. Sabolova, S. Schlosser and J. Martak, J. Chem. Eng. Data, 46, 735 (2001).

    Article  CAS  Google Scholar 

  11. Z.Y. Li, W. Qin and Y. Dai, J. Chem. Eng. Data, 47, 843 (2002).

    Article  Google Scholar 

  12. Ş. I. Kırbaşlar, S. Şahin and M. Bilgin, J. Chem. Thermodyn., 39, 1279 (2007).

    Article  Google Scholar 

  13. Ş. I. Kırbaşlar, J. Chem. Thermodyn., 38, 696 (2006).

    Article  Google Scholar 

  14. Ş. I. Kırbaşlar, M. Bilgin and D. Batr, J. Chem. Thermodyn., 37, 175 (2005).

    Article  Google Scholar 

  15. M. Bilgin, J. Chem. Thermodyn., 38, 1643 (2006).

    Article  Google Scholar 

  16. M. Bilgin, Ş. I. Kırbaşlar, Ö. Özcan and U. Dramur, J. Chem. Thermodyn., 37, 297 (2005).

    Article  CAS  Google Scholar 

  17. A. Gök, Ş. I. Kırbaşlar, H. Uslu and H. Ghanadzadeh Gilani, Fluid Phase Equilib., 303, 71 (2011).

    Article  Google Scholar 

  18. H. Ghanadzadeh, A. Ghanadzadeh, S. Asgharzadeh and N. Dastmoozeh, Thermochim. Acta, 523, 154 (2011).

    Article  CAS  Google Scholar 

  19. H. Ghanadzadeh, A. Ghanadzadeh, Z. Aghajani, S. Abbasnejad and S. Shekarsaraee, J. Chem. Thermodyn., 42, 695 (2010).

    Article  CAS  Google Scholar 

  20. D. S. Abrams and J.M. Prausnitz. AIChE J., 21, 116 (1975).

    Article  CAS  Google Scholar 

  21. H. Renon and J.M. Prausnitz. AIChE J., 14, 135 (1968).

    Article  CAS  Google Scholar 

  22. N. Peschke and S. I. Sandler, J. Chem. Eng. Data, 40, 315 (1995).

    Article  CAS  Google Scholar 

  23. H. Li and K. Tamura, Fluid Phase Equilib., 263, 223 (2008).

    Article  CAS  Google Scholar 

  24. A. Merzougui, A, Hasseine, A, Kabouche and M. Korichi, Fluid Phase Equilib., 309, 161 (2011).

    Article  CAS  Google Scholar 

  25. A. Bondi, J. Phys. Chem., 68, 441 (1964).

    Article  CAS  Google Scholar 

  26. A. Bondi, Physical Properties of Molecular Crystals, Liquids and Glasses, John Wiley and Sons Inc., New York (1968).

    Google Scholar 

  27. T. Banerjee, M. K. Singh, R.K. Sahoo and A. Khanna, Fluid Phase Equilib., 234, 64 (2005).

    Article  CAS  Google Scholar 

  28. D. F. Othmer and P. E. Tobias, Ind. Eng. Chem., 34, 690 (1942).

    Article  CAS  Google Scholar 

  29. V. Brandani, A. Chianese and M. Rossi, J. Chem. Eng. Data, 30, 27 (1985).

    Article  CAS  Google Scholar 

  30. A. Chafer, J. de la Torre, J. B. Monton and E. Lladosa, Fluid Phase Equilib., 265, 122 (2008).

    Article  CAS  Google Scholar 

  31. H. Ghanadzadeh Gilani, M. Golpour and B. Abbasi Souraki, J. Chem. Thermodyn., 49, 39 (2010).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hossein Ghanadzadeh.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ghanadzadeh, H., Asgharzadeh, S., Dastmoozeh, N. et al. Tie-line data for aqueous mixtures of butyric acid with isobutyl acetate at various temperatures. Korean J. Chem. Eng. 29, 1615–1621 (2012). https://doi.org/10.1007/s11814-012-0067-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-012-0067-3

Key words

Navigation