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Investigating the processes of contaminant removal in Fe0/H2O systems

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Abstract

The instability of the premise of direct quantitative contaminant reduction by elemental iron (Fe0) materials in Fe0/H2O systems is pointed out. Basic knowledge of aqueous iron corrosion shows that the Fe0 surface is not available for decontamination in nature. A comparison of the reactivity of Fe0 and Zn0 shows that the effectiveness of Fe0 materials for environmental remediation is due to the formation of a non-adhesive, porous oxide scale on Fe0. Contaminants are enmeshed within the scale and possibly reduced by FeII and H/H2. An evaluation of current experimental conditions shows that well-mixed batch systems have disturbed the process of scale formation. Therefore, the majority of published works have operatively created conditions for contaminant reduction that are not likely to occur in nature. Since working under such unrealistic conditions has mediated the above-mentioned premise, interactions in Fe0/H2O systems yielding contaminant removal should be revisited.

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  1. Angewandte Geologie, Universität Göttingen, Goldschmidtstraße 3, D-37077, Göttingen, Germany

    Chicgoua Noubactep

  2. Kultur und Nachhaltige Entwicklung CDD e.V., Postfach 1502, D-37005, Göttingen, Germany

    Chicgoua Noubactep

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Noubactep, C. Investigating the processes of contaminant removal in Fe0/H2O systems. Korean J. Chem. Eng. 29, 1050–1056 (2012). https://doi.org/10.1007/s11814-011-0298-8

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