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Vapor-liquid equilibra for cyclohexane+2-propoxyethanol and cyclohexane+2-butoxyethanol systems

  • Separation Technology, Thermodynamics
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Abstract

2-propoxyethanol (C3E1) and 2-butoxyethanol (C4E1) are nonionic surfactants which are a particularly interesting class of substances due to both inter-molecular and intra-molecular association, related to the presence of O and OH in the same molecule. Binary (vapor+liquid) equilibrium data were measured for cyclohexane+2-propoxyethanol and cyclohexane+2-butoxy ethanol systems at temperatures ranging from 303.15 K to 323.15 K at 10 K intervals. A static apparatus was used in this study. Two systems show positive deviation from Raoult’s law and no azeotrope. The experimental data were correlated well with Peng-Robinson-Stryjek-Vera equation of state using Wong-Sandler mixing rule incorporating the non-random-two-liquid model.

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Correspondence to Moon Sam Shin.

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Kim, S., Choi, Y.K., Kim, D. et al. Vapor-liquid equilibra for cyclohexane+2-propoxyethanol and cyclohexane+2-butoxyethanol systems. Korean J. Chem. Eng. 29, 644–649 (2012). https://doi.org/10.1007/s11814-011-0236-9

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  • DOI: https://doi.org/10.1007/s11814-011-0236-9

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