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Measurement and correlation of the isobaric vapor-liquid equilibrium for mixtures of alcohol+ketone systems at atmospheric pressure

  • Separation Technology, Thermodynamics
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Abstract

Vapor-liquid equilibrium (VLE) for binary mixtures composed of ethanol+methyl isobutyl ketone, 1-butanol+ methyl ethyl ketone, and 1-butanol+methyl propyl ketone systems was measured using a circulation type equilibrium apparatus at atmospheric pressure. The measured data and literature data for alcohol and ketone systems have been correlated by the UNIversal Quasi-Chemical (UNIQUAC) model with two binary interaction parameters and the non-random lattice fluid equation of state with hydrogen bonding equation of state (NLF-HB EoS) using a single binary interaction parameter. For the NLF-HB EoS calculations, the numbers of proton acceptor for ketones were adjusted between 0 and 1. The calculation results with the NLF-HB EoS are better than those with the UNIQUAC model.

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Authors and Affiliations

  1. Department of Chemical and Biological Engineering, Korea University, 5-1 Anam-dong, Sungbuk-gu, Seoul, 136-713, Korea

    Myoung Do Seo, Young Jo Kim & Jeong Won Kang

  2. Department of Chemical and Biomolecular Engineering, Sogang University, Seoul, 121-742, Korea

    Jong Sung Lim

Authors
  1. Myoung Do Seo
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  2. Young Jo Kim
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  3. Jong Sung Lim
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  4. Jeong Won Kang
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Correspondence to Jeong Won Kang.

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Seo, M.D., Kim, Y.J., Lim, J.S. et al. Measurement and correlation of the isobaric vapor-liquid equilibrium for mixtures of alcohol+ketone systems at atmospheric pressure. Korean J. Chem. Eng. 29, 103–110 (2012). https://doi.org/10.1007/s11814-011-0147-9

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  • DOI: https://doi.org/10.1007/s11814-011-0147-9

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