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Simultaneous absorption of carbon dioxide, sulfur dioxide, and nitrogen dioxide into aqueous 1, 8-diamino-p-menthane

  • Separation Technology
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Abstract

3 gaseous mixtures of CO2, SO2, and NO2 were simultaneously absorbed into 1, 8-diamino-p-menthane (DAM) in a stirred, semi-batch tank with a planar, gas-liquid interface within a range of 0–2.0 kmol/m3 of DAM, 0.05–0.3 atm of CO2, 0.0025–0.04 atm of SO2, and 298.15–323.15 K at a fixed NO2 of 0.001 atm to measure their total molar fluxes. Diffusivity and Henry constants of CO2, SO2, and NO2 were obtained using the reference data, measured by N2O analogy. The mass transfer coefficient of each gas, needed to obtain the absorption rate without a chemical reaction, was modified with viscosity of aqueous DAM solution. In CO2-SO2-NO2-DAM system accompanied by first-order reaction with respect to CO2 and instantaneous reactions with respect to SO2 and NO2, the enhancement factors of CO2 and SO2 were obtained by using an approximate solution of mass balances consisting of reaction regimes of two gases, one of which reacts instantaneously, and then, the enhancement factor of NO2 by comparing the instantaneous rates of SO2 and NO2. The observed values of the molar flux approached to the calculated values very well.

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References

  1. M. Aresta, Carbon dioxide recovery and utilization, Kluwer Academic Pub., Boston (2003).

    Google Scholar 

  2. M. Caplow, J. Am. Chem. Soc., 90, 6795 (1968).

    Article  CAS  Google Scholar 

  3. P. V. Danckwerts, Chem. Eng. Sci., 34, 443 (1979).

    Article  CAS  Google Scholar 

  4. E. F. da Silva and H. F. Sendsen, Ind. Eng. Chem. Res., 43, 3413 (2004).

    Article  Google Scholar 

  5. T. Mimura, T. Suda, A. Honda and H. Kumazawa, Chem. Eng. Commun., 170, 245 (1998).

    Article  CAS  Google Scholar 

  6. J. Stein, M. Kind and E. Schlunder, Chem. Eng. J., 86, 17 (2002).

    Article  CAS  Google Scholar 

  7. S.H. Jung, G. T. Jeong, G.Y. Lee, J. M. Cha and D. H. Park, Korean J. Chem. Eng., 24, 1064 (2007).

    Article  CAS  Google Scholar 

  8. S. Ebrahimi, C. Picioreanu, R. Kleerebezem, J. J. Heijnen and M. C. M. van Loosdrecht, Chem. Eng. Sci., 58, 3589 (2003).

    Article  CAS  Google Scholar 

  9. S. Colle, J. Vanerschuren and D. Thomas, Chem. Eng. Process, 43, 1397 (2004).

    Article  CAS  Google Scholar 

  10. J. Xia, B. Rumpf and G. Maurer, Ind. Eng. Chem. Res., 38, 1149 (1999).

    Article  CAS  Google Scholar 

  11. M. H. H. an Dam, A. S. Lamine, D. Roizard, P. Lochon and P. Roizard, Ind. Eng. Chem. Res., 36, 4628 (1997).

  12. D. Nagel, R. de Kermadec, H.G. Lintz, C. Roizard and F. Lapicque, Chem. Eng. Sci., 57, 4883 (2002).

    Article  CAS  Google Scholar 

  13. P.V. Danckwerts, Gas-liquid reactions, McGraw-Hill, New York (1970).

    Google Scholar 

  14. K.G. Denbigh and A. J. Prince, J. Am. Chem. Soc., 69, 790 (1947).

    Article  Google Scholar 

  15. P. Gray and A. D. Yoffe, Chem. Rev., 55, 1069 (1955).

    Article  CAS  Google Scholar 

  16. J. J. Carberry, Chem. Eng. Sci., 9, 189 (1959).

    Article  CAS  Google Scholar 

  17. P.G. Caudle and K.G. Denbigh, Trans. Faraday, Soc., 49, 39 (1959).

    Article  Google Scholar 

  18. M. M. Wendel and R. L. Pigford, J. Am. Chem. Soc., 4, 249 (1958).

    CAS  Google Scholar 

  19. M. P. Ho and G. E. Klinzing, Can J. Chem. Eng., 64, 243 (1986).

    Article  CAS  Google Scholar 

  20. E. Sada, H. Kumazawa and Y. Yoshikawa, J. Am. Chem. Soc., 34, 1215 (1988).

    CAS  Google Scholar 

  21. E.Y. Kenig, R. Schneider and A. Gorak, Chem. Eng. Sci., 54, 5195 (1999).

    Article  CAS  Google Scholar 

  22. S.W. Park, D.W. Park, K. J. Oh and S. S. Kim, Sep. Sci. Technol., 44, 543 (2009).

    Article  CAS  Google Scholar 

  23. K. S. Hwang, D.W. Kim, S.W. Park, D.W. Park, K. J. Oh and S. S. Kim, Sep. Sci. Technol., 44, 3888 (2009).

    Article  CAS  Google Scholar 

  24. K. J. Oh, S. S. Kim and S.W. Park, Sep. Sci. Technol., To be accepted (2010).

  25. L. A. Goetter and R. L. Pigford, J. Am. Chem. Soc., 17, 793 (1971).

    Google Scholar 

  26. H. Hikita, S. Asai and H. Ishikawa, Chem. Eng., J., 18, 169 (1979).

    CAS  Google Scholar 

  27. K. J. Oh, Y. S. Choi, S. S. Kim and S.W. Park, Korean J. Chem. Eng., To be accepted (2010).

  28. J. B. Seo, S. B. Jeon, W. J. Choi, J.W. Kim, G. H. Lee and K. J. Oh, Korean J. Chem. Eng., 28, 170 (2011).

    Article  CAS  Google Scholar 

  29. L. K. Daraiswany and M. M. Sharma, Heterogeneous reaction: Analysis, example and reactor design, Wiley, New York (1984).

    Google Scholar 

  30. W. Yu, G. Astarita and D.W. Savage, Chem. Eng. Sci., 40, 1585 (1985).

    Article  CAS  Google Scholar 

  31. G. F. Versteeg and W. P. M. van Swaaij, J. Chem. Eng. Data, 33, 29 (1988).

    Article  CAS  Google Scholar 

  32. A. K. Saha, S. S. Bandyopadhyay and A.K. Biswas, J. Chem. Eng. Data, 38,78 (1993).

    Article  CAS  Google Scholar 

  33. W. Pasiuk-Bronikowska and K. J. Rudzinski, Chem. Eng. Sci., 46, 2281 (1991).

    Article  CAS  Google Scholar 

  34. F. T. Shadid and D. Handley, Chem. Eng. Res. Dev., 67, 185 (1989).

    CAS  Google Scholar 

  35. E. L. Cussler, Diffusion, Cambridge University Press, New York (1984).

    Google Scholar 

  36. G. Carta and R. L. Pigford, Ind. Eng. Chem. Fundam., 22, 329 (1983).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. School of Civil and Environmental Engineering, Pusan National University, Busan, 609-735, Korea

    Kwang-Joong Oh

  2. Greenhouse Gas Research Center, Korea Institute of Energy Research, Daejeon, 305-343, Korea

    Byoung-Moo Min

  3. Department of Environmental Administration, Catholic University of Pusan, Busan, 609-757, Korea

    Seong-Soo Kim

  4. School of Chemical and Biomolecular Engineering, Pusan National University, Busan, 609-735, Korea

    Sang-Wook Park

Authors
  1. Kwang-Joong Oh
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  2. Byoung-Moo Min
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  3. Seong-Soo Kim
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  4. Sang-Wook Park
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Correspondence to Sang-Wook Park.

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Oh, KJ., Min, BM., Kim, SS. et al. Simultaneous absorption of carbon dioxide, sulfur dioxide, and nitrogen dioxide into aqueous 1, 8-diamino-p-menthane. Korean J. Chem. Eng. 28, 1754–1760 (2011). https://doi.org/10.1007/s11814-011-0025-5

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  • DOI: https://doi.org/10.1007/s11814-011-0025-5

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