Skip to main content
Log in

Catalytic degradation of polyethylene over SBA-16

  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

The performance of SBA-16 catalysts toward the degradation of two kinds of polyethylenes, high-density polyethylene (HDPE) and linear low-density polyethylene (LLDPE), was evaluated by using a thermogravimetric analyzer and batch reactor. The effect of the acidity of SBA-16 upon degradation efficiency was investigated. Quantitative analyses of the products were conducted by GC/MS and GC. The Al-SBA-16 led to a higher catalytic conversion than SBA-16. Hydrocarbons (C7–C10) were mainly produced by Al-SBA-16, whereas a much broader distribution of oil products (C7–C14) was obtained by SBA-16. The Al-SBA-16 also showed high catalytic stability. The results of this study suggest that Al-SBA-16 has a high potential as a catalyst for degradation of waste plastics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. R. Bagri and P. T. Williams, J. Anal. Appl. Pyrolysis, 63, 29 (2002).

    Article  CAS  Google Scholar 

  2. W. Kaminsky, in: Feedstock recycling and pyrolysis of waste plastics, J. Scheirs and W. Kaminsky Eds., Part II, pp. 627–640, John Wiley & Sons, Ltd., Chichester (2006).

    Chapter  Google Scholar 

  3. T. Yoshioka and G. Grause, in: Feedstock recycling and pyrolysis of waste plastics, J. Scheirs and W. Kaminsky Eds., Part II, pp. 641–661, John Wiley & Sons, Ltd., Chichester (2006).

    Chapter  Google Scholar 

  4. J. Aguado, D. P. Serrano and J. M. Escola, in: Feedstock recycling and pyrolysis of waste plastics, J. Scheirs and W. Kaminsky Eds., Part I, pp. 73–110, John Wiley & Sons, Ltd., Chichester (2006).

    Chapter  Google Scholar 

  5. H. J. Park, Y. K. Park, J. I. Dong, J. K. Jeon, J. H. Yim and K. E. Jeong, Res. Chem. Intermed., 34, 727 (2008).

    Article  CAS  Google Scholar 

  6. H. J. Park, J. H. Yim, J. K. Jeon, J. M. Kim, K. S. Yoo and Y. K. Park, J. Phys. Chem. Solids, 69, 1125 (2008).

    Article  Google Scholar 

  7. Y. K. Park, J. S. Kim, J. H. Choi, J. K. Jeon, S. D. Kim, S. S. Kim, J. M. Kim and K. S. Yoo, J. Korean Soc. Waste Manage., 20, 565 (2003).

    Google Scholar 

  8. Y. K. Park, J. S. Kim, J. K. Jeon, J. E. Lim, J. M. Kim and K. S. Yoo, Polymer-Korea, 29, 122 (2005).

    CAS  Google Scholar 

  9. J. K. Jeon, Y. K. Park, S. Kim, S. S. Kim, J. H. Yim and J. M. Sohn, J. Ind. Eng. Chem., 13, 176 (2007).

    CAS  Google Scholar 

  10. J. K. Jeon, Y. K. Park, S. S. Kim, D. Cho and J. C. Kim, J. Ind. Eng. Chem., 13, 735 (2007).

    CAS  Google Scholar 

  11. K. H. Lee and D. H. Shin, Korean J. Chem. Eng., 23, 209 (2006).

    Article  CAS  Google Scholar 

  12. K. H. Cho, D. R. Cho, K. H. Kim and D. W. Park, Korean J. Chem. Eng., 24, 223 (2007).

    Article  CAS  Google Scholar 

  13. T. W. Kim, R. Ryoo, M. Kruk, K. P. Gierszal, M. Jaroniec, S. Kamiya and O. Terasaki, J. Phys. Chem. B, 108, 11480 (2004).

    Article  CAS  Google Scholar 

  14. J. A. Bae, K. C. Song, J. K. Jeon, Y. S. Ko, Y. K. Park and J. H. Yim, Micro. Meso. Mater., 123, 289 (2009).

    Article  CAS  Google Scholar 

  15. Y. C. Park, J. Y. Park, D. H. Bae and D. Shun, Korean J. Chem. Eng., 26, 1608 (2009).

    Article  CAS  Google Scholar 

  16. L. Tao, G. B. Zhao, J. Qian and Y. K. Qin, Korean J. Chem. Eng., 26, 856 (2009).

    Article  CAS  Google Scholar 

  17. G. Chandrasekar, K. S. You, J. W. Ahn and W. S. Ahn, Micropor. Mesopor. Mater., 111, 455 (2008).

    Article  CAS  Google Scholar 

  18. D. P. Serrano, J. Aguado and J. M. Escola, Ind. Eng. Chem. Res., 39, 1177 (2000).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Young-Kwon Park.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Choi, S.J., Park, YK., Jeong, KE. et al. Catalytic degradation of polyethylene over SBA-16. Korean J. Chem. Eng. 27, 1446–1451 (2010). https://doi.org/10.1007/s11814-010-0281-9

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-010-0281-9

Key words

Navigation