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Adsorption of carbon dioxide onto PDA-CP-MS41 adsorbent

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Abstract

Carbon dioxide was adsorbed onto mesoporous adsorbent of PDA-CP-MS41, which was synthesized by CP-MS41 with propylene diamine, in a laboratory-scale packed-bed. Experiments were carried out at different adsorption temperatures (30–60 °C), amounts of adsorbent (1–3 g), and flow rates of nitrogen (15–60 cm3/min) to obtain the breakthrough curves of CO2. These curves were tested by the deactivation model, which combined the adsorption of CO2 and the deactivation of adsorbent particles. The adsorption rate constant and the deactivation rate constant were evaluated through analysis of the experimental breakthrough data using a nonlinear least squares technique. The experimental breakthrough data were fitted very well to the deactivation model than the adsorption isotherm models in the literature.

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References

  1. M. Aresta, Carbon dioxide recovery and utilization, Kluwer academic Pub., Boston (2003).

    Google Scholar 

  2. R. K. Bartoo, Chem. Eng. Prog., 80, 35 (1984).

    CAS  Google Scholar 

  3. W. Fuchs and N. T. Syosett, U. S. Patent 3,511,595 (1970).

    Google Scholar 

  4. D. Gidaspow and M. Onischak, U. S. Patent 3,865,924 (1975).

    Google Scholar 

  5. S. Hirano, N. Shigomoto, S. Yamada and H. Hayashi, Bull. Chem. Soc. Jpn., 68, 1030 (1995).

    Article  CAS  Google Scholar 

  6. H. Hayashi, H. J. Taniuchi, N. Furuyashiki, S. Sugiyama, S. Hirano, N. Shigemoto and T. Nonaka, Ind. Eng. Chem. Res., 37, 185 (1998).

    Article  CAS  Google Scholar 

  7. T. Shigemoto, S. Sugiyama and H. Hayashi, J. Chem. Eng. Jpn., 38, 711 (2005).

    Article  CAS  Google Scholar 

  8. A.G. Okunev, V. E. Sharnov, Y. I. Aristov and V. N. Parmon, React. Kinet. Catal. Lett., 71, 355 (2004).

    Article  Google Scholar 

  9. M. L. Ruhl, Chem. Eng. Prog., 89, 1344 (1993).

    Google Scholar 

  10. C. T. Kresge, M. E. Leonowicz, W. J. Roth, J. C. Vartuli, J. S. Beck, Nature, 359, 710 (1992).

    Article  CAS  Google Scholar 

  11. J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K.D. Schmitt, C. T.W. Chu, D.H. Olson, E.W. Sheppard, S. B. McCullen, J.B. Higgins and J. L. Schlenker, J. Am. Chem. Soc., 114, 10834 (1992).

    Article  CAS  Google Scholar 

  12. D. Zhao, J. Feng, Q. Huo, N. Melosh, G. H. Fredrickson, B. F. Chmelka and G. D. Stucky, Science, 279, 548 (1998).

    Article  CAS  Google Scholar 

  13. A. Bhaumik and T. Tatsumi, J. Catal., 189, 31 (2000).

    Article  CAS  Google Scholar 

  14. S. L. Burkett, S. D. Sim and S. J. Mann, J. Chem. Soc. Chem. Commun., 1367 (1996).

  15. M.H. Lim, C. F. Blanford and A. Stein, J. Am. Chem. Soc., 119, 4090 (1997).

    Article  CAS  Google Scholar 

  16. C. E. Fowler, B. Lebeau and S. Mann, J. Chem. Soc. Chem. Commun., 1825 (1998).

  17. F. Babonneau, L. Leite and S. Fontlupt, J. Mater. Chem. 9, 175 (1999).

    Article  CAS  Google Scholar 

  18. H.Y. Huang and R. T. Yang, Ind. Eng. Chem. Res., 42, 2427 (2003).

    Article  CAS  Google Scholar 

  19. X. Xu, C. Song, B.G. Miller and A.W. Scaroni, Fuel Proc. Technol., 86, 1457 (2005).

    Article  CAS  Google Scholar 

  20. S. Udayakumar, S.W. Park, D.W. Park and B. S. Choi, Catal. Commun., 9, 1563 (2008).

    Article  CAS  Google Scholar 

  21. L.K. Doraiswamyand and M. M. Sharma, Heterogeneous reactions, John Wiley & Sons, New York (1954).

    Google Scholar 

  22. M. Ishida and C. Y. Wen, AIChE J., 14, 311 (1968).

    Article  CAS  Google Scholar 

  23. P.A. Pamachandran and B.D. Kulkarni, Ind. Eng. Chem. Res. Process Des. Dev., 19, 717 (1980).

    Article  Google Scholar 

  24. J.W. Evans and S. Song, Ind. Eng. Chem. Process Des. Dev., 13, 146 (1974).

    Article  CAS  Google Scholar 

  25. B. S. Sampath, P.A. Ramachandran and R. Hughes, Chem. Eng. Sci., 30, 135 (1975).

    Article  CAS  Google Scholar 

  26. M. G. Ranade and J.W. Evans, Ind. Eng. Chem. Process Des. Dev., 19, 118 (1980).

    Article  CAS  Google Scholar 

  27. D.M. Ruthven, Principles of adsorption and adsorption processes, John & Wiley, New York (1984).

    Google Scholar 

  28. M. Suzuki, Adsorption engineering, Kodansga Ltd., Tokyo (1990).

    Google Scholar 

  29. N. Orbey, G. Dogu and T. Dogu, Can. J. Chem. Eng., 60, 314 (1982).

    Article  CAS  Google Scholar 

  30. S. Yasyerli, T. Dogu, G. Dogu and I. Ar, Chem. Eng. Sci., 51, 2523 (1996).

    Article  CAS  Google Scholar 

  31. T. Kopac and S. Kocabas, Chem. Eng. Comm., 190, 1041 (2003).

    Article  CAS  Google Scholar 

  32. Y. Suyadal, M. Erol and M. Oguz, Ind. Eng. Chem. Res., 39, 724 (2000).

    Article  CAS  Google Scholar 

  33. S.W. Park, D.W. Sung, B. S. Choi and K.W. Oh, Sep. Sci. Technol., 41, 2665 (2006).

    Article  CAS  Google Scholar 

  34. S.W. Park, D.W. Sung, B. S. Choi, J.W. Lee and H. Kumazawa, J. Ind. Eng. Chem., 12, 522 (2006).

    CAS  Google Scholar 

  35. S.W. Park, B. S. Choi and J.W. Lee, Sep. Sci. Technol., 42, 2221 (2007).

    Article  CAS  Google Scholar 

  36. K. S. Hwang, S.W. Park, D.W. Park, K. J. Oh and S. S. Kim, Korean J. Chem. Eng., 26, in Press (2009).

  37. T. Dogu, AIChE J., 32, 849 (1986).

    Article  CAS  Google Scholar 

  38. O. Leal, C. Bolivar, C. Ovalles, J. J. Garcia and Y. Espidel, Inorganica Chimica Acta, 240, 183 (1995).

    Article  CAS  Google Scholar 

  39. S. Yasyerli, G. Dogu and I. Ar, Chem. Eng. Comm., 190, 1055 (2003).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Division of Chemical Engineering, Pusan National University, Busan, 609-735, Korea

    Kyu-Suk Hwang, Lina Han, Dae-Won Park, Kwang-Joong Oh & Sang-Wook Park

  2. School of Environmental Science, Catholic University of Pusan, Busan, 609-757, Korea

    Seong-Soo Kim

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  1. Kyu-Suk Hwang
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  2. Lina Han
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  3. Dae-Won Park
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  4. Kwang-Joong Oh
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  6. Sang-Wook Park
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Correspondence to Sang-Wook Park.

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Hwang, KS., Han, L., Park, DW. et al. Adsorption of carbon dioxide onto PDA-CP-MS41 adsorbent. Korean J. Chem. Eng. 27, 241–248 (2010). https://doi.org/10.1007/s11814-009-0301-9

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  • DOI: https://doi.org/10.1007/s11814-009-0301-9

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