Skip to main content
Log in

Two phase (air-molten carbonate salt) flow characteristics in a molten salt oxidation reactor

  • Materials (Organic, Inorganic, Electronic, Thin Films)
  • Published:
Korean Journal of Chemical Engineering Aims and scope Submit manuscript

Abstract

Molten salt oxidation process is one of the most promising alternatives to incineration that can be used to effectively destroy the organic components of mixed and hazardous wastes. To detect the flow characteristics of the molten salt oxidation process (air-molten carbonate salt two-phase flow), differential pressure fluctuation signals from a molten salt oxidation process have been analyzed by adopting the stochastic methods. Effects of the input air flow rate (0.05–0.22 m/sec) and the molten salt temperature (870–970 °C) on the phase holdup and flow characteristics are studied. The gas holdup increases with an increasing molten salt temperature due to the decrease of the viscosity and surface tension of the molten carbonate salt. It is found that a stochastic analysis of the differential pressure signals enables us to obtain the flow characteristics in the molten salt oxidation process. The experimentally obtained gas holdup data in the molten salt reactor were well described and characterized by means of the drift-flux model.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W. D. Deckwer, R. Burckhart and G. Zoll, Chem. Eng. Sci., 29, 2177 (1974).

    Article  CAS  Google Scholar 

  2. Y. Kang, J. S. Shim, M. H. Ko and S. D. Kim, Korean J. Chem. Eng., 13, 317 (1996).

    Article  CAS  Google Scholar 

  3. S. J. Kim, Y. J. Cho, C. G. Lee, Y. Kang and S. D. Kim, Korean J. Chem. Eng., 19, 175 (2002).

    Article  CAS  Google Scholar 

  4. J. H. Bell, P. A. Hass and J. C. Rudolph, Sep. Sci. Technol., 30, 1755 (1995).

    Article  CAS  Google Scholar 

  5. P. C. Hsu, K. G. Foster, T. D. Ford, P. H. Wallman, E. Watkins, C. O. Pruneda and M.G. Adamson, Waste Management, 20, 363 (2000).

    Article  CAS  Google Scholar 

  6. M. G. Adamson, P. C. Hsu, D. L. Hipple, K.G. Foster, R. W. Hopper and T. D. Ford, in G. E. Marcelle (Ed.), France, 1 (1998).

  7. C. O. Pruned, B. E. Watkins and R. S. Upadhye, JANNAF Propulsion and Subcommittee Joint Meeting, December, FL (1995).

  8. M. Alam and S. Kamath, Environ. Sci. Technol., 32, 3986 (1998).

    Article  CAS  Google Scholar 

  9. C. Vial, S. Poncin, G. Wild and N. Midoux, Chem. Eng. Proc., 40, 135 (2001).

    Article  CAS  Google Scholar 

  10. K. J. Woo, Y. J. Cho, K. I. Kim, Y. Kang and S. D. Kim, HWAHAK KONGHAK, 36, 937 (1998).

    CAS  Google Scholar 

  11. T. J. Lin, K. Tsuchiya and L. S. Fan, AIChE J., 44, 545 (1998).

    Article  CAS  Google Scholar 

  12. R. Pohorecki, W. Moniuk, A. Zdrojkowski and P. Bielski, Chem. Eng. Sci., 56, 1167 (2001).

    Article  CAS  Google Scholar 

  13. Y. J. Cho, P. S. Song, S. H. Kim, Y. Kang and S. D. Kim, J. Chem. Eng. of Japan, 34, 254 (2001).

    Article  CAS  Google Scholar 

  14. Y. J. Cho, K. J. Woo, Y. Kang and S. D. Kim, Chem. Eng. Pro., 41, 699 (2002).

    Article  CAS  Google Scholar 

  15. L. T. Fan, Y. Kang, M. Yashima and D. Neogi, Chem. Eng. Comm., 135, 147 (1995).

    Article  CAS  Google Scholar 

  16. Y. Kang, K. J. Woo, M. H. Ko, Y. J. Cho and S. D. Kim, Korean J. Chem. Eng., 16, 784 (1999).

    Article  CAS  Google Scholar 

  17. L. S. Fan, Butterworths, MA (1989).

  18. Y. Kang and S.D. Kim, Ind. Eng. Chem. Process Des. Dev., 25, 717 (1986).

    Article  CAS  Google Scholar 

  19. J. Zahradnik, M. Fialova, M. Ruzicka, J. Drahos, F. Kastanek and N. H. Thomas, Chem. Eng. Sci., 52, 3811 (1997).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yung-Zun Cho.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cho, YZ., Yang, HC. & Kang, Y. Two phase (air-molten carbonate salt) flow characteristics in a molten salt oxidation reactor. Korean J. Chem. Eng. 26, 828–832 (2009). https://doi.org/10.1007/s11814-009-0138-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11814-009-0138-2

Key words

Navigation