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Preparation, characterization, and catalytic activity of H5PMo10V2O40 immobilized on nitrogen-containing mesoporous carbon (PMo10V2/N-MC) for selective conversion of methanol to dimethoxymethane

  • Catalysis, Reaction Engineering, Industrial Chemistry
  • Published:
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Abstract

Nitrogen-containing mesoporous carbon (N-MC) was synthesized by a templating method using SBA-15 and polypyrrole as a templating agent and a carbon precursor, respectively. The N-MC was then modified to have a positive charge, and thus, to provide a site for the immobilization of [PMo10V2O40]5−. By taking advantage of the overall negative charge of [PMo10V2O40]5−, H5PMo10V2O40 (PMo10V2) catalyst was chemically immobilized on the N-MC support as a charge-matching component. Characterization results showed that nitrogen in the N-MC played an important role in forming a nitrogen-derived functional group (amine group), and PMo10V2 catalyst was finely and chemically immobilized on the nitrogen-derived functional group of N-MC support. In the vapor-phase selective conversion of methanol, the PMo10V2/N-MC catalyst showed a higher conversion of methanol than the bulk PMo10V2 catalyst. Furthermore, the PMo10V2/N-MC catalyst showed a higher selectivity for dimethoxymethane (a product formed by bifunctional oxidation-acid-acid catalysis) and a higher selectivity for methylformate (a product formed by bifunctional oxidation-acid-oxidation catalysis) than the PMo10V2 catalyst. Reaction pathway for selective conversion of methanol to dimethoxymethane over PMo10V2/N-MC catalyst could be controlled by changing the methanol feed rate.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Gwanak-gu, Seoul, 151-744, Korea

    Heesoo Kim, Dong Ryul Park, Sunyoung Park, Ji Chul Jung & In Kyu Song

  2. Korea Research Institute of Chemical Technology, Daejeon, 305-600, Korea

    Sang-Bong Lee

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  1. Heesoo Kim
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  2. Dong Ryul Park
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  3. Sunyoung Park
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  4. Ji Chul Jung
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  5. Sang-Bong Lee
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  6. In Kyu Song
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Correspondence to In Kyu Song.

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Kim, H., Park, D.R., Park, S. et al. Preparation, characterization, and catalytic activity of H5PMo10V2O40 immobilized on nitrogen-containing mesoporous carbon (PMo10V2/N-MC) for selective conversion of methanol to dimethoxymethane. Korean J. Chem. Eng. 26, 660–665 (2009). https://doi.org/10.1007/s11814-009-0110-1

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  • DOI: https://doi.org/10.1007/s11814-009-0110-1

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