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Oxidation of cyclopentene catalyzed by tungsten-substituted molybdophosphoric acids

  • Catalysis, Reaction Engineering, Industrial Chemistry
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Abstract

A series of Keggin type tungsten-substituted molybdophosphoric acids (H3PMo12−n W n O40·XH2O) were synthesized and characterized by ICP-AES, FT-IR, TG-DSC, and XRD. The tungsten substitution extent significantly affected their catalytic activity in the oxidation of cyclopentene and the selectivity of the resultant products. The tungsten-substituted molybdophosphoric acids with tungsten substitution numbers in a range of 3–6.8 exhibited high catalytic activity in the oxidation of cyclopentene. After reaction for 8 h, the conversion of cyclopentene was up to 97%; the oxidation products mainly consisted of glutaraldehyde, cis-1,2-cyclopentanediol and trans-1,2-cyclopentanediol with the yields of ca. 23%, 27%, and 45%, respectively.

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Authors and Affiliations

  1. Faculty of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, P. R. China

    Jinjuan Xue, Hengbo Yin, Haixia Li, Dongzhi Zhang, Tingshun Jiang, Longbao Yu & Yutang Shen

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  1. Jinjuan Xue
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  2. Hengbo Yin
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  3. Haixia Li
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  4. Dongzhi Zhang
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  5. Tingshun Jiang
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  6. Longbao Yu
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  7. Yutang Shen
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Correspondence to Hengbo Yin.

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Xue, J., Yin, H., Li, H. et al. Oxidation of cyclopentene catalyzed by tungsten-substituted molybdophosphoric acids. Korean J. Chem. Eng. 26, 654–659 (2009). https://doi.org/10.1007/s11814-009-0109-7

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  • DOI: https://doi.org/10.1007/s11814-009-0109-7

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