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Comparison of fractal properties of porous structures during coal devolatilization

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Abstract

This paper investigates fractal property changes of pore structures during coal devolatilization. Similar to char pores, coal pores can also be classified as micro pores and macro pores based on their fractal dimensions. The specific surface area and fractal dimension of micro pores in coal particles are basically unchanged after devolatilization. However, the specific surface area and fractal dimension of macro pores, which are key factors in char combustion, are increased after devolatilization. In fact, the fractal dimensions are basically doubled. These parameters will affect another fractal geometrical factor β in char pores that is correlated to char combustion rate. Since the rate of char combustion can be predicted from their fractal pore properties, it may be possible to predict char combustion directly from the properties of their parent coal pores in the future.

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References

  1. C. R. Clarkson and R. M. Bustin, Fuel, 78, 1333 (1999).

    Article  CAS  Google Scholar 

  2. B. Feng and K. B. Suresh, Carbon, 41, 507 (2003).

    Article  CAS  Google Scholar 

  3. M. Koichi, A. Hiroyuki, W. C. Xu, G. Rajender, F. W. Terry and T. Akira, Fuel, 84, 63 (2005).

    Article  Google Scholar 

  4. B. Ruiz, J. B. Parra, J. A. Pajarea and L. J. Pis, J. Anal. Appl. Pyrolysis, 58, 873 (2001).

    Article  Google Scholar 

  5. P. K. Singla, S. Miura, R. R. Hudgins and P. L. Silveston, Fuel, 62, 645 (1983).

    Article  CAS  Google Scholar 

  6. R. Zajdlik, L. Jelemensky, B. Remiarova and J. Markos, Chem. Eng. Sci., 56, 1355 (2001).

    Article  CAS  Google Scholar 

  7. D. Avnir, D. Farin and P. Pfeifer, J. Colloid Interface Sci., 103, 112 (1985).

    Article  CAS  Google Scholar 

  8. W. I. Friesen and R. J. Mikula, J. Colloid Interface Sci., 120, 263 (1987).

    Article  CAS  Google Scholar 

  9. W. I. Friesen and O. I. Ogunsola, Fuel, 74, 604 (1995).

    Article  CAS  Google Scholar 

  10. P. J. McMahon, I. K. Snook and W. Treimer, J. Colloid Interface Sci., 252, 177 (2002).

    Article  CAS  Google Scholar 

  11. A. C. Mitropoulos, J. M. Haynes, R. M. Richardson, T. A. Steriotis, A. K. Stubos and N. K. Kanellopoulos, Carbon, 34, 775 (1996).

    Article  CAS  Google Scholar 

  12. T. Nakagawa, K. Nishikawa and I. Komaki, Carbon, 37, 520 (1999).

    Article  CAS  Google Scholar 

  13. T. Nakagawa, I. Komaki, M. Sakawa and K. Nishikawa, Fuel, 79, 1341 (2000).

    Article  CAS  Google Scholar 

  14. P. Salatino and F. Zimbardi, Carbon, 32, 51 (1994).

    Article  CAS  Google Scholar 

  15. S. Hu, M. Li, J. Xiang, L. S. Sun, P. S. Li, S. Su and X. X. Sun, Fuel, 83, 1307 (2004).

    Article  Google Scholar 

  16. R. He, X. C. Xu, C. H. Chen, H. Fan and B. Zhang, Fuel, 78, 1291 (1998).

    Article  Google Scholar 

  17. P. Ehrburger, F. Louys and J. Lahaye, Carbon, 27, 389 (1989).

    Article  CAS  Google Scholar 

  18. P. L. J. Walker, Carbon, 28, 261 (1990).

    Article  CAS  Google Scholar 

  19. R. He, J. Sato and C. H. Chen, Combust. Sci. Technol., 174, 19 (2002).

    Article  CAS  Google Scholar 

  20. S. S. Park and H. Y. Kang, Korean J. Chem. Eng., 23, 367 (2006).

    Article  CAS  Google Scholar 

  21. K. H. Lee, S. Y. Kim and K. P. Yoo, Korean J. Chem. Eng., 11, 131 (1994).

    Article  CAS  Google Scholar 

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Correspondence to Rong He.

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Wang, X., He, R. Comparison of fractal properties of porous structures during coal devolatilization. Korean J. Chem. Eng. 24, 466–470 (2007). https://doi.org/10.1007/s11814-007-0081-z

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  • DOI: https://doi.org/10.1007/s11814-007-0081-z

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