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A multilayer study of pCO2 in the surface waters of the Yellow and South China Seas in spring and the sea-air carbon dioxide flux

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Abstract

A multilayer study of pCO2 for the Yellow and South China Seas in the surface waters was conducted based on data from four cruises sponsored by the China SOLAS Project in 2005 and 2006, including data for the surface microlayer (SML), subsurface layer (SSL) and surface layer (SL). The carbon fluxes across the air-sea interface were calculated. The results showed that the pCO2 values in the surface waters of the study area decreased in the following order: pCO2 SML > pCO2 SSL > pCO2 SL. The highest values were found in March for all SML, SSL and SL, followed by those in April, and the lowest were in May. The pCO2 values had a significant positive correlation with temperature or salinity. While there was no relationship between pCO2 and longitude, there was a significant negative correlation between it and latitude, i.e., ‘high latitude low pCO2’. By using four calculation models, the carbon dioxide fluxes (\( F_{CO_2 } \) ) in spring in the Yellow and South China Seas, which were found to act as a ‘sink’ of atmospheric CO2, were preliminarily estimated on the basis of the pCO2 data in the SML to be −7.00×106t C and −22.35×106t C, respectively. It is suggested that the \( F_{CO_2 } \) calculated on the basis of pCO2 data in the SML is more reliable than that calculated on the basis of those in the SL.

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References

  • Cai, W. J., L. R. Pometoy, and M. A. Moran, 1999. Oxygen and carbon dioxide mass balance in the estuarine/intertidal marsh complex of five rivers in the Southeastern U. S. Limnol. Oceanog., 44: 639–649.

    Google Scholar 

  • Cai, W. J., and Y. Wang, 1998. The chemistry fluxes and sources of carbon dioxide in the estuarine waters of the Satilla and Altamaha Rivers, Georgia. Limnol. Oceanog., 43: 657–668.

    Google Scholar 

  • Cai, W. J., and M. H. Dai, 2004. Comment on ‘Enhanced open ocean storage of CO2 from shelf sea pumping’. Science, 306: 1477c.

    Article  Google Scholar 

  • DeGrandpre, M. D., G. J. Olbu, and C. M. Beatty, 2002. Air-sea CO2 fluxes on the US Middle Atlantic Bight. Deep-Sea Res. II, 49: 4355–4367.

    Article  Google Scholar 

  • Dickson, A. G., and F. J. Millero, 1987. A comparison of the equilibrium constants for the dissociation of carbonic acid in seawater media. Deep-Sea Research II, 34: 1733–1743.

    Article  Google Scholar 

  • Johnson, K. M., A. G. Dickson, and G. Eischeid, 1998. Coulmetric total carbon dioxide analysis for marine studies: assessment of the quality of total inorganic carbon measurements made during the US Indian Ocean CO2 survey 1994–1996. Mar. Chem., 63: 21–37.

    Article  Google Scholar 

  • Keir, R. S., G. Rehder, and M. Frankignoulle, 2001. Partial pressure and air-sea flux of CO2 in the Northeast Atlantic during September 1995. Deep-Sea Res. II, 48: 3179–3189.

    Article  Google Scholar 

  • Liss, P. S., and L. Merlivat, 1986. Air-sea gas exchange rates: introduction and synthesis, In: The Role of Air-Sea Exchange in Geochemical Cycling. Buat-Menard, P., and Reidel, D., eds., Norwell, Mass, 113–127.

  • Mehrbach, C., C. H. Culberson, and J. E. Hawley, 1973. Measurement of the apparent dissociation constants of carbonic acid in seawater at atmospheric pressure. Limnol. Oceanog., 18(6): 897–907.

    Article  Google Scholar 

  • Millero, F. J., A. G. Dickson, and G. Eischeid, 1998. Assessment of the quality of the shipboard measurements of total alkalinity on the WOCE Hydrographic Program Indian Ocean CO2 survey cruises 1994–1996. Mar. Chem., 63: 9–20.

    Article  Google Scholar 

  • Peng, T. H., and T. Takahashi, 1989. Carbon Dioxide in the Ocean. Under contract PE-ACO5-840R31400, Environmental Sciences Division, ORNL, 1-10.

  • Sabine, C. L., R. A. Feely, and N. Cruber, 2004. The oceanic sink for anthropogenic CO2. Science, 305: 367–371.

    Article  Google Scholar 

  • Sun, Y. M., and J. M. Song, 2002. Advances in Biogeochemical Process Research on Marine Carbon Cycles in China (1998–2002). Adv. Mar. Sci., 20(3): 110–116 (in Chinese).

    Google Scholar 

  • Tans, P. P., I. Y. Fung, and T. Takahashi, 1990. Observational constrains on the global atmospheric CO2 budget. Science, 247: 1431–1438.

    Article  Google Scholar 

  • Wang, F., L. J. Zhang, and J. Zhang, 2002. A preliminary study of pCO2 in surface water of the southern Yellow Sea in summer. J. Ocean Univ. Qingdao. 32(6): 1007–1011 (in Chinese).

    Google Scholar 

  • Wang, S. L., C. T. A. Chen, and G. H. Hong, 2000. Carbon dioxide and related parameters in the East China Sea. Cont. Shelf Res., 20: 525–544.

    Article  Google Scholar 

  • Wanninkhof, R. H., 1992, Relationship between gas exchange and wind speed over the ocean. J. Geophy. Res., 97(C5):7373–7381.

    Article  Google Scholar 

  • Yool, A., and M. J. R. Fasham, 2001. An examination of the ‘continental shelf pump’ in an open ocean general circulation mode. Glob. Biogeochem. Cycl., 15: 831–844.

    Article  Google Scholar 

  • Zhang, Z. B., W. J. Cai, and L. S. Liu, 2003a. Physicochemistry Studies on the Sea surface microlayer III, Direct determination of thickness of sea surface microlayer using a pH microelectrode at original location. Sci. China (Series B), 46(4):339–351.

    Article  Google Scholar 

  • Zhang, Z. B., L. S. Liu, and C. Y. Liu, 2003b. Physicochemistry Studies on the Sea surface microlayer II, The layer of sudden change of physical and chemical properties. J. Colloid Interf. Sci., 264: 148–159.

    Article  Google Scholar 

  • Zhang, Z. B., L. S. Liu, and Z. J. Wu, 1998. Physicochemistry Studies of the Sea surface microlayer, I. Thickness of the Sea surface microlayer and its experiment determination. J. Colloid Interf. Sci., 204(2): 294–299.

    Article  Google Scholar 

  • Zhang, Z. B., G. P. Yang, and Liu. L. S, 1997. A new suggestion on the flux of matter in the air-sea interface. Chin. Sci. Bull., 42(9): 943–94.

    Google Scholar 

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Correspondence to Chunying Liu.

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Liu, C., Zhang, C., Yang, X. et al. A multilayer study of pCO2 in the surface waters of the Yellow and South China Seas in spring and the sea-air carbon dioxide flux. J. Ocean Univ. China 7, 263–268 (2008). https://doi.org/10.1007/s11802-007-0263-2

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  • DOI: https://doi.org/10.1007/s11802-007-0263-2

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