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Utilization of aluminum hydroxide waste generated in fluoride adsorption and coagulation processes for adsorptive removal of cadmium ion

  • Jiawei Ju
  • Ruiping Liu
  • Zan He
  • Huijuan Liu
  • Xiwang Zhang
  • Jiuhui Qu
Research Article

Abstract

Although Al-based coagulation and adsorption processes have been proved highly efficient for fluoride (F) removal, the two processes both generate large amount of Al(OH)3 solid waste containing F (Al(OH)3-F). This study aimed to investigate the feasibility of utilizing Al(OH)3-F generated in Al(OH)3 adsorption (Al(OH)3-Fads) and coagulation (Al(OH)3-Fcoag) for the adsorption of cadmium ion (Cd(II)). The adsorption capacity of Al(OH)3-Fads and Al(OH)3-Fcoag for Cd(II) was similar as that of pristine aluminum hydroxide (Al(OH)3), being of 24.39 and 19.90 mg·g–1, respectively. The adsorption of Cd(II) onto Al(OH)3-Fads and Al(OH)3-Fcoag was identified to be dominated by ion-exchange with sodium ion (Na+) or hydrogen ion (H+), surface microprecitation, and electrostatic attraction. The maximum concentration of the leached fluoride from Al(OH)3-Fads and Al(OH)3-Fcoag is below the Chinese Class-I IndustrialWastewater Discharge Standard for fluoride (<10 mg·L–1). This study demonstrates that the Al(OH)3 solid wastes generated in fluoride removal process could be potentially utilized as a adsorbent for Cd(II) removal.

Keywords

Al(OH)3 fluoride cadmium adsorption reclamation sequential extraction 

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Supplementary material

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© Higher Education Press and Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Jiawei Ju
    • 1
    • 2
  • Ruiping Liu
    • 1
  • Zan He
    • 1
    • 2
  • Huijuan Liu
    • 1
  • Xiwang Zhang
    • 3
  • Jiuhui Qu
    • 1
  1. 1.State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijingChina
  2. 2.University of Chinese Academy of SciencesBeijingChina
  3. 3.Department of Chemical EngineeringMonash UniversityClaytonAustralia

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