Abstract
A new densification method of chemical manganese dioxide (CMD)-NaMnO4 densification has been developed. This MnO2 produced by NaMnO4 oxidation possessed γ-type structure. After the crude MnO2 was densified, the tap density of the MnO2 powder could be increased from 1.2 to 2.0 g/cm3. The discharge capacity is higher than that densified by other oxidizers.
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Fernandes Julio B. Studies on chemically precipitated Mn (IV) oxides. Electrochemica Acta, 1983, 28(3). 309–315
Isao Tanabe. The synthesis of densified CMD from Mn-NH4-carbonate and its discharge properties in ZnCl2 batteries. J Electrochem Soc, 1982(10):2372–2377
Isao Tanabe, Nobuaki Miyamoto, Tooru Nagaura. Synthesis of γ-type CMD from dense MnCO3. J Electrochem Soc, 1987(12):2945–2950
Kanungo S B. Relationship between physicochemical properties and electrochemical activity of some synthetic MnO2. Electrochemica Acta, 1981, 26(8), 1147–1156
Kozawa A, Powers R A. Cathode reduction of β-MnO2 and γ-MnO2 in NH4Cl and KOH electrolytes. Electrochemical Technology, 1967,5(11–12):535–541
Balewski L, Brenet J P. A new method for the study of the electrochemical reactivity of manganese dioxide. Electrochemical Technology, 1967,5(11–12):527–531
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Synopsis of the first author Wang Chenggang, associate professor, born in 1955, now in Department of Metallurgy in Xi’an University of Arch. Tech., majoring in metallurgy of nonferrous metals and mathematic modeling of metallurgical processes.
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Wang, C., Zhao, Q. Study on densification of chemical manganese dioxide for batteries. J Cent. South Univ. Technol. 5, 93–95 (1998). https://doi.org/10.1007/s11771-998-0044-5
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DOI: https://doi.org/10.1007/s11771-998-0044-5