Abstract
Mercury-free zinc-alloy powder were electrodeposited from alkaline solution. Additives containing lead, indium or bismuth were added in the electrolyte and zinc powders with corresponding compositions were obtained. The relations between adding amounts of additives and the contents of corresponding compositions in zinc powder are not linear. Aluminum and calcium cannot be co-deposited with zinc. Electrodeposition effectively reduced the contents of harmful impurities. Gas evolution of electrodeposited Zn-Pb-In-Bi alloy powder was less than that of atomized mercury-free alloy powder.
Similar content being viewed by others
References
Feng Shaobin, Dong Huichao, Xia Tongchi, et al. A study of electrolytic technology for corrosion-resistant zinc-alloy powder. Battery, 1993, 23(20): 55
Mcbreen J, Gannon E. Bismuth oxide as an additive in pasted zinc electrodes. J Powder Source, 1985, 15: 169
Toyohide Uemura, Tomotaka Motomura, Tomiko Yamaguchi, et al. Zinc alloy powder for alkaline cell and method for production of the same. US Patent, 5 312476
Xu Xiangquan. Progress in development of mercury-free zinc powder. Battery, 1994, 24(4): 184
Author information
Authors and Affiliations
Additional information
Project supported by the Key Program of Hunan Province
Synopsis of the first author Li Xinhai, professor, born in 1962, mainly specializing in powder source materials and high-energy chemical powder source.
Rights and permissions
About this article
Cite this article
Li, X., Liang, J. & Guo, B. Electrodeposition of corrosion-resistant zinc-alloy powder from alkaline solution. J Cent. South Univ. Technol. 5, 75–78 (1998). https://doi.org/10.1007/s11771-998-0039-2
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11771-998-0039-2