Skip to main content
Log in

Isothermal kinetics of the first stage reduction of magnetite cold bond pellets with carbon monoxide

  • Published:
Journal of Central South University of Technology Aims and scope Submit manuscript

Abstract

The reduction of Fe3O4 to Fe is accomplished in two stages. In order to understand the reduction mechanism of magnetite cold bond pellets during the first period of heating-up process, it is necessary to study the kinetics of the reaction. In this work, the first stage of reduction of magnetite cold bond pellets, that is the reduction from Fe3O4 to FeO, has been investigated using an isothermal thermogravimetric method. Isothermal experiments were carried out at 750°C, 800°C, 850°C and 900°C, respectively. The results showed that the reaction was controlled by chemical reaction below 800°C, whereas, at higher temperature, it was controlled by a mixed controlled mechanism of chemical reaction and Ginstling-Brounshtein diffusion as well.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Murayama T, Ono Y, Kawai Y. Step-wise reduction of bematite pellets with CO-CO2 gas mixtures. J Iron Steel Inst Jpn, 1977, 63(7): 1099–1107

    Google Scholar 

  2. Ray H S, Kundu N. Thermal analysis studies on the initial stages of iron oxide reduction. Thermochim Acta, 1986, 101: 107–118

    Article  Google Scholar 

  3. Paul S, Mukherjee S. Non-isothermal and isothermal reduction kinetics of iron ore agglomerates. Ironmaking and Steelmaking, 1992, 19(3): 190–193

    Google Scholar 

  4. Ray A K, Prasad K K, Sen P K. Kinetics of reduction of iron ore with carbon monoxide. Trans India Inst Met, 1994, 47(4): 215–219

    Google Scholar 

  5. Trujic V, Markotic A. Thermogravimetric and laboratory investigations of magnetite concentrate reduction by solid reducers. Transactions of the ISS, 1991(1): 51–57

  6. Kiselve V A, Permyakova L I, Leontev L I, et al. The reduction kinetics of ore-carbon pellets prepared from lisakovsk roasted magnetic concentrate. Izv Akad Nauk SSSR Met (in Russian), 1982(6): 33–36

  7. Seaton C E, Foster J S, Velasco J. Reduction kinetics of hematite and magnetite pellets containing coal char. Trans Iron Steel Inst Jpn, 1983, 23(6): 490–496

    Google Scholar 

  8. Gao X, Dollimore D. The thermal decomposition of oxalates. Part 26: A kinetic study of the thermal decomposition of manganese (II) Oxalate dihydrate. Thermochim Acta, 1993, 215: 47–63

    Article  Google Scholar 

  9. Mo Dingcheng. Metallurgical kinetics (in Chinese). Changsha: Central South University of Technology Press, 1987, 193–204

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Project supported by the Nonferrous Metals Industrial Corporation of China

Synopsis of the author Chen Qiyuan, professor, born in 1948. Major research fields: metallurgical thermodynamics and kinetics.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Chen, Q., Zhou, H., Zhang, P. et al. Isothermal kinetics of the first stage reduction of magnetite cold bond pellets with carbon monoxide. J Cent. South Univ. Technol. 5, 1–3 (1998). https://doi.org/10.1007/s11771-998-0020-0

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11771-998-0020-0

Key words

Navigation