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MoSe2@N, P-C composites for sodium ion battery

钠离子电池复合负极材料MoSe2@N,P-C的合成与性能研究

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Abstract

The conversion reaction-based anode materials of sodium ion batteries have relatively high capacity; however, the application of these materials is limited by their structural collapse due to the poor structure stability. In this work, MoSe2 nanosheets were synthesized by a solvothermal method. An organic solvent was intercalated into the MoSe2 materials to enlarge the interlayer spacing and improve the conductivity of the material. The MoSe2 material was coated with an organic pyrolysis carbon and then a uniform carbon layer was formed. The surface carbon hybridization of the nanosheet materials was realized by the introduction of heteroatoms during the sintering process. The as-prepared MoSe2@N, P-C composites showed a superior rate performance as it could maintain the integrity of the morphology and structure under a high current density. The composites had a discharge specific capacity of 302.4 mA·h/g after 100 cycles at 0.5 A/g, and the capacity retention rate was 84.96%.

摘要

在钠离子电池体系中,基于转化反应机理的负极材料具有极高的比容量。然而,这类材料的结 构稳定性差,可能出现结构坍塌,限制其应用。本文采用水热法,合成了MoSe2@N, P-C 复合材料, 作为钠离子电池负极材料。以有机溶剂作为插层剂,扩大MoSe2纳米片的层间距,从而提升其导电能 力,并在后续烧结过程中引入碳源,使MoSe2表面形成独特的碳层,实现纳米材料的表面杂化。这种 方法制备的MoSe2@N, P-C 复合材料表现出优异的倍率性能,在大电流密度下进行充放电仍能维持其 结构稳定。在0.5 A/g 恒定电流密度下循环100 圈后,其放电容量达302.4 mA·h/g,容量保持率为 84.96%。

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Author notes

  1. PENG Tao, LUO Yu-hong contributed equally to this work.

Authors and Affiliations

  1. School of Metallurgy and Environment, Central South University, Changsha, 410083, China

    Tao Peng  (彭涛), Lin-bo Tang  (汤林波), Zhen-jiang He  (贺振江) & Jun-chao Zheng  (郑俊超)

  2. National Engineering Research Center of Low-carbon Nonferrous Metallurgy, Central South University, Changsha, 410083, China

    Tao Peng  (彭涛), Yu-hong Luo  (罗玉红), Lin-bo Tang  (汤林波), Zhen-jiang He  (贺振江) & Jun-chao Zheng  (郑俊超)

  3. Engineering Research Center of Ministry of Education for Advanced Battery Materials, Central South University, Changsha, 410083, China

    Tao Peng  (彭涛), Yu-hong Luo  (罗玉红), Lin-bo Tang  (汤林波), Zhen-jiang He  (贺振江) & Jun-chao Zheng  (郑俊超)

  4. School of Mechanical, Medical and Process Engineering, Queensland University of Technology, Brisbane, Queensland, 4001, Australia

    Cheng Yan  (闫澄)

  5. School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, 450001, China

    Jing Mao  (毛景)

  6. College of Chemistry, Tianjin Normal University, Tianjin, 300387, China

    Ke-hua Dai  (代克华)

  7. School of Chemistry and Chemical Engineering, Jishou University, Jishou, 416000, China

    Xian-wen Wu  (吴贤文)

  8. School of Materials Science and Engineering, Central South University, Changsha, 410083, China

    Yu-hong Luo  (罗玉红)

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  1. Tao Peng  (彭涛)
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Contributions

TANG Lin-bo provided the concept and edited the draft of manuscript. PENG Tao and LUO Yu-hong conducted the literature review and wrote the first draft of the manuscript. HE Zhen-jiang, YAN Cheng, MAO Jing, DAI Ke-hua, WU Xian-wen and ZHENG Jun-chao edited the draft of manuscript.

Corresponding authors

Correspondence to Lin-bo Tang  (汤林波) or Jun-chao Zheng  (郑俊超).

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Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships to influence the work reported in this paper.

Foundation item: Project(51572300) supported by the National Natural Science Foundation of China

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Peng, T., Luo, Yh., Tang, Lb. et al. MoSe2@N, P-C composites for sodium ion battery. J. Cent. South Univ. 29, 2991–3002 (2022). https://doi.org/10.1007/s11771-022-5126-2

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  • DOI: https://doi.org/10.1007/s11771-022-5126-2

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