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Effect of TiC nanoparticle on friction and wear properties of TiC/AA2219 nanocomposites and its strengthening mechanism

TiC 纳米颗粒对TiC/AA2219 纳米复合材料摩擦磨损性能的影响及其强化机理

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Abstract

TiC nanoparticles reinforced 2219 aluminum matrix composites were successfully prepared by ultrasonic casting, followed by forging and T6 heat treatment. The friction and wear properties of the disc-to-column were studied under four separate normal values of 5, 10, 20 and 30 N. The increasing hardness value of the nanocomposite may be attributed to the large amount of TiC (i.e., 1.3 wt.% and 1.7 wt.%) introduced to the composites. The friction coefficient of the nanocomposite decreased with the increase of TiC nanoparticles (0–1.7 wt.%) under the same load. But the wear resistance of the TiC/AA2219 nanocomposite increased by 30%–90% as compared to the 2219 matrix alloy. And it decreased with the increasing load. The composite with 0.9 wt.% TiC produced the best results in terms of friction and wear because of its relatively higher hardness and perfect ability to retain a transfer layer of a comparatively larger thickness. On the wear surface, some Al2O3 particles were found which aided in the development of protective shear regions and improved the wear resistance. The wear mechanism for the TiC/AA2219 nanocomposite was a combination of adhesive and oxidative wear, with the composites containing hard TiC nanoparticles being mainly abrasive.

摘要

采用超声辅助铸造技术成功制造了TiC纳米颗粒增强2219铝基复合材料, 并对其进行锻造和T6热处理. 本文研究了TiC/AA2219纳米复合材料在5、 10、 20 和30 N下的摩擦磨损性能. 研究发现, 引入大量的TiC颗粒(1.3 wt.%和1.7 wt.%)后, 复合材料的硬度明显增加. 在相同载荷下, 纳米复合材料的摩擦系数随着TiC颗粒的增加(0~1.7 wt.%)而降低. 但与2219铝合金基体相比, TiC/AA2219复合材料的抗磨损性提高30%−90%. 复合材料的抗磨损性能随着载荷的增加逐渐减小. 当复合材料内纳米TiC含量为0.9 wt.%时, 由于复合材料具有较高的硬度并有较大的摩擦厚度转移层, 材料具有最好的摩擦磨损性能. 另外, 在磨损表面发现了一些Al2O3颗粒, 这些颗粒有助于形成保护性剪切区并提高材料耐磨性. TiC/AA2219纳米复合材料的主要摩擦机制是黏着磨损和氧化磨损, 其中含有大量硬质TiC颗粒时主要表现为磨料磨损.

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References

  1. YU Tian-yu, LIU Jun-yan, HE Yu, et al. Microstructure and wear characterization of carbon nanotubes (CNTs) reinforced aluminum matrix nanocomposites manufactured using selective laser melting [J]. Wear, 2021, 476: 203581. DOI: https://doi.org/10.1016/j.wear.2020.203581.

    Article  Google Scholar 

  2. DINAHARAN I, NELSON R, VIJAY S J, et al. Microstructure and wear characterization of aluminum matrix composites reinforced with industrial waste fly ash particulates synthesized by friction stir processing [J]. Materials Characterization, 2016, 118: 149–158. DOI: https://doi.org/10.1016/j.matchar.2016.05.017.

    Article  Google Scholar 

  3. LEI Yu-shun, YAN Hong, WEI Zhi-fan, et al. Effect of hot extrusion on microstructure and tribological behavior of Al2O3p reinforced 7075-matrix composites [J]. Journal of Central South University, 2021, 28(8): 2269–2284. DOI: https://doi.org/10.1007/s11771-021-4768-9.

    Article  Google Scholar 

  4. MA Jun, NIU Li-bin, WU Hong, et al. Formation and wear behaviors of in-situ Al3Ti/Al composites using aluminum and titanium fibers under electromagnetic induction heating [J]. Journal of Central South University, 2020, 27(12): 3594–3602. DOI: https://doi.org/10.1007/s11771-020-4500-1.

    Article  Google Scholar 

  5. GUO Bai-song, SONG Min, YI Jian-hong, et al. Improving the mechanical properties of carbon nanotubes reinforced pure aluminum matrix composites by achieving non-equilibrium interface [J]. Materials & Design, 2017, 120: 56–65. DOI: https://doi.org/10.1016/j.matdes.2017.01.096.

    Article  Google Scholar 

  6. WANG Feng, ESKIN D, MI Jia-wei, et al. A synchrotron X-radiography study of the fragmentation and refinement of primary intermetallic particles in an Al-35 Cu alloy induced by ultrasonic melt processing [J]. Acta Materialia, 2017, 141: 142–153. DOI: https://doi.org/10.1016/j.actamat.2017.09.010.

    Article  Google Scholar 

  7. CHEN L Y, XU J Q, CHOI H, et al. Processing and properties of magnesium containing a dense uniform dispersion of nanoparticles [J]. Nature, 2015, 528(7583): 539–543. DOI: https://doi.org/10.1038/nature16445.

    Article  Google Scholar 

  8. ABORKIN A V, ELKIN A I, RESHETNIAK V V, et al. Thermal expansion of aluminum matrix composites reinforced by carbon nanotubes with in situ and ex-situ designed interfaces ceramics layers [J]. Journal of Alloys and Compounds, 2021, 872: 159593. DOI: https://doi.org/10.1016/j.jallcom.2021.159593.

    Article  Google Scholar 

  9. WANG Z J, LIU S, QIU Z X, et al. A study of the microstructure, texture and tensile properties of 1060/Al-TiC/1060 sandwich composites prepared by hot-roll bonding [J]. Metallurgical and Materials Transactions A, 2020, 51(12): 6714–6726. DOI: https://doi.org/10.1007/s11661-020-06044-0.

    Article  Google Scholar 

  10. CUI Wei, XU Hui, CHEN Jian-hao, et al. Effect of graphite powder as a forming filler on the mechanical properties of SiCp/Al composites by pressure infiltration [J]. International Journal of Minerals, Metallurgy, and Materials, 2016, 23(5): 601–607. DOI: https://doi.org/10.1007/s12613-016-1272-6.

    Article  Google Scholar 

  11. ZHANG Shao-yang, WANG Fu-ping. Comparison of friction and wear performances of brake material dry sliding against two aluminum matrix composites reinforced with different SiC particles [J]. Journal of Materials Processing Technology, 2007, 182(1–3): 122–127. DOI: https://doi.org/10.1016/j.jmatprotec.2006.07.018.

    Article  Google Scholar 

  12. HUDA A, SALIHI A, ADIL A M, HUSSAIN J, et al. Mechanical and wear behavior of AA7075 aluminum matrix composites reinforced by Al2O3 nanoparticles [J]. Nanocomposites, 2019, 5(3): 1–7. DOI: https://doi.org/10.1080/20550324.2019.1637576.

    Google Scholar 

  13. MICHAEL RAJAN H B, RAMABALAN S, DINAHARAN I, et al. Effect of TiB2 content and temperature on sliding wear behavior of AA7075/TiB2 in situ aluminum cast composites [J]. Archives of Civil and Mechanical Engineering, 2014, 14(1): 72–79. DOI: https://doi.org/10.1016/j.acme.2013.05.005.

    Article  Google Scholar 

  14. JEROME S, RAVISANKAR B, KUMAR MAHATO P, et al. Synthesis and evaluation of mechanical and high temperature tribological properties of in situ Al-TiC composites [J]. Tribology International, 2010, 43(11): 2029–2036. DOI: https://doi.org/10.1016/j.triboint.2010.05.007.

    Article  Google Scholar 

  15. YANG Yi-long, LIU Zhi-lin, JIANG Ri-peng, et al. Microstructural evolution and mechanical properties of the AA2219/TiC nanocomposite manufactured by ultrasonic solidification [J]. Journal of Alloys and Compounds, 2019, 811: 151991. DOI: https://doi.org/10.1016/j.jallcom.2019.151991.

    Article  Google Scholar 

  16. YANG Yi-long, JIANG Ri-peng, LI Xiao-qian, et al. Effect of nanoparticle content on the microstructural and mechanical properties of forged and heat-treated TiC/2219 nanocomposites [J]. Metals, 2019, 9(9): 982. DOI: https://doi.org/10.3390/met9090982.

    Article  Google Scholar 

  17. NEMATI N, KHOSROSHAHI R, EMAMY M, et al. Investigation of microstructure, hardness and wear properties of Al-4.5 wt.% Cu-TiC nanocomposites produced by mechanical milling [J]. Materials & Design, 2011, 32(7): 3718–3729. DOI: https://doi.org/10.1016/j.matdes.2011.03.056.

    Article  Google Scholar 

  18. SU Hai, GAO Wen-li, FENG Zhao-hui, et al. Processing, microstructure and tensile properties of nano-sized Al2O3 particle reinforced aluminum matrix composites [J]. Materials & Design, 2012, 36: 590–596. DOI: https://doi.org/10.1016/j.matdes.2011.11.064.

    Article  Google Scholar 

  19. SRIVASTAVA N, CHAUDHARI G P. Strengthening in Al alloy nano composites fabricated by ultrasound assisted solidification technique [J]. Materials Science and Engineering A, 2016, 651: 241–247. DOI: https://doi.org/10.1016/j.msea.2015.10.118.

    Article  Google Scholar 

  20. TIAN Wei-si, ZHAO Qing-long, ZHAO Chuan-jiang, et al. The dry sliding wear properties of nano-sized TiC p/Al-Cu composites at elevated temperatures [J]. Materials (Basel, Switzerland), 2017, 10(8): 939. DOI: https://doi.org/10.3390/ma10080939.

    Article  Google Scholar 

  21. VEERAVALLI R R, NALLU R, MOHAMMED MOULANA MOHIUDDIN S. Mechanical and tribological properties of AA7075-TiC metal matrix composites under heat treated (T6) and cast conditions [J]. Journal of Materials Research and Technology, 2016, 5(4): 377–383. DOI: https://doi.org/10.1016/j.jmrt.2016.03.011.

    Article  Google Scholar 

  22. XU Hui, ZHANG Gong-zhen, CUI Wei, et al. Effect of Al2O3sf addition on the friction and wear properties of (SiCp+ Al2O3sf)/Al2024 composites fabricated by pressure infiltration [J]. International Journal of Minerals, Metallurgy, and Materials, 2018, 25(3): 375–382. DOI: https://doi.org/10.1007/s12613-018-1581-z.

    Article  Google Scholar 

  23. KARUN A S, RAJAN T, PILLAI U, et al. Enhancement in tribological behaviour of functionally graded SiC reinforced aluminium composites by centrifugal casting [J]. Journal of Composite Materials, 2016, 50(16): 2255–2269. DOI: https://doi.org/10.1177/0021998315602946.

    Article  Google Scholar 

  24. LI Song-mei, YU Xiu-mei, LIU Jian-hua, et al. Microstructure and abrasive wear behavior of anodizing composite films containing SiC nanoparticles on Ti6Al4V alloy [J]. Journal of Central South University, 2014, 21(12): 4415–4423. DOI: https://doi.org/10.1007/s11771-014-2443-0.

    Article  Google Scholar 

  25. YIGEZU B S, JHA P K, MAHAPATRA M M. Effect of sliding distance, applied load, and weight percentage of reinforcement on the abrasive wear properties of in situ synthesized Al-12%Si/TiC composites [J]. Tribology Transactions, 2013, 56(4): 546–554. DOI: https://doi.org/10.1080/10402004.2013.767401.

    Article  Google Scholar 

  26. HUANG Pao-chang, HOU K H, HONG Jia-jun, et al. Study of fabrication and wear properties of Ni-SiC composite coatings on A356 aluminum alloy [J]. Wear, 2021, 477: 203772. DOI: https://doi.org/10.1016/j.wear.2021.203772.

    Article  Google Scholar 

  27. MUNAGALA V N V, TORGERSON T B, SCHARF T W, et al. High temperature friction and wear behavior of cold-sprayed Ti6Al4V and Ti6Al4V-TiC composite coatings [J]. Wear, 2019, 426–427: 357–369. DOI: https://doi.org/10.1016/j.wear.2018.11.032.

    Article  Google Scholar 

  28. SARDAR S, KARMAKAR S K, DAS D. High stress abrasive wear characteristics of Al7075 alloy and 7075/Al2O3 composite [J]. Measurement, 2018, 127: 42–62. DOI: https://doi.org/10.1016/j.measurement.2018.05.090.

    Article  Google Scholar 

  29. ROSENBERGER M R, SCHVEZOV C E, FORLERER E. Wear of different aluminum matrix composites under conditions that generate a mechanically mixed layer [J]. Wear, 2005, 259(1–6): 590–601. DOI: https://doi.org/10.1016/j.wear.2005.02.003.

    Article  Google Scholar 

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Authors

Contributions

YANG Yi-long provided the concept, carried out the experiments, performed data analysis, and edited the draft of manuscript. ZHANG Yun carried out part of the experiments, edited the draft of manuscript, replied to reviews’ comments, and revised the final version. ZHANG Hao-ming, LIU Xu-he offered some valuable suggestions for the contents of the manuscript. LI Xiao-qian designed the project.

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Correspondence to Yun Zhang  (张昀).

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The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Additional information

Foundation item: Project(2020RC2002) supported by Science and Technology Innovation Program of Hunan Province, China; Project (2021JJ40774) supported by Natural Science Foundation of Hunan Province, China; Project(20A430007) supported by Key Scientific Research Projects of Colleges and Universities in Henan Province, China; Project(212102210032) supported by the Key Scientific and Technological Projects in Henan Province, China; Project(HEU10202117) supported by the Key Laboratory of Superlight Materials Surface Technology, Ministry of Education, China

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Yang, Yl., Zhang, Y., Zhang, Hm. et al. Effect of TiC nanoparticle on friction and wear properties of TiC/AA2219 nanocomposites and its strengthening mechanism. J. Cent. South Univ. 29, 767–779 (2022). https://doi.org/10.1007/s11771-022-4952-6

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