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A new low-bandgap polymer acceptor based on benzotriazole for efficient all-polymer solar cells

苯并三氮唑基窄带隙聚合物受体用于高效全聚合物太阳电池

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Abstract

The rational design of polymer acceptors with strong and broad absorption is critical to improve photovoltaic performance. In this work, a new polymer acceptor PY9-T based on heptacyclic benzotriazole (Y9-C16) as a building block and thiophene unit as the linking unit was synthesized, which exhibited a low bandgap (1.37 eV) and a high extinction coefficient of the neat film (1.44×105 cm−1). When PY9-T was blended with the wide bandgap polymer donor PBDB-T, the all-polymer solar cells (APSCs) showed a high power conversion efficiency (PCE) of 10.45% with both high open circuit voltage of 0.881 V and short-circuit current density of 19.82 mA/cm2. In addition, APSCs based on PY9-T show good thermal stability, as evidenced by slight changes morphologies when annealed at 100 °C. These results suggest that Y9-C16 provides a new building block to develop efficient and stable polymer acceptors.

摘要

合理设计具有强和宽吸收的聚合物受体有助于提高光伏性能。本文以七环苯并三氮唑(Y9-C16) 为构筑单元,噻吩为连接单元合成一个新型聚合物受体材料PY9-T。该受体材料的薄膜具有较低的带 隙(1.37 eV)和较高的消光系数(1.44×105 cm−1)。当PY9-T 与宽带隙聚合物给体PBDB-T 共混时,制备 全聚合物太阳电池(APSC)实现10.45%的高能量转换效率,器件具有0.881 V 的高开路电压和 19.82 mA/cm2 的高短路电流密度。此外,器件在100 °C 退火后,共混膜形貌仅发生微小的变化,表明 APSC 具有好的热稳定性,Y9-C16 为开发高效稳定的聚合物受体提供了新的构筑单元。

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References

  1. YU Gang, GAO J, HUMMELEN J C, WUDI F, HEEGER A J. Polymer photovoltaic cells: Enhanced efficiencies via a network of internal donor-acceptor heterojunctions [J]. Science, 1995, 270(5243): 1789–1791. DOI: https://doi.org/10.1126/science.270.5243.1789.

    Article  Google Scholar 

  2. HALLS J J M, PICHLER K, FRIEND R H, MORATTI S C, HOLMES A B. Exciton dissociation at a poly (p-phenylenevinylene)/CeO heterojunction [J]. Synthetic Metals, 1996, 77(1–3): 277–280. DOI: https://doi.org/10.1016/0379-6779(96)80102-0.

    Article  Google Scholar 

  3. LI Yong-fang, ZOU Ying-ping. Conjugated polymer photovoltaic materials with broad absorption band and high charge carrier mobility [J]. Advanced Materials, 2008, 20(15): 2952–2958. DOI: https://doi.org/10.1002/adma.200800606.

    Article  Google Scholar 

  4. LI Chen, LIU Miao-yin, PSCHIRER N G, BAUMGARTEN M, MÜLLEN K. Polyphenylene-based materials for organic photovoltaics [J]. Chemical Reviews, 2010, 110(11): 6817–6856. DOI: https://doi.org/10.1021/cr100052z.

    Article  Google Scholar 

  5. ZHANG Zhi-guo, YANG Yan-kang, YAO Jia, XUE Ling-wei, CHEN Shan-shan, LI Xiao-jun, MORRISON W, YANG Chang-duk, LI Yong-fang. Constructing a strongly absorbing low-bandgap polymer acceptor for high-performance allpolymer solar cells [J]. Angewandte Chemie International Edition, 2017, 56: 13503–13507. DOI: https://doi.org/10.1002/anie.201707678.

    Article  Google Scholar 

  6. ZHANG Zhi-guo, LI Yong-fang. Polymerized small molecule acceptors for high performance all-polymer solar cells [J]. Angewandte Chemie International Edition, 2020, 60(9): 2–14. DOI: https://doi.org/10.1002/anie.202009666.

    Google Scholar 

  7. WANG Gang, MELKONYAN F S, FACCHETTI A, MARKS T J. All-polymer solar cells: Recent progress, challenges, and prospects [J]. Angewandte Chemie International Edition, 2019, 58(13): 4129–4142. DOI: https://doi.org/10.1002/anie.201808976.

    Article  Google Scholar 

  8. DUAN Chun-hui, DING Li-ming. The new era for organic solar cells: Polymer donors [J]. Science Bulletin, 2020, 65(17): 1422–1424. DOI: https://doi.org/10.1016/j.scib.2020.04.044.

    Article  Google Scholar 

  9. LI Zhao-jun, XU Xiao-feng, ZHANG Wei, MENG Xiang-yi, MA Wei, YARTSEV A, INGANÄS O, ANDERSSON M R, JANSSEN R A J, WANG Er-gang. High performance allpolymer solar cells by synergistic effects of fine-tuned crystallinity and solvent annealing [J]. Journal of the American Chemical Society, 2016, 138(34): 10935–10944. DOI: https://doi.org/10.1021/jacs.6b04822.

    Article  Google Scholar 

  10. ZHOU Liu-yang, HE Xuan, LAU T K, QIU Bei-bei, WANG Tao, LU Xin-hui, LUSZCZYNSKA B, ULANSKI J, XU Shu-tao, CHEN Guo-hui, YUAN Jun, ZHANG Zhi-guo, LI Yong-fang, ZOU Ying-ping. Nonhalogenated solvent-processed all-polymer solar cells over 7.4% efficiency from quinoxaline-based polymers [J]. ACS Applied Materials & Interfaces, 2018, 10(48): 41318–41325. DOI: https://doi.org/10.1021/acsami.8b13949.

    Article  Google Scholar 

  11. YANG Jing, XIAO Bo, TANG Ai-ling, LI Jian-feng, WANG Xiao-chen, ZHOU Er-jun. Aromatic-diimide-based n-type conjugated polymers for all-polymer solar cell applications [J]. Advanced Materials, 2019, 31(45): 1804699. DOI: https://doi.org/10.1002/adma.201804699.

    Article  Google Scholar 

  12. WU Jing-nan, MENG Yuan, GUO Xia, ZHU Lei, LIU Feng, ZHANG Mao-jie. All-polymer solar cells based on a novel narrow-bandgap polymer acceptor with power conversion efficiency over 10% [J]. Journal of Materials Chemistry A, 2019, 7(27): 16190–16196. DOI: https://doi.org/10.1039/c9ta04611a.

    Article  Google Scholar 

  13. YAO Hua-tong, BAI Fu-jin, HU Hua-wei, ARUNAGIRI L, ZHANG Jian-quan, CHEN Yu-zhong, YU Han, CHEN Shang-shang, LIU Tao, LAI J Y L, ZOU Ying-ping, ADE H, YAN He. Efficient all-polymer solar cells based on a new polymer acceptor achieving 10.3% power conversion efficiency [J]. ACS Energy Letters, 2019, 4(2): 417–422. DOI: https://doi.org/10.1021/acsenergylett.8b02114.

    Article  Google Scholar 

  14. FAN Qun-ping, AN Qiao-shi, LIN Yuan-bao, XIA Yu-xin, LI Qian, ZHANG Ming, SU Wen-yan, PENG Wen-hong, ZHANG Chun-feng, LIU Feng, HOU Lin-tao, ZHU Wei-guo, YU Dong-hong, XIAO Min, MOONS E, ZHANG Fu-jun, ANTHOPOULOS T D, INGANÄS O, WANG Er-gang. Over 14% efficiency all-polymer solar cells enabled by a low bandgap polymer acceptor with low energy loss and efficient charge separation [J]. Energy & Environmental Science, 2020, 13(12): 5017–5027. DOI: https://doi.org/10.1039/D0EE01828G.

    Article  Google Scholar 

  15. SUN Hui-liang, YU Han, SHI Yong-qiang, YU Jian-wei, PENG Zhong-xiang, ZHANG Xian-he, LIU Bin, WANG Junwei, SINGH R, LEE J, LI Yong-chun, WEI Zi-xiang, LIAO Qiao-gan, KAN Zhi-peng, YE Long, YAN He, GAO Feng, GUO Xu-gang. A narrow-bandgap n-type polymer with an acceptor-acceptor backbone enabling efficient all-polymer solar cells [J]. Advanced Materials, 2020, 32(43): 2004183. DOI: https://doi.org/10.1002/adma.202004183.

    Article  Google Scholar 

  16. YUAN Jun, ZHANG Yun-qiang, ZHOU Liu-yang, ZHANG Gui-chuan, YIP H L, LAU T K, LU Xin-hui, ZHU Can, PENG Hong-jian, JOHNSON P A, LECLERC M, CAO Yong, ULANSKI J, LI Yong-fang, ZOU Ying-ping. Single-junction organic solar cell with over 15% efficiency using fused-ring acceptor with electron-deficient core [J]. Joule, 2019, 3(4): 1140–1151. DOI: https://doi.org/10.1016/j.joule.2019.01.004.

    Article  Google Scholar 

  17. FENG Liu-liu, YUAN Jun, ZHANG Zhen-zhen, PENG Hong-jian, ZHANG Zhi-Guo, XU Shu-tao, LIU Ye, LI Yong-fang, ZOU Ying-ping. Thieno[3,2-b]pyrrolo-fused pentacyclic benzotriazole-based acceptor for efficient organic photovoltaics [J]. ACS Applied Materials & Interfaces, 2017, 9(37): 31985–31992. DOI: https://doi.org/10.1021/acsami.7b10995.

    Article  Google Scholar 

  18. LIU Sha, YUAN Jun, DENG Wan-yuan, LUO Mei, XIE Yuan, LIANG Quan-bin, ZOU Ying-ping, HE Zhi-cai, WU Hongbin, CAO Yong. High-efficiency organic solar cells with low non-radiative recombination loss and low energetic disorder [J]. Nature Photonics, 2020, 14(5): 300–305. DOI: https://doi.org/10.1038/s41566-019-0573-5.

    Article  Google Scholar 

  19. YUAN Jun, ZHANG Yun-qiang, ZHOU Liu-yang, ZHANG Chu-jun, LAU T K, ZHANG Gui-chuan, LU Xin-hui, YIP H L, SO S K, BEAUPRE S, MAINVILLE M, JOHNSON P A, LECLERC M, CHEN Hong-gang, PENG Hong-jian, LI Yong-fang, ZOU Ying-ping. Fused Benzothiadiazole: A building block for n-type organic acceptor to achieve highperformance organic solar cells [J]. Advanced Materials, 2019, 31(17): 1807577. DOI: https://doi.org/10.1002/adma.201807577.

    Article  Google Scholar 

  20. JIANG Kui, WEI Qing-ya, LAI J Y L, PENG Zheng-xing, KIM H K, YUAN Jun, YE Long, ADE H, ZOU Ying-ping, YAN He. Alkyl chain tuning of small molecule acceptors for efficient organic solar cells [J]. Joule, 2019, 3(12): 3020–3033. DOI: https://doi.org/10.1016/j.joule.2019.09.010.

    Article  Google Scholar 

  21. WEI Qing-ya, LIU Wei, LECLERC M, YUAN Jun, CHEN Hong-gang, ZOU Ying-ping. A-DA’D-A non-fullerene acceptors for high-performance organic solar cells [J]. Science China Chemistry, 2020, 63(10): 1352–1366. DOI: https://doi.org/10.1007/s11426-020-9799-4.

    Article  Google Scholar 

  22. CAO Rui, CHEN Yu, CAI Fang-fang, CHEN Hong-gang, LIU Wei, GUAN Hui-lan, WEI Qing-ya, LI Jing, CHANG Qin, LI Zhe, ZOU Ying-ping. A new chlorinated non-fullerene acceptor based organic photovoltaic cells over 12% efficiency [J]. Journal of Central South University, 2020, 27(12): 3581–3593. DOI: https://doi.org/10.1007/s11771-020-4501-0.

    Article  Google Scholar 

  23. JIA Tao, ZHANG Jia-bin, ZHONG Wen-kai, LIANG Yuanying, ZHANG Kai, DONG Sheng, YING Lei, LIU Feng, WANG Xiao-hui, HUANG Fei, CAO Yong. 14.4% efficiency all-polymer solar cell with broad absorption and low energy loss enabled by a novel polymer acceptor [J]. Nano Energy, 2020, 72: 104718. DOI: https://doi.org/10.1016/j.nanoen.2020.104718.

    Article  Google Scholar 

  24. LUO Mei, ZHOU Liu-yang, YUAN Jun, ZHU Can, CAI Fang-fang, HAI Jie-feng, ZOU Ying-ping. A new nonfullerene acceptor based on the heptacyclic benzotriazole unit for efficient organic solar cells [J]. Journal of Energy Chemistry, 2020, 42: 169–173. DOI: https://doi.org/10.1016/j.jechem.2019.07.002.

    Article  Google Scholar 

  25. YUAN Jun, ZHANG Huo-tian, ZHANG Rui, WANG Yu-ming, HOU Jian-hui, LECLERC M, ZHAN Xiao-wei, HUANG Fei, GAO Feng, ZOU Ying-ping. Reducing voltage losses in the A-DA’D-A acceptor-based organic solar cells [J]. Chem, 2020, 6(9): 2147–2161. DOI: https://doi.org/10.1016/j.chempr.2020.08.003.

    Article  Google Scholar 

  26. ZHOU Hua-xing, YANG Li-qiang, YOU Wei. Rational design of high performance conjugated polymers for organic solar cells [J]. Macromolecules, 2012, 45(2): 607–632. DOI: https://doi.org/10.1021/ma201648t.

    Article  Google Scholar 

  27. LU Lu-yao, ZHENG Tian-yue, WU Qing-he, SCHNEIDER A M, ZHAO Dong-lin, YU Lu-ping. Recent advances in bulk heterojunction polymer solar cells [J]. Chemical Reviews, 2015, 115(23): 12666–12731. DOI: https://doi.org/10.1021/acs.chemrev.5b00098.

    Article  Google Scholar 

  28. YUAN Jun, HUANG Tian-yi, CHENG Pei, ZOU Ying-ping, ZHANG Huo-tian, YANG J L, CHANG Sheng-Yung, ZHANG Zhen-zhen, HUANG Wen-chao, WANG Rui, MENG Dong, GAO Feng, YANG Yang. Enabling low voltage losses and high photocurrent in fullerene-free organic photovoltaics [J]. Nat Commun, 2019, 10: 570. DOI: https://doi.org/10.1038/s41467-019-08386-9.

    Article  Google Scholar 

  29. PROCTOR C M, KIM C, NEHER D, NGUYEN T Q. Nongeminate recombination and charge transport limitations in diketopyrrolopyrrole-based solution-processed small molecule solar cells [J]. Advanced Functional Materials, 2013, 23(28): 3584–3594. DOI: https://doi.org/10.1002/adfm.201202643.

    Article  Google Scholar 

  30. CHEN Xiao-bin, XU Gui-ying, ZENG Guang, GU Hong-wei, CHEN Hai-yang, XU Hai-tao, YAO Hui-feng, LI Yao-wen, HOU Jian-hui, LI Yong-fang. Realizing ultrahigh mechanical flexibility and >15% efficiency of flexible organic solar cells via a “welding” flexible transparent electrode [J]. Advanced Materials, 2020, 32(14): 1908478. DOI: https://doi.org/10.1002/adma.201908478.

    Article  Google Scholar 

  31. MIHAILETCHI V D, WILDEMAN J, BLOM P W. Space-charge limited photocurrent [J]. Physical Review Letters, 2005, 94(12): 126602. DOI: https://doi.org/10.1103/PhysRevLett.94.126602.

    Article  Google Scholar 

  32. BLOM P W M, JONG M J M D, MUNSTER M G V. Electric-field and temperature dependence of the hole mobility in poly (p-phenylene vinylene) [J]. Physical Review B, 1997, 55: 656–659. DOI: https://doi.org/10.1103/PhysRevB.55.R656.

    Article  Google Scholar 

  33. MALLIARAS G G, SALEM J R, BROCK P J, SCOTT C. Electrical characteristics and efficiency of single-layer organic light-emitting diodes [J]. Physical Review B, 1998, 58: 13411–13414. DOI: https://doi.org/10.1103/PhysRevB.58.R13411.

    Article  Google Scholar 

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Funding

Project(21875286) supported by the National Natural Science Foundation of China

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China

    Zhe Li  (李哲), Hong-gang Chen  (陈泓钢), Jun Yuan  (袁俊), Jie Zou  (邹洁), Jing Li  (李静), Hui-lan Guan  (管慧兰) & Ying-ping Zou  (邹应萍)

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  1. Zhe Li  (李哲)
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  2. Hong-gang Chen  (陈泓钢)
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  3. Jun Yuan  (袁俊)
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  5. Jing Li  (李静)
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Contributions

LI Zhe, YUAN Jun and ZOU Ying-ping conceived and directed the experiments. LI Zhe, ZOU Jie, GUAN Hui-lan and LI Jing performed the material synthesis. CHEN Hong-gang performed fabrication of devices. The first draft was written by LI Zhe, YUAN Jun and ZOU Ying-ping revised and edited the manuscript. ZOU Ying-ping supervised this work.

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Correspondence to Ying-ping Zou  (邹应萍).

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Conflict of interest

LI Zhe, CHEN Hong-gang, YUAN Jun, ZOU Jie, LI Jing, GUAN Hui-lan, and ZOU Ying-ping declare that they have no conflict of interest.

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Li, Z., Chen, Hg., Yuan, J. et al. A new low-bandgap polymer acceptor based on benzotriazole for efficient all-polymer solar cells. J. Cent. South Univ. 28, 1919–1931 (2021). https://doi.org/10.1007/s11771-021-4741-7

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