Abstract
The gasification industries make use of biomass residue as feedstock to produce synthesis gas, but the gasification of this waste biomass generates tons of ash everyday. Performance properties and agglomeration behavior of corncob ash (CCA) collected from the gasification of corncobs in a pilot-scale gasification station were investigated by using some experimental methods. Based on the chemical composition results, the agglomeration tendency of CCA from combustion and gasification process was also analyzed. Chemical analysis shows that the fly ash is mainly composed of inorganic matters formed by K, Mg, Ca, Na, Fe, Al, S, etc. The agglomeration characteristics indicate that the slagging degree increases with the increase of ashing temperature, and the slagging tendency of these CCA samples from gasification or combustion is different with various slagging indices. All CCA samples from combustion or gasification can cause slagging/fouling problems in thermal conversion systems. The applications of CCA are closely related to its performances, and CCA has the potential to be used in various fields, for example, as a material for ceramic products and activated carbon, as an adsorbent, as a crude fertilizer, and as a structural material.
Similar content being viewed by others
References
DEMIRBAS A. Biofuels sources, biofuel policy, biofuel economy and global biofuel projections [J]. Energy Conversion and Management, 2008, 49(8): 2016–2116.
NIU Yan-qing, TAN Hong-zhang, WANG Xue-bin, LIU Zheng-ning, LIU Hai-yu, LIU Yang, XU Tong-mo. Study on fusion characteristics of biomass ash [J]. Bioresource Technology, 2010, 101(23): 9373–9381.
WANG Cui-ping, WU Ya-jue, LIU Qing, YANG Hai-rui. Study of the characteristics of the ashing process of straw/coal combustion [J]. Fuel, 2011, 90(9): 2939–2944.
XIAO Rui-rui, CHEN Xue-li, WANG Fu-chen, YU Guang-suo. The physicochemical properties of different biomass ashes at different ashing temperature [J]. Renewable Energy, 2011, 36(1): 244–249.
FANG Xiang, JIA Li. Experimental study on ash fusion characteristics of biomass [J]. Bioresource Technology, 2012, 104: 769–774.
SHARMA S, GHOSHAL A L. Study of kinetics of co-pyrolysis of coal and waste LDPE blends under argon atmosphere [J]. Fuel, 2010, 89(12): 3943–3951.
PAN H, EBERHARDT T L. Characterization of fly ash from the gasification of wood and assessment for its application as a soil amendment [J]. BioResources, 2011, 6(4): 3987–4004.
KILPIMAA S, KUOKKANEN T, LASSI U. Characterization and utilization potential of wood ash from combustion process and carbon residue from gasification process [J]. BioResources, 2013, 8(1): 1011–1127.
DU Sheng-lei, YANG Hai-ping, QIAN Ke-zhen, WANG Xian-hua, CHEN Han-ping. Fusion and transformation properties of the inorganic components in biomass ash [J]. Fuel, 2014, 117: 1281–1287.
KNUDSEN J N, JENSEN P A, DAN-JOHANSEN M. Transformation and release to the gas phase of Cl, K, and S during combustion of annual biomass [J]. Energy Fuels, 2004, 18(5): 1385–1399.
LIU Yuan-yuan, WANG Jia-jia, LIN Xiang, WANG Li-ao, ZHONG Shan, YANG Wei. Microstructures and thermal properties of municipal solid waste incineration fly ash [J]. Journal of Central South University, 2012, 19(3): 855–862.
ABRAHAM R, GEORGE J, THOMAS J, YUSUFF K K M. Physicochemical characterization and possible application of the waste biomass ash from oleoresin industries of India [J]. Fuel, 2013, 109: 366–372.
EL-HENDAWY A N A, SAMRA S E, GIRGIS B S. Adsorption characteristics of activated carbons obtained from corncobs [J]. Colloids and Surfaces A-Physicochemical and Engineering Aspects, 2001, 180(3): 209–221.
ZEVENHOVEN-ONDERWATER M, BACKMAN R, SKRIFVARS B J, HUPA M. The ash chemistry in fluidized bed gasification of biomass fuels. Part I: Predicting the chemistry of melting ashes and ash-bed material interaction [J]. Fuel, 2011, 80(10): 1489–1502.
STANISLAV V V, DAVID B, CHRISTINA G V. An overview of the behaviour of biomass during combustion: Part I. Phase-mineral transformations of organic and inorganic matter [J]. Fuel, 2013, 112: 392–449.
WU Peng, YU Chun-jiang, BAI Ji-song, LI Lian-ming, HUANG Fang. Mechanism study of Chlorine release during biomass pyrolysis [J]. Proceedings of the Chinese Society for Electrical Engineering, 2013, 33(11): 75–81. (in Chinese)
CAO Xiao-wei. Biomass entrained-flow gasification characteristics and gasification kinetics of biomass chars [D]. Hangzhou: Zhejiang University, 2007: 73–75. (in Chinese)
TORTOSA MASIA A A, BUHRE B J P, GUPTA R P, WALL T F. Characterising ash of biomass and waste [J]. Fuel Processing Technology, 2007, 88(11): 1071–1081.
SZEMMELVEISZ K, SZUCS I, PALOTAS A B, WINKLER L, EDDINGS E G. Examination of the combustion conditions of herbaceous biomass [J]. Fuel Processing Technology, 2009, 90(6): 839–847.
CHEN Xiao-ping, GU Li-feng, HAN Xiao-ping, ZHAO Chang-sui, LIU Dao-yin. Pyrolysis characteristics and ash fusion property of sludge and blended fuel of sludge and coal [J]. Journal of Southeast University (Natural Science Edition), 2008, 38(6): 1038–1043. (in Chinese)
KRISHNARAO R V, SUBRAHMANYAM J, KUMAR T J. Studies on the formation of black particles in rice husk silica ash [J]. Journal of the European Ceramic Society, 2001, 21(1): 99–104.
ADESANYA D A, RAHEEM A A. A study of the permeability and acid attack of corncob ash blended cements [J]. Construction and Building Materials, 2010, 24(3): 403–409.
ADESANYA D A, RAHEEM A A. Development of corn cob ash blended cement [J], Construction and Building Materials, 2009, 23(1): 347–352.
Author information
Authors and Affiliations
Corresponding author
Additional information
Foundation item: Project(2013020137) supported by the Natural Science Foundation of Liaoning Province, China; Project(2015-36) supported by Rural Energy Comprehensive Construction Foundation of the Ministry of Agriculture, China
Rights and permissions
About this article
Cite this article
Yao, Xw., Xu, Kl. & Li, Y. Experimental investigation of performance properties and agglomeration behavior of fly ash from gasification of corncobs. J. Cent. South Univ. 24, 496–505 (2017). https://doi.org/10.1007/s11771-017-3452-6
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11771-017-3452-6