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Poly(styrene-co-divinylbenzene)-PAMAM-IDA chelating resin: Synthesis, characterization and application for Ni(II) removal in aqueous

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Abstract

PS-PAMAM-IDA chelating resins were prepared by low-generations of polyamidoamine (PAMAM) and then chloroacetic acid functionalizing commercially available ammoniated polystyrene matrix, to preconcentrate Ni2+ from synthetic aqueous samples. Different generations of PAMAM were used to obtain different chelating resins, PS-IDA, PS-1.0G PAMAM-IDA and PS-2.0G PAMAM-IDA. The synthesized resins were characterized by FTIR and elemental analysis. The effect of solution pH, kinetic studies, resin loading capacity, matrix effects etc., on metal ion adsorption to adsorbent phase, were studied by batch method. The PS-1.0G PAMAM-IDA resin was the most excellent adsorbents, with a maximum adsorption capacity of (24.09±1.79) mg/g for Ni2+ ion at pH=7. The interpretation of the equilibrium data was given by Langmuir isotherms model, and the correlation coefficient values for PS-IDA, PS-1.0G PAMAM-IDA and PS-2.0G PAMAM-IDA resins were 0.992, 0.994 and 0.987, respectively.

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References

  1. KOLODYNISKA D, HUBICKI Z, GECA M. Polyaspartic acid as a new complexin agent in removal of heavy metal ions on polystyrene anion exchangers [J]. Ind Eng Chem Res, 2008, 47: 6221–6227.

    Article  Google Scholar 

  2. DEEPATONA A, VALIX M. Recovery of nickel and cobalt from organic acid complexes: Adsorption mechanisms of metal-organic complexes onto aminophosphanate chelating resin [J]. J Hazard Mater B, 2006, 137: 925–933.

    Article  Google Scholar 

  3. SHUKLA S R, PAI R S, SHENDARKAR A D. Adsorption of Ni(II), Zn(II) and Fe(II) on modified coir fibres [J]. Sep Purif Technol, 2006, 47: 141–147.

    Article  Google Scholar 

  4. YUCHI A, SATO T, MORIMOTO Y, MIZUNO H, WADA H. Adsorption mechanism of trivalent metal ions on chelating resins containing iminodiacetic acid groups with reference to selectivity [J]. Anal Chem, 1997, 69: 2941–2944.

    Article  Google Scholar 

  5. PESAVENTO M, BIESUZ R, GALLORINI M, PROFUMO A. Sorption mechanism of trace amounts of divalent metal ions on a chelating resin containing iminodiacetate groups [J]. Anal Chem, 1993, 65: 2522–2527.

    Article  Google Scholar 

  6. MURAVIEV D, GONZALO A, VAIENTE M. Ion exchange on resins with temperature-responsive selectivity. 1. Ion-exchange equilibrium of Cu2+ and Zn2+ on iminodiacetic and aminomethylphosphonic resins [J]. Anal Chem, 1995, 67: 3028–3035.

    Article  Google Scholar 

  7. ATZEI D, FERRI T, SADUN C, SANGIORGIO P, CAMINITI R. Structural characterization of complexes between iminodiacetate blocked on styrene-divinylbenzene matrix (Chelex 100 Resin) and Fe(III), Cr(III), and Zn(II) in solid phase by energy-dispersive X-ray diffraction [J]. J Am Chem Soc, 2001, 123: 2552–2558.

    Article  Google Scholar 

  8. MUMFORD K A, MORTHCOTT K A, SHALLCROSS D C, STEVENS G W, SNAPE I. Development of a two parameter temperature-dependent semi-empirical thermodynamic ion exchange model using binary equilibria with Amberlite IRC 748 resin [J]. Ind Eng Chem Res, 2007, 46: 766–3773.

    Article  Google Scholar 

  9. JONES J W, BRYANT W S, BOSMAN A W, JANSSEN R J, MEIJER E W, GIBSON H W. Crowned dendrimers: pH-Responsive pseudorotaxane formation [J]. J Org Chem, 2003, 68: 2385–2389.

    Article  Google Scholar 

  10. DIALLO M, CHRISTIE S, SWAMINATHAN P, BALOGH L, SHI X, PAPELIS W C, GODDARD W, JOHNSON J. Dendritic chelating agents. 1. Cu (II) binding to ethylene diamine core poly (amidoamine) dendrimers in aqueous solutions [J]. Langmuir, 2004, 20: 2640–2651.

    Article  Google Scholar 

  11. CERONI P, VICINELLI V, MAESTRI M, BALZANI V, LEE S, HEYST J V, GORKA M, VOGTLE F. Luminescent dendrimers as ligands for metal ions [J]. J Organomet Chem, 2004, 689: 4375–4383.

    Article  Google Scholar 

  12. LANG H, MALDONADO S, STEVENSON K J, CHANDLER B D. Titania-supported Pd Au bimetallic catalysts prepared from dendrimer-encapsulated nanoparticle precursors [J]. J Am Chem Soc, 2004, 126: 12949–12956.

    Article  Google Scholar 

  13. MA F, QU R, SUN C, WANG C, JI C, ZHANG Y, YIN P. Adsorption behaviors of Hg(II) on chitosan functionalized by amino-terminated hyperbranched polyamidoamine polymers [J]. J Hazard Mater, 2009, 172: 792–801.

    Article  Google Scholar 

  14. QU Xiang-jin, LI Jin-huan, AI Shi-yun. Studies on the synthesis and property of PAMAM dendrimers [J]. J Shandong Agri Univ (Nat Sci Ed), 2008, 39(3): 429–432. (in Chinese)

    Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China

    Yao-chi Liu  (刘耀驰), Xue-nong Li  (李学农), Chun-zhi Wang  (王春志), Xiu Kong  (孔秀) & Li-zi Zhoug  (周荔子)

  2. Baling Company, China Petroleum & Chemical Corporation, Yueyang, 414000, China

    Xue-nong Li  (李学农) & Chun-zhi Wang  (王春志)

Authors
  1. Yao-chi Liu  (刘耀驰)
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  2. Xue-nong Li  (李学农)
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  3. Chun-zhi Wang  (王春志)
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  4. Xiu Kong  (孔秀)
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  5. Li-zi Zhoug  (周荔子)
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Correspondence to Yao-chi Liu  (刘耀驰).

Additional information

Foundation item: Project(51074192) supported by the National Natural Science Foundation of China

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Liu, Yc., Li, Xn., Wang, Cz. et al. Poly(styrene-co-divinylbenzene)-PAMAM-IDA chelating resin: Synthesis, characterization and application for Ni(II) removal in aqueous. J. Cent. South Univ. 21, 3479–3484 (2014). https://doi.org/10.1007/s11771-014-2325-5

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  • DOI: https://doi.org/10.1007/s11771-014-2325-5

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