Abstract
Brittle pro-eutectoid cementite that forms along prior-austenite in hypereutectoid steels is deleterious to mechanical properties. The optimum process parameters which suppress the formation of pro-eutectoid cementite in hypereutectoid steels with carbon content in the range of 0.8%–1.3% in mass fraction, were investigated. Pro-eutectoid cementite formation is effectively hindered by increasing the deformation temperature and decreasing the amount of strain. Transformation at lower temperatures close to the nose of the cooling-transformation diagram also reduces the tendency of the formation of pro-eutectoid cementite. Control of prior-austenite grain size and grain boundary conditions is important. Due to larger number of nucleation sites, finer prior-austenite grain size results in the acceleration of transformation to pro-eutectoid cementite. However, large prior-austenite and straight boundaries lead to less nucleation sites of pro-eutectoid cementite. The cooling rate and carbon content should be reduced as much as possible. The transformation temperature below 660 °C and the strain of 0.5 at deformation temperature of 850 °C are suggested.
Similar content being viewed by others
References
CHE Lei, GOTOH M, HORIMOTO Y, HIROSE Y. Effect of microstructure of cementite on interphase stress state in carbon steel [J]. Journal of Iron and Steel Research (International), 2007, 14: 31–38.
ZHOU Shu-cai, BAI Chen-guang, LEI Ya, REN Zheng-de, CAO Peng-jun, YANG Zhi-li. Effect of low-frequency rotary electromagnetic-field on solidification structure of continuous casting austenitic stainless steel [J]. Journal of Central South University of Technology, 2009, 16: 360–364.
ZHANG Chao-lei, LIU Ya-zheng, JIANG Chao, XIAO Jin-fu. Effects of niobium and vanadium on hydrogen induced delayed fracture in high strength spring steel [J]. Journal of Iron and Steel Research (International), 2011, 18: 49–53.
MOHRBACHER H. A strategy of avoiding delayed fracture in ultrahigh strength automotive steels by Nb microalloying [J]. Journal of Iron and Steel Research (International), 2011, 18: 893–897.
ZHANG Xiao-dan, ANDREW G, NIELS H, HUANG Xiao-xu, LIU Wei, LIU Qing. Evolution of cementite morphology in pearlitic steel wire during wet wire drawing [J]. Materials Characterization, 2010, 61: 65–72.
SHABASHOV V A, LITVINOV A V, KATAEVA N V, LYASHKOV K A, NOVIKOV S I, TITOVA S G. Formation of boron solid solution in Fe-Ni invar upon severe plastic deformation [J]. The Physics of Metals and Metallography, 2011, 112: 245–255.
DONG Zhi-Hua, CHEN Deng-fu, SONG Li-wei, HU Hui, YANG Xing-lei. High-temperature mechanical properties of shipbuilding steel BC in continuous casting [J]. Journal of Iron and Steel Research (International), 2011, 18: 605–609.
SHABASHOV V A, KORSHUNOV L G, ZAMATOVSKII A E, LITVINOV A V, SAGARADZE V V, KOSITSYNA I I. Deformation-induced dissolution of carbides of the Me(V, Mo)-C type in high-manganese steels upon the friction effect [J]. The Physics of Metals and Metallography, 2012, 113: 914–921.
HAJISAFARI M, NATEGH S, YOOZBASHIZADEH H, EKRAMI A. Improvement in mechanical properties of microalloyed steel 30MSV6 by a precipitation hardening process [J]. Journal of Iron and Steel Research (International), 2013, 20: 66–73.
TYSHCHENKO A I, THEISEN W, OPPENKOWSKI A, SIEBERT S, RAZUMOV O N, SKOBLIK A P, SIROSH V A, PETROV Y N, GAVRILJUK V G. Low-temperature martensitic transformation and deep cryogenic treatment of a tool steel [J]. Materials Science and Engineering A, 2010, 527: 7027–7039.
SMITH C S. Microstructure [J]. Transactions of the American Society of Metals, 1953, 45: 533–575.
FANG Fang, YONG Qi-long, YANG Cai-fu, SU Hang. Microstructure and precipitation behavior in HAZ of V and Ti microalloyed steel [J]. Journal of Iron and Steel Research (International), 2009, 16: 68–72.
FURUHARA T, MAKI T. Variant selection in heterogeneous nucleation on defects in diffusional phase transformation and precipitation [J]. Materials Science and Engineering A, 2001, 312: 145–154.
SHA Qing-yun, HUANG Guo-jian, GUAN Ju, MA Xiao-jun, LI Da-hang. A new route for identification of precipitates on austenite grain boundary in an Nb-V-Ti microalloyed steel [J]. Journal of Iron and Steel Research (International), 2011, 18: 53–57.
TURKDOGAN E T. Activation enthalpy of self-diffusion in pure metals interpreted as a measure of their interatomic force constant [J]. Canadian Metallurgical Quarterly, 2002, 41: 441–449.
ATKINSON A. Wagner theory and short circuit diffusion [J]. Materials Science and Technology, 1988, 4: 1046–1051.
BALLUFFI R W. Grain boundary diffusion mechanisms in metals [J]. Journal of Electronic Materials, 1992, 13: 527–553.
GOUN M, MAUGIS P, DRILLET J. A criterion for the change from fast to slow regime of cementite dissolution in Fe-C-Mn Steels [J]. Journal of Materials Science and Technology, 2012, 28: 728–736.
IZOTOV V I, GETMANOVA M E, FILIPPOV G A, SHISHOV A A, YANDIMIROV A A. Characteristics of deformation and damage in wheel steel with different pearlite dispersions [J]. Metallurgist, 2007, 51: 588–595.
HIRTH J P. Some current topics in dislocation theory [J]. Acta Materialia, 2000, 48: 93–104.
Author information
Authors and Affiliations
Corresponding author
Additional information
Foundation item: Project(51222405) supported by the National Science Foundation for Outstanding Young Scholars of China, Project(51034002) supported by the National Natural Science Foundation of China; Project(132002) supported by the Fok Ying Tong Education Foundation, China; Project(N120502001) supported by the Basic Scientific Research Operation of Center University of China
Rights and permissions
About this article
Cite this article
Guan, Rg., Zhao, Zy., Chao, Rz. et al. Effects of deformation parameters on formation of pro-eutectoid cementite in hypereutectoid steels. J. Cent. South Univ. 21, 1256–1263 (2014). https://doi.org/10.1007/s11771-014-2060-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11771-014-2060-y