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Effects of deformation parameters on formation of pro-eutectoid cementite in hypereutectoid steels

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Abstract

Brittle pro-eutectoid cementite that forms along prior-austenite in hypereutectoid steels is deleterious to mechanical properties. The optimum process parameters which suppress the formation of pro-eutectoid cementite in hypereutectoid steels with carbon content in the range of 0.8%–1.3% in mass fraction, were investigated. Pro-eutectoid cementite formation is effectively hindered by increasing the deformation temperature and decreasing the amount of strain. Transformation at lower temperatures close to the nose of the cooling-transformation diagram also reduces the tendency of the formation of pro-eutectoid cementite. Control of prior-austenite grain size and grain boundary conditions is important. Due to larger number of nucleation sites, finer prior-austenite grain size results in the acceleration of transformation to pro-eutectoid cementite. However, large prior-austenite and straight boundaries lead to less nucleation sites of pro-eutectoid cementite. The cooling rate and carbon content should be reduced as much as possible. The transformation temperature below 660 °C and the strain of 0.5 at deformation temperature of 850 °C are suggested.

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References

  1. CHE Lei, GOTOH M, HORIMOTO Y, HIROSE Y. Effect of microstructure of cementite on interphase stress state in carbon steel [J]. Journal of Iron and Steel Research (International), 2007, 14: 31–38.

    Google Scholar 

  2. ZHOU Shu-cai, BAI Chen-guang, LEI Ya, REN Zheng-de, CAO Peng-jun, YANG Zhi-li. Effect of low-frequency rotary electromagnetic-field on solidification structure of continuous casting austenitic stainless steel [J]. Journal of Central South University of Technology, 2009, 16: 360–364.

    Article  Google Scholar 

  3. ZHANG Chao-lei, LIU Ya-zheng, JIANG Chao, XIAO Jin-fu. Effects of niobium and vanadium on hydrogen induced delayed fracture in high strength spring steel [J]. Journal of Iron and Steel Research (International), 2011, 18: 49–53.

    Article  Google Scholar 

  4. MOHRBACHER H. A strategy of avoiding delayed fracture in ultrahigh strength automotive steels by Nb microalloying [J]. Journal of Iron and Steel Research (International), 2011, 18: 893–897.

    Google Scholar 

  5. ZHANG Xiao-dan, ANDREW G, NIELS H, HUANG Xiao-xu, LIU Wei, LIU Qing. Evolution of cementite morphology in pearlitic steel wire during wet wire drawing [J]. Materials Characterization, 2010, 61: 65–72.

    Article  Google Scholar 

  6. SHABASHOV V A, LITVINOV A V, KATAEVA N V, LYASHKOV K A, NOVIKOV S I, TITOVA S G. Formation of boron solid solution in Fe-Ni invar upon severe plastic deformation [J]. The Physics of Metals and Metallography, 2011, 112: 245–255.

    Article  Google Scholar 

  7. DONG Zhi-Hua, CHEN Deng-fu, SONG Li-wei, HU Hui, YANG Xing-lei. High-temperature mechanical properties of shipbuilding steel BC in continuous casting [J]. Journal of Iron and Steel Research (International), 2011, 18: 605–609.

    Google Scholar 

  8. SHABASHOV V A, KORSHUNOV L G, ZAMATOVSKII A E, LITVINOV A V, SAGARADZE V V, KOSITSYNA I I. Deformation-induced dissolution of carbides of the Me(V, Mo)-C type in high-manganese steels upon the friction effect [J]. The Physics of Metals and Metallography, 2012, 113: 914–921.

    Article  Google Scholar 

  9. HAJISAFARI M, NATEGH S, YOOZBASHIZADEH H, EKRAMI A. Improvement in mechanical properties of microalloyed steel 30MSV6 by a precipitation hardening process [J]. Journal of Iron and Steel Research (International), 2013, 20: 66–73.

    Article  Google Scholar 

  10. TYSHCHENKO A I, THEISEN W, OPPENKOWSKI A, SIEBERT S, RAZUMOV O N, SKOBLIK A P, SIROSH V A, PETROV Y N, GAVRILJUK V G. Low-temperature martensitic transformation and deep cryogenic treatment of a tool steel [J]. Materials Science and Engineering A, 2010, 527: 7027–7039.

    Article  Google Scholar 

  11. SMITH C S. Microstructure [J]. Transactions of the American Society of Metals, 1953, 45: 533–575.

    Google Scholar 

  12. FANG Fang, YONG Qi-long, YANG Cai-fu, SU Hang. Microstructure and precipitation behavior in HAZ of V and Ti microalloyed steel [J]. Journal of Iron and Steel Research (International), 2009, 16: 68–72.

    Article  Google Scholar 

  13. FURUHARA T, MAKI T. Variant selection in heterogeneous nucleation on defects in diffusional phase transformation and precipitation [J]. Materials Science and Engineering A, 2001, 312: 145–154.

    Article  Google Scholar 

  14. SHA Qing-yun, HUANG Guo-jian, GUAN Ju, MA Xiao-jun, LI Da-hang. A new route for identification of precipitates on austenite grain boundary in an Nb-V-Ti microalloyed steel [J]. Journal of Iron and Steel Research (International), 2011, 18: 53–57.

    Article  Google Scholar 

  15. TURKDOGAN E T. Activation enthalpy of self-diffusion in pure metals interpreted as a measure of their interatomic force constant [J]. Canadian Metallurgical Quarterly, 2002, 41: 441–449.

    Article  Google Scholar 

  16. ATKINSON A. Wagner theory and short circuit diffusion [J]. Materials Science and Technology, 1988, 4: 1046–1051.

    Article  Google Scholar 

  17. BALLUFFI R W. Grain boundary diffusion mechanisms in metals [J]. Journal of Electronic Materials, 1992, 13: 527–553.

    Article  Google Scholar 

  18. GOUN M, MAUGIS P, DRILLET J. A criterion for the change from fast to slow regime of cementite dissolution in Fe-C-Mn Steels [J]. Journal of Materials Science and Technology, 2012, 28: 728–736.

    Article  Google Scholar 

  19. IZOTOV V I, GETMANOVA M E, FILIPPOV G A, SHISHOV A A, YANDIMIROV A A. Characteristics of deformation and damage in wheel steel with different pearlite dispersions [J]. Metallurgist, 2007, 51: 588–595.

    Article  Google Scholar 

  20. HIRTH J P. Some current topics in dislocation theory [J]. Acta Materialia, 2000, 48: 93–104.

    Article  Google Scholar 

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Correspondence to C. S. Lee.

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Foundation item: Project(51222405) supported by the National Science Foundation for Outstanding Young Scholars of China, Project(51034002) supported by the National Natural Science Foundation of China; Project(132002) supported by the Fok Ying Tong Education Foundation, China; Project(N120502001) supported by the Basic Scientific Research Operation of Center University of China

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Guan, Rg., Zhao, Zy., Chao, Rz. et al. Effects of deformation parameters on formation of pro-eutectoid cementite in hypereutectoid steels. J. Cent. South Univ. 21, 1256–1263 (2014). https://doi.org/10.1007/s11771-014-2060-y

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  • DOI: https://doi.org/10.1007/s11771-014-2060-y

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