Skip to main content
Log in

Oxidation behaviors of Ni-Cr-Al superalloy foams at 1 000 °C in air

  • Published:
Journal of Central South University Aims and scope Submit manuscript

Abstract

The oxidation behaviors of Ni-16Cr-xAl (x=4.5%, 9.0%, mass fraction) superalloy foams in air at 1 000 °C were investigated. The effects of Al content on the resistance to high temperature oxidation were examined. The oxidation mechanisms of the foams were discussed. The results show that the resistance to the oxidation of the Ni-16Cr-xAl based alloy at 1 000 °C increases with the content of Al increasing from 4.5% to 9.0%. Complex oxide products are formed on the surface of the superalloy foams after the oxidation. Cr2O3 and Al2O3 are the predominant oxides for the scales of the foams with 4.5% Al and 9% Al, respectively. Excellent high temperature oxidation resistance and superior pore conformation stability for the Ni-16Cr-xAl based superalloy foam with 9% Al can be mainly attributed to the formation of relatively continuous and protective Al2O3 oxides on the surface of the foam.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. PEUKERT W. High temperature filtration in the process industry [J]. Filtration & Separation, 1998, 35: 461–464.

    Article  Google Scholar 

  2. TERPSTRA R L, ANDERSON I E, GLEESON B. Development of metallic hot gas filters [C]// 2001 International Conference on Powder Metallurgy and Particulate Materials. New Orleans, USA: Metal Powder Industries Federation, 2001: 84–97.

    Google Scholar 

  3. NIU Y, ZHANG X J, WU Y, GESMUNDO F. The third-element effect in the oxidation of Ni-xCr-7Al (x=0, 5, 10, 15at.%) alloys in 1 atm O2 at 900–1 000 °C [J]. Corros Sci, 2006, 48: 4020–4036.

    Article  Google Scholar 

  4. MORALES-RODRGUEZ A, BRAVO-LEON A, RICHTER G. Influence of oxidation on the high-temperature mechanical properties of zirconia/nickel cermets [J]. Scripta Mater, 2006, 54: 2087–2090.

    Article  Google Scholar 

  5. XIANG Jun-huai, NIU Yan, WU Wei-tao. High temperature scaling of Ni-15Cu-5Al alloy in 1×105 Pa pure oxygen [J]. J Cent South Univ Technol, 2004, 11: 348–352.

    Article  Google Scholar 

  6. WANG S, WU Y, GESMUNDO F, NIU Y. Oxidation of a ternary Ni-10Cr-4Al alloy in 1atm O2 at 900–1 000 °C [J]. Oxid Met, 2008, 69: 299–315.

    Article  Google Scholar 

  7. JANG Chang-hui, KIM D J, KIM D H, SAH I J, RYU W-S, YOO Y-S. Oxidation behaviors of wrought nickel-based superalloys in various high temperature environments [J]. Trans Nonferrous Met Soc China, 2011, 21: 1524–1531.

    Article  Google Scholar 

  8. YOUNG D J, CHYRKIN A, HE J, GRÜNER D, QUADAKKERS W J. Slow transition from protective to breakaway oxidation of Haynes 214 foil at high temperature [J]. Oxid Met, 2013, 79: 405–427.

    Article  Google Scholar 

  9. GIGGINS C S, PETTIT F S. Oxidation of NiCrAl alloys between 1000 and 1200 °C [J]. J Electrochem Soc, 1971, 118: 1782–1790.

    Article  Google Scholar 

  10. WALLWORK G R, HED A Z. Some limiting factors in the use of alloys at high temperatures [J]. Oxid Met, 1971, 3: 171–184.

    Article  Google Scholar 

  11. ANWAR U H. A TEM study of the oxide scale development in Ni-Cr-Al alloys [J]. Corros Sci, 2004, 46: 27–36.

    Article  Google Scholar 

  12. BAUTISTA A, ARAHUETES E, VELASCO F, MORAL C, CALABRÉS R. Oxidation behavior of highly porous metallic components [J]. Oxid Met, 2008, 70: 267–286.

    Article  Google Scholar 

  13. CHOI S-H, KIM S-Y, YUN J-Y, KONG Y-M, KIM B-K, LEE K-A. Effect of pore size on the high temperature oxidation of Ni-Fe-Cr-Al porous metal [J]. Met Mater Int, 2011, 17: 301–307.

    Article  Google Scholar 

  14. MUKHERJEE S K, UPADHYAYA G S. Oxidation behavior of sintered 434L ferritic stainless steel-Al2O3 composites with ternary additions [J]. Oxid Met, 1985, 23: 177–189.

    Article  Google Scholar 

  15. BAUTISTA A, MORAL C, VELASCO F, SIMAL C, GUZMÁN S. Density-improved powder metallurgical ferritic stainless steels for high-temperature applications [J]. J Mater Process Tech, 2007, 189: 344–351.

    Article  Google Scholar 

  16. BAUTISTA A, VELASCO F, CAMPOS M, RABANAL M E, TORRALBA J M. Oxidation behavior at 900 °C of austenitic, ferritic, and duplex stainless steels manufactured by powder metallurgy [J]. Oxid Met, 2003, 59: 373–393.

    Article  Google Scholar 

  17. BAUTISTA A, VELASCO F, ABENOJAR J. Oxidation resistance of sintered stainless steels: Effect of yttria additions [J]. Corros Sci, 2003, 45: 1343–1354.

    Article  Google Scholar 

  18. ZHENG Zhi, JIANG Yao, DONG Hong-xing, TANG Lie-min, HE Yue-hui, HUANG Bai-yun. Environmental corrosion resistance of porous TiAl intermetallic compounds [J]. Trans Nonferrous Met Soc China, 2009, 19: 581–585.

    Article  Google Scholar 

  19. WU C H, GAO W, HYLAND M, GONG H. Characterisation of high temperature corrosion products on FeAl intermetallics by XPS [J]. Corros Sci, 2001, 43: 1891–1903.

    Article  Google Scholar 

  20. WAGNER C D, RIGGS W M, DAVIS L E, MOULDER J F. Handbook of X-ray photoelectron spectroscopy [M]. Eden Prairie: Perkin-Elmer Corporation, 1979: 42–74.

    Google Scholar 

  21. MOULDER J F, CHASTAIN J. Handbook of X-Ray photoelectron spectroscopy [M]. Eden Prairie: MN, 1992: 76–82.

    Google Scholar 

  22. YANG J C, SCHUMANN E, LEVIN I, RUHLE M. Transient oxidation of NiAl [J]. Acta Mater, 1998, 46: 2195–2201.

    Article  Google Scholar 

  23. WAGNER C. Passivity and inhibition during the oxidation of metals at elevated temperatures [J]. Corros Sci, 1965, 5: 751–764.

    Article  Google Scholar 

  24. WOOD G C. High-temperature oxidation of alloys [J]. Oxid Met, 1970, 2: 11–57.

    Article  Google Scholar 

  25. LIU Zhen-yu, GAO Wei, DAHM K L, WANG Fu-hui. Oxidation behaviour of sputter-deposited Ni-Cr-Al micro-crystalline coatings [J]. Acta Mater, 1998, 46: 1691–1700.

    Article  Google Scholar 

  26. BAUTISTA A, GONZÁLEZ-CENTENO A, BLANCO G, GUZMÁN S. Application of EIS to the study of corrosion behaviour of sintered ferritic stainless steels before and after high-temperature exposure [J]. Mater Charact, 2008, 59: 32–39.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yan Wang  (王岩).

Additional information

Foundation item: Project(51134003) supported by the National Natural Science Foundation of China

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tang, Hp., Wang, Y., Liu, Y. et al. Oxidation behaviors of Ni-Cr-Al superalloy foams at 1 000 °C in air. J. Cent. South Univ. 20, 3345–3353 (2013). https://doi.org/10.1007/s11771-013-1858-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11771-013-1858-3

Key words

Navigation