Skip to main content

Surface modification of coconut-based activated carbon by SDS and its effects on Pb2+ adsorption

Abstract

Coconut-based activated carbons were modified with sodium dodecyl sulfate (SDS). The activated carbons, which were modified by different concentrations of SDS, were characterized by acid/base titrations, textural analysis (BET), atomic absorption spectrochemical analysis and Zeta potential measurements. The effects of SDS modification on Pb2+ absorption were studied further. The results indicate that after the modification of SDS, there are new functional groups on the surface of modified activated carbons and the number of functional group has changed remarkably, the total acidity decreases observably, but the total alkalinity increases dramatically. With the increase of surface load with SDS, the Pb2+ adsorption mass of activated carbons increases and the optimal pH for Pb2+ adsorption of the SDS modified activated carbons is 5. The experimental data are simulated better by Freundlich isotherm model for the modified activated carbons, and the experimental data are simulated better by Langmuir isotherm model for unmodified ones.

This is a preview of subscription content, access via your institution.

References

  1. JIA Qi-geng. Application of activated carbon [M]. East China University of Science and Technology Press, 2002: 58–76. (in Chinese)

    Google Scholar 

  2. CHUAH T G, JUMASIAH A, AZNI I, THOMAS C S Y. Rice husk as a potentially low-cost biosorbent for heavy metal and dye removal: An overview [J]. Desalination, 2005, 175(3): 305–316.

    Article  Google Scholar 

  3. SEKAR M, SAKTHI V, RENGARAJ S. Kinetics and equilibrium adsorption study of lead(II) onto activated carbon prepared from coconut shell [J]. Journal of Colloid and Interface Science, 2004, 279(2): 307–313.

    Article  Google Scholar 

  4. VOLESKY B. Biosorption of heavy metals [M]. CRC Press, Florida, 1990, 7: 43.

    Google Scholar 

  5. DIZGE N, AYDINER C, DEMIRBAS E, KOBYA M, KARA S. Adsorption of reactive dyes from aqueous solutions by fly ash: Kinetic and equilibrium studies [J]. Journal of Hazardous Materials, 2008, 150(3): 737–746.

    Article  Google Scholar 

  6. KALAVATHY M H, KARTHIKEYAN T, RAJGOPAL S, MIRANDA L R. Kinetic and isotherm studies of Cu(II) adsorption onto H3PO4-activated rubber wood sawdust [J]. Journal of Colloid and Interface Science, 2005, 292(2): 354–362.

    Article  Google Scholar 

  7. RAO M M, RAMESH A, RAO C P, SESHAIAH K. Removal of copper and cadmium from the aqueous solutions by activated carbon derived from Ceiba pentandra hulls [J]. Journal of Hazardous Materials, 2006, 129(1/2/3): 123–129.

    Google Scholar 

  8. SREEJALEKSHMI K G, ANOOP K K, ANIRUDHAN T S. Adsorption of Pb(II) and Pb(II)-citric acid on sawdust activated carbon: Kinetic and equilibrium isotherm studies [J]. Journal of Hazardous Materials, 2009, 161(2/3): 1506–1513.

    Article  Google Scholar 

  9. LILIANA G G, JUAN C M P. Pb(II) and Cr(VI) adsorption from aqueous solution on activated carbons obtained from sugar cane husk and sawdust [J]. Journal of Analytical & Applied Pyrolysis, 2008, 81(2): 278–284.

    Article  Google Scholar 

  10. MOHAMED F S, KHATER W A, MOSTAFA M R. Characterization and phenols sorptive properties of carbons activated by sulphuric acid [J]. Chemical Engineering Journal, 2006, 116(1): 47–52.

    Google Scholar 

  11. SUFFET I H, BRENNER L, COYLE J T. Identification and treatment of tastes and odors in drinking water [J]. Environmental Science and Technology, 1978, 12: 1315–1322.

    Article  Google Scholar 

  12. CHINGOMBE P, SAHA B, WAKEMAN R J. Surface modification and characterisation of coal-based activated carbon [J]. Carbon, 2005, 43(15): 3132–3143.

    Article  Google Scholar 

  13. AYYAPPAN R, CARMALIN S A, SWAMINATHAN K, SANDHYA S. Removal of Pb(II) from aqueous solution using carbon derived from agricultural wastes [J]. Process Biochemistry, 2005, 40(3/4): 1293–1299.

    Article  Google Scholar 

  14. SONG Xiao-lan, LIU Hong-yan, CHENG Lei, QU Yi-xin. Surface modification of coconut-based activated carbon by liquid-phase oxidation and its effects on lead ion adsorption [J]. Desalination, 2010, 255(1/2/3): 78–83.

    Article  Google Scholar 

  15. BOEHM H P. Some aspects of the surface chemistry of carbon black and other carbons [J]. Carbon, 1994, 32(5): 759–769.

    Article  Google Scholar 

  16. MORENO C C, CARRASCO M F, MUEDEN A. The creation of acid carbon surfaces by treatment with (NH4)2S2O8 [J]. Carbon, 1997, 35(10/11): 1619–1626.

    Article  Google Scholar 

  17. ANIA C O, PARRA J B, PIS J J. Fuel Process Technol, 2002, 79: 265–271.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Xiao-lan Song  (宋晓岚).

Additional information

Foundation item: Project(2007AA06Z121) supported by the National High Technology Research and Development Program of China; Project(50774095) supported by the National Natural Science Foundation of China; Project(CL12111) supported by the Undergraduate Innovation Experimentation Plan of Central South University, China

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Song, Xl., Zhang, Mw., Zhang, Y. et al. Surface modification of coconut-based activated carbon by SDS and its effects on Pb2+ adsorption. J. Cent. South Univ. 20, 1156–1160 (2013). https://doi.org/10.1007/s11771-013-1598-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11771-013-1598-4

Key words

  • activated carbon
  • surface modification
  • sodium dodecyl sulfate
  • Pb2+ absorption