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Effect of indium addition on corrosion of AP65 magnesium alloy

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Abstract

The effect of indium addition on the corrosion behavior of AP65 Mg alloy was examined. The indium modified AP65 exhibits accelerated pitting corrosion and overall corrosion, but there is almost no incubation period at the onset of corrosion. Polarization curve measurements indicate that the indium modified AP65 has more negative corrosion potential, which is an improvement aspect of the electrochemical activation. The corrosion current density increases from 0.126 to 0.868 mA/cm2 with and without 2.0% (mass fraction) indium addition. The mean potentials of AP65 negatively shift from −1.491 V to −1.584 V by adding 2.0% indium. The effect of indium addition on the corrosion performance of AP65 seems to be associated with the decrease of cathode-to-anode area ratio of the alloy, which may change the electrochemical anode and cathode polarization behavior of the alloy.

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References

  1. FENG Yan, WANG Ri-chu, PENG Chao-qun, WANG Nai-guang. Influence of Mg21Ga5Hg3 compound on electrochemical properties of Mg-5%Hg-5%Ga alloy [J]. Transactions of Nonferrous Metals Society of China, 2009, 19(1): 154–159.

    Article  MathSciNet  Google Scholar 

  2. RENUKA R. Influence of allotropic modifications of sulphur on the cell voltage in Mg-CuI(S) seawater activated battery [J]. Materials Chemistry and Physics, 1999, 59(1): 42–48.

    Article  Google Scholar 

  3. DORON A, GURUKAR S S, ELENA L, ARIEL M, OREN M, ORIT C, MICHELA B. Progress in rechargeable magnesium battery technology [J]. Advanced Materials, 2007, 19: 4260–4267.

    Article  Google Scholar 

  4. RENUKA R. AgCl and Ag2S as additives to CuI in Mg-CuI seawater activated batteries [J]. Journal of Applied Electrochemistry, 1997, 27(12): 1394–1397.

    Article  Google Scholar 

  5. SONG Guang-ling. Effect of tin modification on corrosion of AM70 magnesium alloy [J]. Corrosion Science, 2009, 51(9): 2063–2070.

    Article  Google Scholar 

  6. FENG Yan, WANG Ri-chu, YU Kun, PENG Chao-qun, ZHANG Jia-pei, ZHANG Chun. Activation of Mg-Hg anodes by Ga in NaCl solution [J]. Journal of Alloys and Compounds, 2009, 473(1/2): 215–219.

    Article  Google Scholar 

  7. MA Zheng-qing, LI Wen-xian, YU Kun, WANG Ri-chu, LIANG Ying, CAO Jun-ji, YI Ning, LI Xue-hai. Electrochemical characteristics of magnesium alloys in synthetic seawater [J]. Materials Protection, 2002, 35(1): 16–18.

    Google Scholar 

  8. QU Qing, MA Jie, WANG Lin, LI Lei, BAI Wei, DING Zhong-tao. Corrosion behaviour of AZ31B magnesium alloy in NaCl solutions saturated with CO2 [J]. Corrosion Science, 2011, 53(4): 1186–1193.

    Article  Google Scholar 

  9. ZHAO Hong-yang, BIAN Pei, JU Dong-ying. Electrochemical performance of magnesium alloy and its application on the sea water battery [J]. Journal of Environmental Sciences, 2009, 21(Supplement): 88–91.

    Article  Google Scholar 

  10. SONG Guang-ling. Corrosion and protection of Mg alloys [M]. Beijing Chemical Industry Press, 2006: 38–40.

  11. ZHAO Ming-chun, LIU Ming, SONG Guang-ling, ATRENS A. Influence of the β-phase morphology on the corrosion of the Mg alloy AZ91 [J]. Corrosion Science, 2008, 50(7): 1939–1953.

    Article  Google Scholar 

  12. WANG Nai-guang, WANG Ri-chu, PENG Chao-qun, FENG Yan, ZHANG Xiang-yu. Corrosion behavior of Mg-Al-Pb and Mg-Al-Pb-Zn-Mn alloys in 3.5% NaCl solution [J]. Transactions of Nonferrous Metals Society of China, 2010, 20(10): 1936–1943.

    Article  Google Scholar 

  13. WANG Nai-guang, WANG Ri-chu, PENG Chao-qun, FENG Yan, ZHANG Xiang-yu. Influence of aluminum and lead on activation of magnesium as anode [J]. Transactions of Nonferrous Metals Society of China, 2010, 20(8): 1403–1411.

    Article  Google Scholar 

  14. ZAZOUA A, AZZOUZ N. An investigation on the use of indium to increase dissolution of Al Zn anodes in sea water [J]. Materials and Design, 2008, 29(4): 806–810.

    Article  Google Scholar 

  15. HUO Hong-wei, LI Ying, WANG Fu-hui. Corrosion of AZ91D magnesium alloy with a chemical conversion coating and electroless nickel layer [J]. Corrosion Science, 2004, 46(6): 1467–1477.

    Article  Google Scholar 

  16. LIU Wen-juan, CAO Fa-he, CHANG Lin-rong, ZHANG Zhao, ZHANG Jian-qing. Effect of rare earth element Ce and La on corrosion of behavior of AM60 magnesium alloy [J]. Corrosion Science, 2009, 51(6): 1334–1343.

    Article  Google Scholar 

  17. SONG Guang-ling, ATRENS A. Understanding magnesium corrosion-A framework for improved alloy performance [J]. Advanced Engineering Materials, 2003, 11(5): 837–858.

    Article  Google Scholar 

  18. SONG Guang-ling. Recent progress in corrosion and protection of Mg alloys [J]. Advanced Engineering Materials, 2005, 7(7): 563–586.

    Article  Google Scholar 

  19. AMBAT R, AUNG N N, ZHOU W. Evaluation of micro-structural effects on corrosion behavior of AZ91D magnesium alloy [J]. Corrosion Science, 2000, 42(8): 1433–1455.

    Article  Google Scholar 

  20. ZHAO Ming-chun, LIU Ming, SONG Guang-ling, ATRENS A. Influence of pH and chloride ion concentration on the corrosion of Mg alloy ZE41 [J]. Corrosion Science, 2008, 50(11): 3168–3178.

    Article  Google Scholar 

  21. SHI Zhi-ming, LIU Ming, ATRENS A. Measurement of the corrosion rate of magnesium alloys using Tafel extrapolation [J]. Corrosion Science, 2010, 52(2): 579–588.

    Article  Google Scholar 

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Correspondence to Ri-chu Wang  (王日初).

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Foundation item: Project(JPPT-115-168) supported by the National Key Science and Technology Program of China; Project(51101171) supported by the National Natural Science Foundation of China

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Jin, Hx., Wang, Rc., Peng, Cq. et al. Effect of indium addition on corrosion of AP65 magnesium alloy. J. Cent. South Univ. 19, 2086–2093 (2012). https://doi.org/10.1007/s11771-012-1249-1

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  • DOI: https://doi.org/10.1007/s11771-012-1249-1

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