Skip to main content
Log in

Magnetic field assisted electrocatalytic oxidation of organic pollutants in electroplating wastewater

  • Published:
Journal of Central South University Aims and scope Submit manuscript

Abstract

To degrade the organic compounds in the electroplating wastewater, magnetic field was tentatively introduced into electrocatalytic oxidation on Ti-PbO2 anode. The magnetic field assisted electrocatalytic oxidation can promote anion movement and the generation of active species, resulting more organic compounds to be oxidized and degraded. Oxidation parameters such as treatment time, current density and initial pH of the wastewater were systematically discussed and optimized. The mineralization of organic compounds is improved by over 15% under a magnetic density of 22 mT while the current density is 50 A/m2, pH is 1.8 and the reaction time is 1.5 h. The results indicate that the magnetic field assisted electrocatalytic oxidation has considerable potential in electroplating wastewater treatment.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. CAVACO S A, FERNANDES S, QUINA M M, FERREIRA L M. Removal of chromium from electroplating industry effluents by ion exchange resins [J]. Journal of Hazardous Materials, 2007, 144(3): 634–638.

    Article  Google Scholar 

  2. KUMAR R, BISHNOI N R, GARIMA, BISHNOI K. Biosorption of chromium(VI) from aqueous solution and electroplating wastewater using fungal biomass [J]. Chemical Engineering Journal, 2008, 135(3): 202–208.

    Article  Google Scholar 

  3. SOUSA F W, SOUSA M J, OLIVEIRA I R N, OLIVEIRA A G, CAVALCANTE R M, FECHINE P B A, NETO V O S, KEUKELEIRE D D, NASCIMENTO R F. Evaluation of a low-cost adsorbent for removal of toxic metal ions from wastewater of an electroplating factory [J]. Journal of Environmental Management, 2009, 90(11): 3340–3344.

    Article  Google Scholar 

  4. CHEN S S, LI C W, HSU H D, LEE P C, CHANG Y M, YANG C H. Concentration and purification of chromate from electroplating wastewater by two-stage electrodialysis processes [J]. Journal of Hazardous Materials, 2009, 161(2/3): 1075–1080.

    Article  Google Scholar 

  5. SCIBAN M, RADETIC B, KEVRESAN D, KLASNJA M. Adsorption of heavy metals from electroplating wastewater by wood sawdust [J]. Bioresource Technology, 2007, 98(2): 402–409.

    Article  Google Scholar 

  6. CHIANG L C, CHANG J E, TSENG S C. Electrochemical oxidation pretreatment of refractory organic pollutants [J]. Water Science and Technology, 1997, 36(2/3): 123–130.

    Article  Google Scholar 

  7. MARTINEZ-HUTITLE C A, BATTISTI A D, FERRO S, REYNA S, CERRO-LOPEZ M, QUIRO M A. Removal of the pesticide methamidophos from aqueous solutions by electrooxidation using Pb/PbO2, Ti/SnO2 and Si/BDD electrodes [J]. Environmental Science & Technology, 2008, 42(18): 6929–6935.

    Article  Google Scholar 

  8. UN U T, ALTAY U, KOPARAL A S, OGUTVEREN U B. Complete treatment of olive mill wastewaters by electrooxidation [J]. Chemical Engineering Journal, 2008, 139(3): 445–452.

    Article  Google Scholar 

  9. CHEN X M, GAO F R, CHEN G H. Comparison of Ti/BDD and Ti/SnO2-Sb2O5 electrodes for pollutant oxidation [J]. Journal of Applied Electrochemistry, 2005, 35(2): 185–191.

    Article  Google Scholar 

  10. IIDA T, MATSUSHIMA H, FUKUNAKA Y. Water electrolysis under a magnetic field [J]. Journal of the Electrochemical Society, 2007, 154(8): 112–115.

    Article  Google Scholar 

  11. CHATELUT M, VITTORI O. Influence of an external magnetic field on the electrochemical behaviour of ortho, meta and para nitrobenzaldehydes and nitrobenzoic acids in water dioxane solvent [J]. Elecrrochimica Acta, 1997, 42(15): 2355–2359.

    Article  Google Scholar 

  12. HAO X L, ZOU L Y, ZHANG G S, ZHANG Y B. Magnetic field assisted Fenton reactions for the enhanced degradation of methyl blue [J]. Chinese Chemical Letters, 2009, 20(1): 99–101.

    Article  Google Scholar 

  13. KEITH L H. Identification of organic-compounds in unbleached treated kraft paper-mill wastewaters [J]. Environmental Science & Technology, 1976, 10(6): 555–564.

    Article  Google Scholar 

  14. ROBIN M, SELLERS. Spectrophotometric determination of hydrogen peroxide using potassium titanium(IV) Oxalate [J]. Analyst, 1980, 105: 950–954.

    Article  Google Scholar 

  15. CASELLATO U, CATTARIN S, MUSIANI M. Preparation of porous PbO2 electrodes by electrochemical deposition of composites [J]. Electrochimica Acta, 2003, 48(27): 3991–3998.

    Article  Google Scholar 

  16. SAMET Y, ELAOUD S C, AMMAR S, ABDELHEDI R. Electrochemical degradation of 4-chloroguaiacol for waster water treatment using PbO2 anodes [J]. Journal of Hazardous Materials, 2006, B138(3): 614–619.

    Article  Google Scholar 

  17. ZHOU M H, DAI Q Z, LEI L C, MA C A, WANG D H. Long life modified lead dioxide anode for organic wastewater treatment: electrochemical characteristics and degradation mechanism [J]. Environmental Science & Technology, 2005, 39(1): 363–370.

    Article  Google Scholar 

  18. BUND A, KOEHLER S, KUEHNLEIN H H, PLIETH W. Magnetic field effects in electrochemical reactions [J]. Electrochimica Acta, 2003, 49(1): 147–152.

    Article  Google Scholar 

  19. CHO M S, YUN Y Y, NAM J D, SON Y, LEE Y. Effect of magnetic field on electrochemical polymerization of EDOT [J]. Synthetic Metals, 2008, 158(21/22/23/24): 1043–1046.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Hui-xiang Shi  (史惠祥).

Additional information

Foundation item: Project(2008ZX07101-006-09) supported by the Major Science and Technology Program for Water Pollution Control and Treatment of China

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, Z., Ye, Kw., Yang, Z. et al. Magnetic field assisted electrocatalytic oxidation of organic pollutants in electroplating wastewater. J. Cent. South Univ. Technol. 19, 1679–1684 (2012). https://doi.org/10.1007/s11771-012-1193-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11771-012-1193-0

Key words

Navigation