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Effect of surface treatment on rheological behaviors of glass bead/hydroxyl terminated polybutadiene suspensions

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Abstract

Surface treatment of glass bead (GB) was carried out by using γ-glycidoxypropyltrimethoxy silane (GPTES) and γ-methacryloxypropyltrimethoxy silane (MPTMS) as coupling agents, respectively. The steady viscosity and yield stress of the GB/hydroxyl terminated polybutadiene (HTPB) suspensions were determined by Brookfield R/S rheometer. The effect of surface treatment on the viscosity and yield stress of GB/HTPB suspension was investigated. The results indicate that the viscosity of the pristine GB/HTPB suspension increases with increasing GB, and the relationship between its viscosity and volume fraction of GB depends on the shear rate. The modification of GB by MPTMS changes the viscosity of the MPTMS@GB/HTPB suspension, and its viscosity is the minimum at the MPTMS dosage of 0.3 g per 1 g GB. Additionally, the modification of GB by MPTMS increases the yield stress of the GB/HTPB suspension, and its yield stress is the maximum at the MPTMS dosage of 0.1 g per 1 g GB. The GPTES modified GB/HTPB suspension behaves lower viscosity and weaker shear thinning than the MPTMS modified GB/HTPB suspension within the range of experimental shear rate.

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References

  1. BARNES H A, HUTTON J F, WALTERS K. An introduction to rheology[M]. New York: Elsevier, 1989.

    Google Scholar 

  2. POSLINSKI A J, RYAN M E, GUPTA R K, SESHADRI S G, FRELHETTE F J. Rheological behavior of filled polymeric system (I): Yield stress and shear-thinning effects[J]. Journal of Rheology, 1988, 32(7): 703–735.

    Article  Google Scholar 

  3. METZNER A B. Rheology of suspensions in polymeric liquids[J]. Journal of Rheology, 1985, 29(6): 739–775.

    Article  Google Scholar 

  4. GUPTA R K, SESHADRI S G. Maximum loading levels in filled liquid systems[J]. Journal of Rheology, 1986, 30(3): 503–508.

    Article  Google Scholar 

  5. ZHOU Z W, SOLOMON M J, SCALES P J, BOGER D V. The yield stress of concentrated flocculated suspensions of size distributed particles[J]. Journal of Rheology, 1998, 43(3): 651–671.

    Article  Google Scholar 

  6. SHENOY A V. Rheology of filled polymer systems [M]. Dordrecht: Kluwer Academic Publishers, 1999.

    Google Scholar 

  7. PROBSTEIN R F, SENGUN M Z, TSENG T C. Bimodal model of concentrated suspension viscosity for distributed particle sizes[J]. Journal of Rheology, 1994, 38(4): 811–829.

    Article  Google Scholar 

  8. KRIEGER I M, DOUGHERTY T J. A mechanism for the non-Newtonian in suspensions of rigid spheres[J]. Transactions of the Society of Rheology, 1959, 3(1): 137–152.

    Article  Google Scholar 

  9. MARON S H, PIERCE P E. Application of ree-eyring generalized flow theory to suspensions of spherical particles[J]. Journal of Colloid Science, 1956, 11(1): 80–95.

    Article  Google Scholar 

  10. KAWAGUCHI M, YAMAMOTO T, KATO T. Rheological studies of hydrophilic and hydrophobic silica suspensions in the presence of adsorbed poly(n-isopropylacrylamide)[J]. Langmuir, 1996, 12(26): 6184–6187.

    Article  Google Scholar 

  11. STAMHUIS J E, LOPPÉ J P A. Rheological determination of polymer-filler affinity[J]. Rheological Acta, 1982, 21(1): 103–105.

    Article  Google Scholar 

  12. MARY B, DUBOIS C, CARREAU P J, BROUSSEAU P. Rheological properties of suspensions of polyethylene-coated aluminum nanoparticles[J]. Rheological Acta, 2006, 45(5): 561–573.

    Article  Google Scholar 

  13. PLUEDDEMANN E P. Silane coupling agents[M]. New York: Plenum Press, 1991.

    Google Scholar 

  14. LEE J D, YANG S M. Rheo-optical behaviors and stability of a silica particle suspension coated with silane coupling agents[J]. Journal of Colloid and Interface Science, 1998, 205(2): 397–409.

    Article  MathSciNet  Google Scholar 

  15. XIE X L, TANG C Y, ZHOU X P, et al. Enhanced interfacial adhesion between PPO and glass beads in composites by surface modification of glass beads via in situ polymerization and copolymerization[J]. Chemistry of Materials, 2004, 16(1): 133–138.

    Article  Google Scholar 

  16. LIDDELL P V, BOGER D V. Yield stress measurements with the vane[J]. Journal of Non-Newtonian Fluid Mechanics, 1996, 63(2/3): 235–261.

    Article  Google Scholar 

  17. ZHOU Z W, SCALES P J, BOGER D V. Chemical and physical control of the rheology of concentrated metal oxide suspensions[J]. Chemical Engineering Science, 2001, 56(9): 2901–2920.

    Article  Google Scholar 

  18. ZAMAN A A, BJELOPAVLIC M, MOUDGIL B M. Effect of adsorbed polyethylene oxide on the rheology of colloidal silica suspensions[J]. Journal of Collloidal and Interface Science, 2000, 226(2): 290–298.

    Article  Google Scholar 

  19. POSTHUMUS W, MAGUSIN P C M M, BROKKEN-ZIJP J C M, TINNEMANS A H A, van der LINDE R. Surface modification of oxidic nanoparticles using 3-methacryl oxypropyltrimethoxysilane[J]. Journal of Collloidal and Interface Science, 2004, 269(1): 109–116.

    Article  Google Scholar 

  20. BAUER F, ERNST H, DECKER U, et al. Preparation of scratch and abrasion resistant polymeric nanocomposites by monomer grafting onto nanoparticles, 1 FTIR and multi-nuclear NMR spectroscopy to the characterization of methacryl grafting[J]. Macromolecular Chemistry and Physics, 2000, 201(18): 2654–2659.

    Article  Google Scholar 

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China

    Wei Cui  (崔 伟), Jin-chao Zhao  (赵瑾朝), Cheng-zhe Wang  (王承哲), Xing-ping Zhou  (周兴平) & Xiao-lin Xie  (解孝林)

  2. Hubei Key Laboratory of Materials Chemistry and Service Failure, Huazhong University of Science and Technology, Wuhan, 430074, China

    Wei Cui  (崔 伟), Jin-chao Zhao  (赵瑾朝), Cheng-zhe Wang  (王承哲), Xing-ping Zhou  (周兴平) & Xiao-lin Xie  (解孝林)

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  1. Wei Cui  (崔 伟)
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  2. Jin-chao Zhao  (赵瑾朝)
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  3. Cheng-zhe Wang  (王承哲)
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  4. Xing-ping Zhou  (周兴平)
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  5. Xiao-lin Xie  (解孝林)
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Correspondence to Xiao-lin Xie  (解孝林).

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Cui, W., Zhao, Jc., Wang, Cz. et al. Effect of surface treatment on rheological behaviors of glass bead/hydroxyl terminated polybutadiene suspensions. J. Cent. South Univ. Technol. 15 (Suppl 1), 158–162 (2008). https://doi.org/10.1007/s11771-008-0337-8

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  • DOI: https://doi.org/10.1007/s11771-008-0337-8

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