Abstract
A novel polyamide 6/silica nanocomposite containing epoxy resins (EPA6N) was prepared via in situ polymerization using tetraethoxysilane (TEOS) as the precursor of silica. The dynamic rheological properties of pure PA6 and EPA6N at temperatures of 225 and 235 °C were investigated. The results of transmission electron microscopy (TEM) and atomic force microscopy (AFM) indicate that the silica particles are well dispersed in the polyamide 6 matrix on about 30 nm in diameter, which demonstrates that this method can effectively avoid agglomeration of the inorganic particles. The rheological results suggest that pure PA6 shows Newtonian behavior. However, the novel EPA6N exhibits a solid-like rheological behavior, which is due to the small size, large surface of silica particles and the stronger polyamide 6-silica chemical bond formed through the reactions of epoxy resins with end groups of PA6 molecular chains. The EPA6N also exhibits higher melt viscosity, storage modulus and loss modulus than those of pure PA6.
Similar content being viewed by others
References
GIANNELIS E P. Polymer layered silicate nanocomposites [J]. Adv Mater, 1993, 8: 29–35.
WEN Y, WILKES G L. Organic/inorganic hybrid network materials by the sol-gel approach [J]. Chem Mater, 1996, 8: 1667–1681.
SHARP K G. Inorganic/organic hybrid materials [J]. Adv Mater, 1998, 10: 1243–1248.
WEI Shan-shan, ZHANG Ping, WANG Xia-yu. Study on the mechanical properties of nylon 6/nano-SiO2 compositions [J]. Natural Science Journal of Xiangtan University, 2002, 24(4): 42. (in Chinese)
SHEN L, DU Q G, WANG H T, et al. In situ polymerization and characterization of polyamide-6/silica nanocomposites derived from water glass [J]. Polym Int, 2004, 53: 1153–1160.
WANG Xia-yu, ZHAO Cai-xian, ZHANG Ping. Study on dynamic mechanical behavior of PA6/SiO2 nanocomposites [J]. Natural Science Journal of Xiangtan University, 2005, 27(1): 106–112. (in Chinese)
SALIMA B, ELODIE B L, NATHALIE Z. Silica/polyamide nanocomposite synthesis via an original double emulsification process in miniemulsion [J]. Macromol Rapid Comm, 2005; 26: 1860–1865.
YI Lan-hua, ZHAO Cai-xian, ZHANG Ping, et al. The determination of cyclic oligomers in PA6/SiO2 nanocomposites by HPLC [J]. Natural Science Journal of Xiangtan University, 2006, 28(4): 70–74. (in Chinese)
ZHAO Cai-xian, ZHANG Ping, WANG Xia-yu, et al. Study on the non-isothermal crystallization behaviors of PA6/silica nano-composites prepared by the sol-gel process [J]. J Mater Sci, 2007, 42: 9083–9099.
ZHAO Cai-xian, ZHANG Ping, WANG Xia-yu, et al. Preparation of PA6/SiO2 nanocomposites by in situ polymerization [J]. Polymer Materials Science and Engineering, 2007, 23: 218–221. (in Chinese)
ZHANG Ping, WANG Xia-yu, ZHAO Cai-xian. A new method for prepared PA6/EP/silica nanocomposites via in situ polymerization: China Patent, ZL, 200610031604.8 [P]. 2006.
ZHAO Cai-xian, ZHANG Ping, WANG Xia-yu, et al. Study on the non-isothermal crystallization kinetics of novel polyamide 6/silica nanocomposites containing epoxy resins [J]. Polymer Testing, 2008, 27: 412–419.
INCARNATO L, SCARFACO P, ACIERNO D. Rheological behavior of new melt compounded copolyamide nanocomposites [J]. Polymer, 2004, 45: 3487–3496.
DU Miao, ZHENG Qiang, YANG Hong-mei. Dynamic rheological behavior for polymer composites filled with particles [J]. Journal of the Society of Rheology, 2003, 31: 305–311.
RAVISHANKAR K, AYYER A I. Comparative rheological studies of polyamide-6 and its low loaded nanocomposite based on layered silicates [J]. Rheol Acta, 2004, 43: 1435–1528.
VLASVELD D P N, JONG M, BERSEE H E N, et al. The relation between rheological and mechanical properties of PA6 nano- and micro-composites [J]. Polymer, 2005, 46: 10279–10289.
YANG Hong, LI Bo, WANG Ke, et al. Rheology and phase structure of PP/EPDM/SiO2 ternary composites [J]. Europe Polymer J, 2008, 44: 113–123.
Author information
Authors and Affiliations
Corresponding author
Additional information
Foundation item: Project(07A071) supported by the Scientific Research Foundation of Hunan Provincial Education Department
Rights and permissions
About this article
Cite this article
Zhao, Cx., Zhang, P., Chen, Gb. et al. Rheological behavior of novel polyamide 6/silica nanocomposites containing epoxy resins. J. Cent. South Univ. Technol. 15 (Suppl 1), 76–79 (2008). https://doi.org/10.1007/s11771-008-0318-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11771-008-0318-y