Skip to main content
Log in

Adsorption of copper(II) and chromium(VI) on diaspore

  • Published:
Journal of Central South University of Technology Aims and scope Submit manuscript

Abstract

The adsorption of Cu(II) and Cr(VI) on diaspore was studied with the help of X-ray diffraction analysis, BE measurement, zeta potential measurement and atomic adsorption spectrometry. The adsorption equilibrium almost reaches within 60 min. The adsorption isotherms of Cu(II) and Cr(VI) could be well described by the Langmuir equation. The adsorption capacities o Cu(II) and Cr(VI) are 1.944 and 1.292 mg/g, respectively. The adsorption percentage of Cr(II) increases with the increment solution pH, but the adsorption percentage of Cr(VI) decreases. This could be explained by zeta potential theoretical and electrostatic attraction between metal ions and diaspore surface.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. SITTING M. Handbook of toxic and hazardous chemicals [M]. Bracknell: Noyes Publications, 1981.

    Google Scholar 

  2. DAS D D, MAHAPATRA R, PRADHAN J, DAS S N, THAKUR R S. Removal of Cr(VI) from aqueous solution using activated cow dung carbon [J]. Journal of Colloid and Interface Science, 2000, 232(2): 235–240.

    Article  Google Scholar 

  3. BEREKET G, AROG A Z, OZEL M Z. Removal of Pb(II), Cd(II), Cu(II) and Zn(II) from aqueous solutions [J]. Journal of Colloid and Interface Science, 1997, 187(2): 338–343.

    Article  Google Scholar 

  4. HESHAM A, PHILIP R W. XPS study of the adsorption of lead on goethite (α-FeOOH) [J]. Applied Surface Science, 1998, 136(1/2): 46–54.

    Google Scholar 

  5. JUANG R S, WU W L. Adsorption of sulfate and copper(II) on goethite in relation to the change of zeta potentials [J]. Journal of Colloid and Interface Science, 2002, 249(1): 22–29.

    Article  Google Scholar 

  6. TRIVEDI P, AXE L, DYER J. Adsorption of metal ions onto goethite: Single-adsorbate and competitive systems [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2001, 191(1/2): 107–121.

    Article  Google Scholar 

  7. FROST R L, KLOPROGGE J T. Dehydroxylation and the vibrational spectroscopy of aluminum oxyhydroxides using infrared emission spectroscopy (Part III): Diaspore [J]. Applied Spectroscopy, 1999, 53(7): 829–835.

    Article  Google Scholar 

  8. RODDA D P, WELLS J D, JOHNSON B B. Anomalous adsorption of copper(II) on goethite [J]. Journal of Colloid and Interface Science, 1996, 184(2): 564–569.

    Article  Google Scholar 

  9. CHEN Xiang-qing, HU Yue-hua, WANG Yu-hua, XIONG Dao-ling. Effects of sodium hexmetaphosphate on flotation separation of diaspore and kaolinite [J]. Journal of Central South University of Technology, 2005, 12(4): 420–424.

    Article  Google Scholar 

  10. HU Yue-hua, LIU Xiao-wen, XU Zheng-he. Role of crystal structure in flotation separation of diaspore from kaolinite, pyrophyllite and illite [J]. Minerals Engineering, 2003, 16(3): 219–227.

    Article  Google Scholar 

  11. PARKS G A. The isoelectric points of solids, solid hydroxides, and aqueous hydroxo complex systems [J]. Chemical Review, 1965, 65: 177–198.

    Article  Google Scholar 

  12. YOON R H, SALMAN T, DONNAY G. Predictive point zero charge of oxides and hydroxides [J]. Journal of Colloid and Interface Science, 1979, 70(3): 483–493.

    Article  Google Scholar 

  13. LIU Xiao-wen, HU Yue-hua, XU Zheng-he. Effect of chemical composition on electrokinetics of diaspore [J]. Journal of Colloid and Interface Science, 2003, 267(1): 211–216.

    Article  Google Scholar 

  14. KO K R, RYU S K, PARK S J. Effect of ozone treatment on Cu(II) and Cr(VI) adsorption behavious of activated carbon fibers[J]. Carbon, 2004, 42(8/9): 1864–1867.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yue-hua Hu  (胡岳华).

Additional information

Foundation item: Project(2005CB623701) supported by the Major State Basic Research Development Program of China

Rights and permissions

Reprints and permissions

About this article

Cite this article

Liu, Xw., Wang, Jr. & Hu, Yh. Adsorption of copper(II) and chromium(VI) on diaspore. J. Cent. South Univ. Technol. 15, 515–519 (2008). https://doi.org/10.1007/s11771-008-0097-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11771-008-0097-5

Key words

Navigation