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Effect of magnetic field on property and structure of polyaniline doped with multiple sulfonic acids

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Abstract

Polyaniline(PAn) doped with multiple sulfonic acid system of dodecylbenzenesulfonic acid(DBSA) and sulfosalicylic acid(SSA) was synthesized by emulsion polymerization using ammonium persulfate(APS) as an oxidizing agent in the presence and the absence of a constant magnetic field(MF)of 0.8 T. The structure and properties of the PAn were characterized by X-ray diffractometer(XRD), thermogravimetric apparatus(TGA), FT-IR spectroscope(FT-IR) and four probe digital multimeter. The results indicate that, when the molar ratio of DBSA to SSA is 1/3, that of dopant to An is 3/2, that of APS to An is 4/5 in the synthesizing media, and the doping time is 3 h, the conductivity of the PAn synthesized in the presence of the MF of 0.8 T reaches 5.88 S/cm, which is higher than that of the PAn synthesized in the absence of the MF. The thermal stability, the crystallinity and the doping degree of the PAn synthesized in the presence of the MF are also improved. MF not only enhances the conductivity, but also reduces the doping time, the dosage of the dopant and the oxidizing agent when the conductivity reaches the maximum.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China

    Li Ma  (马 利) & Ke-long Huang  (黄可龙)

  2. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 400044, China

    Li Ma  (马 利), Chao Chen  (陈 超), Meng-yu Gan  (甘孟瑜), Wei Lu  (卢 苇) & Feng-qiang Chen  (陈奉强)

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  1. Li Ma  (马 利)
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  2. Ke-long Huang  (黄可龙)
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  3. Chao Chen  (陈 超)
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  4. Meng-yu Gan  (甘孟瑜)
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  5. Wei Lu  (卢 苇)
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  6. Feng-qiang Chen  (陈奉强)
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Correspondence to Li Ma  (马 利).

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Foundation item: Project(20176066) supported by the National Natural Science Foundation of China

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Ma, L., Huang, Kl., Chen, C. et al. Effect of magnetic field on property and structure of polyaniline doped with multiple sulfonic acids. J. Cent. South Univ. Technol. 15, 479–483 (2008). https://doi.org/10.1007/s11771-008-0090-z

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  • DOI: https://doi.org/10.1007/s11771-008-0090-z

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