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Influence of Mg3N2 powder on microstructures and mechanical properties of AZ31 Mg alloy

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Abstract

In order to obtain an effective and reliable grain refiner for Mg-Al alloys, 1% (mass fraction) Mg3N2 was added into AZ31 Mg alloy. The microstructures of the Mg alloys were studied by optical microscopy, scan electron microscopy and X-ray energy dispersive spectroscopy, and the mechanical properties were determined. The results show that adding a small amount of Mg3N2 to AZ31 Mg alloy can refine the grain size from 103 to 58 μm. The ultimate tensile strength and elongation of AZ31 Mg alloy are 174.1MPa and 8.3%, respectively. After the addition of 1% Mg3N2, the ultimate tensile strength and elongation of AZ31 Mg alloy are increased up to 198.7 MPa and 11.8%, respectively. The grain refinement mechanism is that AlN is formed after Mg3N2 is added. Both AlN and Mg phases are of HCP lattice structure, and the disregistry between Mg phases and AlN along (0001)Mg//(0001)AlN is 3.04%, which is very effective for heterogeneous nucleation.

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References

  1. KINJI H, HIDETOSHI S, YORINOBU T, KENJI H. Effects of Ca and Sr addition on mechanical properties of a cast AZ91 magnesium alloy at room and elevated temperature [J]. Materials Science and Engineering A, 2005, A403: 276–280.

    Google Scholar 

  2. TONY S, VESSELINA R NIKOLAY N. Nanocrystallization and hydrogen storage in rapidly solidified Mg-Ni-RE alloys [J]. Journal of Alloys and Compounds, 2001, 334: 219–223.

    Google Scholar 

  3. MORDIKE B L, EBERT T. Magnesium: Properties—Applications—Potential [J]. Materials Science and Engineering A, 2001, A302(1): 37–45.

    Article  Google Scholar 

  4. KUBOTA K, MABUCHI M, HIGASHI K. Review processing and mechanical properties of fine-grained magnesium alloys [J]. Journal of Materials Science, 1999, 34(10): 2255–2262.

    Article  Google Scholar 

  5. TAMURA Y, KONO N, MOTEGI T. Grain refining of pure magnesium by adding Mg-Zr master alloy [J]. Journal of Japan Institute of Light Metals, 1997, 47(12): 679–684.

    Article  Google Scholar 

  6. STJOHN D H, MA Q, MARK A E. Grain refinement of magnesium alloys [J]. Metallurgical and Materials Transactions A, 2005, 36(7): 1669–1679.

    Article  Google Scholar 

  7. LEE Y, DAHLE A, STJOHN D. The role of solute in grain refinement of magnesium [J]. Metallurgical and Materials Transactions A, 2000, 31(11): 2895–2906.

    Article  Google Scholar 

  8. LIU Yan-hui, LIU Xiang-fa, BIAN Xiu-fang. Grain refinement of Mg-Al alloys with Al4C3-SiC/Al master alloy [J]. Materials Letters, 2004, 58(7/8): 1282–1287.

    Article  Google Scholar 

  9. JIN Q L, EOM J P, LIM S G. Grain refining mechanism of carbon addition method in Mg-Al magnesium alloy [J]. Scripta Mater, 2003, 49(11): 1129–1132.

    Article  Google Scholar 

  10. YANO E, TAMURA Y, MOTEGI T. Effect of carbon powder on grain refinement of an AZ91E magnesium alloy [J]. Materials Transactions, 2003, 44(1): 107–110.

    Article  Google Scholar 

  11. CHEN Jing-yang, GUAN Shao-kang, SHI Guang-xin. Effects of B on microstructure and properties of Mg-7Al-0.4Zn-0.2Mn alloy [J]. Special Casting and Nonferrous Alloys, 2005, 25(8): 454–456. (in Chinese)

    Google Scholar 

  12. HOU Q H, RAJ M, MICHAEL K. Feasibility of aluminium nitride formation in aluminium alloys [J]. Materials Science and Engineering A, 1995, A195: 121–129.

    Article  Google Scholar 

  13. YE H Z, LIU X Y, BEN L. In situ synthesis of AlN in Mg-Al alloys by liquid nitridation [J]. Journal of Materials Processing Technology, 2005, 166(1): 79–85.

    Article  Google Scholar 

  14. YE H Z, LIU X Y, BEN L. In situ synthesis of AlN particles in Mg-Al alloy by Mg3N2 addition [J]. Materials Letters, 2004, 58(19): 2361–2364.

    Article  Google Scholar 

  15. LU L, DAHLE A K, TAYLOR J A. Theoretical and practical considerations of grain refinement of Mg-Al alloys [J]. Materials Science Forum, 2005, 488/489: 299–302.

    Article  Google Scholar 

  16. LU L, DAHLE A K, STJOHN D H. Grain refinement efficiency and mechanism of aluminium carbide in Mg-Al alloys [J]. Scripta Materialia, 2005, 53(5): 517–522.

    Article  Google Scholar 

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Correspondence to Hong-liang Zhao  (赵红亮).

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Foundation item: Project(2007430023) supported by the Office of Education, Henan Province, China; Project(0612002500) supported by the Excellent Young Scientists Foundation of Henan Province, China

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Zhao, Hl., Zhou, Zx., Liu, Xd. et al. Influence of Mg3N2 powder on microstructures and mechanical properties of AZ31 Mg alloy. J. Cent. South Univ. Technol. 15, 459–462 (2008). https://doi.org/10.1007/s11771-008-0086-8

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  • DOI: https://doi.org/10.1007/s11771-008-0086-8

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