Abstract
With the microscopic phase-field dynamic model, the effects of temperature and concentration on the nucleation incubation time of Ni75AlxV25−x alloy were studied and the relation between the incubation time and precipitation mechanism was investigated by using the atomic occupation probability picture and average order parameter curve. The simulation results demonstrate that there exists the incubation time for different precipitation mechanisms, such as non-classical nucleation, the mixed style of non-classical nucleation and spinodal decomposition, and spinodal ordering; and the incubation time shortens in turn for the three kinds of mechanisms. With the increase of Al content of Ni75AlxV25−x alloy, the incubation time of L12 phases shortens continuously and that of D022 phases is prolonged. The effects of temperature on the incubation time of L12 and D022 phases are accordant, i.e. the incubation time is greatly prolonged with the temperature rising.
Similar content being viewed by others
References
Robson J D. Modelling the overlap of nucleation, growth and coarsening during precipitation[J]. Acta Mater, 2004, 52: 4669–4676.
Wagner R, Kampmann R. Phase Transformations in Materials[M]. Weinheim: VCH Verlagsges, 1991.
Cherne F J, Baskes M I, Schwarz R B, et al. Nonclassical nucleation in supercooled nickel[J]. Modelling Simul Mater Sci Eng, 2004, 12: 1063–1068.
Kessler M, Dieterich W, Majhofer A. Ordering kinetics in an fcc A3B binary alloy model: Monte Carlo studies[J]. Physical Review B, 2003, 67: 134201.
Soisson F, Martin G. Monte-Carlo simulations of the decomposition of metastable solid solutions: transient and steady-state nucleation kinetics [J]. Physical Review B, 2000, 62(1): 203–214.
Chen L Q, Simmons J A. Microscopic master equation approach to diffusional transformations in inhomogeneous systems-single site approximation and direct exchange mechanism[J]. Acta Metal Mater, 1994, 42(9): 2943–2954.
Khachaturyan A G. Theory of Structural Transformation in Solids[M]. New York: Wiley, 1983.
WANG Yong-xin, CHEN Zheng, LIU Bing, et al. Computer simulation on precipitation mechanism of phase in early stage in external energy field [J]. The Chinese Journal of Nonferrous Metals, 2004, 14(1): 255–262. (in Chinese)
ZHAO Yu-hong, CHEN Zheng, LI Xiao-ling. Computer simulation of strain-induced morphological transformation of coherent precipitates [J]. J Univ Sci Technol Beijing, 2003, 10(4): 55–60.
Zapolsky H, Pareige C, Marteau L, et al. Atom probe analyses and numerical calculation of ternary phase diagram in Ni-Al-V system [J]. Calphad, 2001, 25(1): 125–134.
Pareige C, Blavette D. Simulation of the FCC→FCC+L12+D022 kinetic reaction [J]. Scripta Mater, 2001, 44: 243–247.
Chen L Q, Khachaturyan A G. Computer simulation of structural transformations during precipitation of an ordered intermetallic phase [J]. Acta Metall Mater, 1991, 39(11): 2533–2551.
Chen L Q. A computer simulation technique for spinodal decomposition and ordering in ternary systems [J]. Scripta Metall Mater, 1993, 29(5): 683–688.
Lifshitz E M, Pitaevski L P. Statistical Physics[M]. Oxford: Pergamon Press, 1980.
Poduri R, Chen L Q. Computer simulation of atomic ordering and compositional clustering in the pseudobinary Ni3Al-Ni3V system[J]. Acta Mater, 1998, 46(5): 1719–1729.
Poduri R, Chen L Q. Computer simulation of the kinetics of order-disorder and phase separation during precipitation of (Al3Li) in Al-Li alloys[J]. Acta Mater, 1997, 45(11): 245–255.
Author information
Authors and Affiliations
Corresponding author
Additional information
Foundation item: Project(50071046) supported by the National Natural Science Foundation of China; project(2002AA331051) supported by the National High Technology Research and Development Program of China
Rights and permissions
About this article
Cite this article
Li, Ys., Chen, Z., Lu, Yl. et al. Microscopic phase-field simulation for nucleation incubation time of Ni75AlxV25−x alloy. J Cent. South Univ. Technol. 12, 635–640 (2005). https://doi.org/10.1007/s11771-005-0060-7
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11771-005-0060-7