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Self-cleaning glass coated with Fe3+-TiO2 thin film

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Abstract

The self-cleaning glass coated with Fe3+-TiO2 photocatalytic thin film was prepared by sol-gel process from the system Ti(OC4H9)4-NH(C2H4OH)2-C2H5OH-H2O containing FeCl3. The microstructure and properties of the film were studied using differential thermal analysis-thermogravimetry(DTA-TG), X-ray diffration(XRD) and scanning electron microscope(SEM). The transmittance of the self-cleaning glass was measured by using UV-Vis spectrometer. The effects of content of Fe3+ and the thickness of Fe3+-TiO2 thin film on the photocatalytic activity were examined. The results show that the photocatalytic thin films are mainly composed of Fe3O4 and TiO2 particles within 10 – 100 nm. The appropriate amount of Fe3+ is effective for improving the photocatalytic activities of TiO2. The best photocatalytic activity is obtained when the molar ratio of Fe3+ to TiO2 is 0.005 and the glass is coated with 9 layers.

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Correspondence to Lu An-xian.

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Lu, Ax., Lin, N., Li, X. et al. Self-cleaning glass coated with Fe3+-TiO2 thin film. J Cent. South Univ. Technol. 11, 124–127 (2004). https://doi.org/10.1007/s11771-004-0026-1

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  • DOI: https://doi.org/10.1007/s11771-004-0026-1

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