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Iron Oxide Catalysts Supported on Porous Silica for the Production of Biodiesel from Crude Jatropha Oil

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Journal of the American Oil Chemists' Society

Abstract

A heterogeneous catalyst, FeO x /SiO2, prepared by the pore-filling method, was found to be active in the transesterification of crude Jatropha oil with methanol. When the transesterification reaction was carried out with a reaction temperature of 220 °C, a catalyst amount of 15 wt%, a methanol/oil molar ratio of 218:1, and a reaction time of 3 h, the yield of fatty acid methyl esters (FAME) in the product exceeded 99.0 %, and met with EN standards for allowable contents of glycerine and mono-, di-, and tri-glycerides. The correlation between the FAME production activity and measured acidity of the FeO x /SiO2 catalysts showed that the transesterification reaction was promoted via the acidic function of these catalysts, which are less inhibited by coexisting free fatty acids in the feedstock triglycerides.

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References

  1. Ma F, Hanna MA (1999) Biodiesel production: a review. Bioresour Technol 70:1–15

    Article  CAS  Google Scholar 

  2. Gryglewicz S (1999) Rapeseed oil methyl esters preparation using heterogeneous catalysts. Bioresour Technol 70:249–253

    Article  CAS  Google Scholar 

  3. Bournay L, Casanave D, Delfort B, Hillion G, Chodorge JA (2005) New heterogeneous process for biodiesel production: a way to improve the quality and the value of the crude glycerin produced by biodiesel plants. Catal Today 106:190–192

    Article  CAS  Google Scholar 

  4. Kim M, DiMaggio C, Yan S, Wang H, Salley SO, Simon Ng KY (2011) Performance of heterogeneous ZrO2 supported metaloxide catalysts for brown grease esterification and sulfur removal. Bioresour Technol 102:2380–2386

    Article  CAS  Google Scholar 

  5. Ngo HL, Zafiropoulos NA, Foglia TF, Samulski ET, Lin W (2008) Efficient two-step synthesis of biodiesel from greases. Energy Fuels 22:626–634

    Article  CAS  Google Scholar 

  6. Berchmans HJ, Hirata S (2008) Biodiesel production from crude Jatropha curcas L. seed oil with a high content of free fatty acids. Bioresour Technol 99:1716–1721

    Article  CAS  Google Scholar 

  7. Hayyan A, Alam MZ, Mirghani MES, Kabbashi NA, Hakimi NINM, Siran YM, Tahiruddin S (2011) Reduction of high content of free fatty acid in sludge palm oil via acid catalyst for biodiesel production. Fuel Process Technol 92:920–924

    Article  CAS  Google Scholar 

  8. Jitputti J, Kitiyanan B, Rangsunvigit P, Bunyakiat K, Attanatho L, Jenvanitpanjakul P (2006) Transesterification of crude palm kernel oil and crude coconut oil by different solid catalysts. Chem Eng J 116:61–66

    Article  CAS  Google Scholar 

  9. Juan JC, Kartika DA, Wub TY, Hin TYY (2011) Biodiesel production from jatropha oil by catalytic and non-catalytic approaches: an overview. Bioresour Technol 102:452–460

    Article  CAS  Google Scholar 

  10. Peng BX, Shu Q, Wang JF, Wang GR, Wang DZ, Han MH (2008) Biodiesel production from waste oil feedstocks by solid acid catalysis. Process Saf Environ Protect 86:441–447

    Article  CAS  Google Scholar 

  11. Semwal S, Arora AK, Badoni RP, Tuli DK (2011) Biodiesel production using heterogeneous catalysts. Bioresour Technol 102:2151–2161

    Article  CAS  Google Scholar 

  12. Brown JC, Gulari E (2004) Hydrogen production from methanol decomposition over Pt/Al2O3 and ceria promoted Pt/Al2O3 catalysts. Catal Commun 5:431–436

    Article  CAS  Google Scholar 

  13. Lotero E, Liu YJ, Lopez DE, Suwannakarn K, Bruce DA, Goodwin JG Jr (2005) Synthesis of biodiesel via acid catalysis. Ind Eng Chem Res 44:5353–5363

    Article  CAS  Google Scholar 

  14. Restola G, Auroux A (2010) Surface acid–base characterization of containing group IIIA catalysts by using adsorption microcalorimetry. In: Occeli ML (ed) Advances in fluid catalytic cracking. CRC Press, Boca Raton, pp 199–256

    Google Scholar 

  15. Mochizuki T, Toba M, Morita Y, Yoshimura Y (2008) Effect of Yb loading on aromatic hydrogenation activity of Pd-Pt/USY zeolite catalysts. J Jpn Pet Inst 51:58–64

    Article  CAS  Google Scholar 

  16. Tanabe K (1970) Solid acids and bases. Kodansha/Academic Press, Tokyo/New York

    Google Scholar 

  17. (2004) Thermodynamic Database MALT for Windows, MALT Group, Kagaku Gijutsu-Sha, Tokyo

  18. Connell G, Dumesic JA (1986) Acidic properties of binary oxide catalysts. J Catal 101:103–113

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported by the Japan Science and Technology Agency, and the Science and Technology Research Partnership for Sustainable Development.

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Correspondence to Yuji Yoshimura.

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Suzuta, T., Toba, M., Abe, Y. et al. Iron Oxide Catalysts Supported on Porous Silica for the Production of Biodiesel from Crude Jatropha Oil. J Am Oil Chem Soc 89, 1981–1989 (2012). https://doi.org/10.1007/s11746-012-2101-3

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  • DOI: https://doi.org/10.1007/s11746-012-2101-3

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